{"id":3594,"date":"2015-02-12T13:53:57","date_gmt":"2015-02-12T05:53:57","guid":{"rendered":"\/\/www.gsbet888.com\/?p=3594"},"modified":"2019-08-02T18:55:54","modified_gmt":"2019-08-02T10:55:54","slug":"atherton-todd%e5%8f%8d%e5%ba%94atherton-todd-reaction","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e5%8f%96%e4%bb%a3%e5%8f%8d%e5%ba%94\/2015\/02\/atherton-todd%e5%8f%8d%e5%ba%94atherton-todd-reaction.html","title":{"rendered":"Atherton-Todd\u53cd\u5e94(Atherton-Todd Reaction)"},"content":{"rendered":"<ul>\n<li><!-- Title --><strong>\u6982\u8981<\/strong><!-- Meta Tags --> <!-- Favicon --> <!-- [if lt IE 9]&gt;-->\n<p> <!-- This site uses the Yoast Google Analytics plugin v5.2.7 - Universal disabled - https:\/\/yoast.com\/wordpress\/plugins\/google-analytics\/ --><a href=\"https:\/\/apis.google.com\/_\/scs\/apps-static\/_\/js\/k=oz.gapi.zh_CN.kufRz6kljfg.O\/m=auth\/exm=plusone\/rt=j\/sv=1\/d=1\/ed=1\/am=AQ\/rs=AGLTcCOfLj9FmV5-nNKKiHhUtpdO8YFYdQ\/t=zcms\/cb=gapi.loaded_1\">https:\/\/apis.google.com\/_\/scs\/apps-static\/_\/js\/k=oz.gapi.zh_CN.kufRz6kljfg.O\/m=auth\/exm=plusone\/rt=j\/sv=1\/d=1\/ed=1\/am=AQ\/rs=AGLTcCOfLj9FmV5-nNKKiHhUtpdO8YFYdQ\/t=zcms\/cb=gapi.loaded_1<\/a><a href=\"https:\/\/apis.google.com\/_\/scs\/apps-static\/_\/js\/k=oz.gapi.zh_CN.kufRz6kljfg.O\/m=plusone\/rt=j\/sv=1\/d=1\/ed=1\/am=AQ\/rs=AGLTcCOfLj9FmV5-nNKKiHhUtpdO8YFYdQ\/t=zcms\/cb=gapi.loaded_0\">https:\/\/apis.google.com\/_\/scs\/apps-static\/_\/js\/k=oz.gapi.zh_CN.kufRz6kljfg.O\/m=plusone\/rt=j\/sv=1\/d=1\/ed=1\/am=AQ\/rs=AGLTcCOfLj9FmV5-nNKKiHhUtpdO8YFYdQ\/t=zcms\/cb=gapi.loaded_0<\/a><a href=\"https:\/\/apis.google.com\/js\/plusone.js\">https:\/\/apis.google.com\/js\/plusone.js<\/a><a href=\"http:\/\/www.gstatic.com\/pub-config\/ca-pub-3643992211965255.js\">http:\/\/www.gstatic.com\/pub-config\/ca-pub-3643992211965255.js<\/a><a href=\"\/\/connect.facebook.net\/ja_JP\/sdk.js#xfbml=1&#038;version=v2.0\">\/\/connect.facebook.net\/ja_JP\/sdk.js#xfbml=1&#038;version=v2.0<\/a><a href=\"http:\/\/www.gsbet888.com\/ga.js\">http:\/\/www.gsbet888.com\/ga.js<\/a>\/\/ <!-- \/ Yoast Google Analytics -->\/\/ <a href=\"http:\/\/www.chem-station.com\/jp\/wp-includes\/js\/jquery\/jquery.js?ver=1.11.1\">http:\/\/www.chem-station.com\/jp\/wp-includes\/js\/jquery\/jquery.js?ver=1.11.1<\/a><a href=\"http:\/\/www.chem-station.com\/jp\/wp-includes\/js\/jquery\/jquery-migrate.min.js?ver=1.2.1\">http:\/\/www.chem-station.com\/jp\/wp-includes\/js\/jquery\/jquery-migrate.min.js?ver=1.2.1<\/a>\/\/ <a href=\"http:\/\/www.chem-station.com\/jp\/wp-content\/plugins\/post-list-generator\/next-page.js?ver=1.3.0\">http:\/\/www.chem-station.com\/jp\/wp-content\/plugins\/post-list-generator\/next-page.js?ver=1.3.0<\/a><!-- This site is using AdRotate v3.11.9 Professional to display their advertisements - https:\/\/www.adrotateplugin.com\/ --> <!-- AdRotate CSS --><!-- \/AdRotate CSS -->\/\/ <a href=\"https:\/\/wprp.zemanta.com\/static\/js\/loader.js?version=3.5.3\">https:\/\/wprp.zemanta.com\/static\/js\/loader.js?version=3.5.3<\/a><!-- WordPress Popular Posts v3.2.1 -->\/\/ <!-- End WordPress Popular Posts v3.2.1 --> <!-- BEGIN: WP Social Bookmarking Light -->\u548c\u7684\u6761\u4ef6\u4e0b\u88ab\u6c27\u5316\u3002\u901a\u8fc7\u56db\u6c2f\u5316\u78b3\u7684\u4f5c\u7528\uff0c\u628aP-H\u952e\u8f6c\u6362\u6210P-Cl\u952e\u7684\u65b9\u6cd5\u3002<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n<div class=\"boxed\">\n<div class=\"content\">\n<div class=\"wrapper\">\n<div class=\"main-content-left\">\n<div class=\"main-article-content\">\n<div class=\"shortcode-content\">\n<ul>\n<li>Atherton, F. R. et al. <em>J. Chem. Soc.<\/em> <strong>1945<\/strong>, 660. DOI:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1039\/jr9450000660\" rel=\"external\" data-wpel-target=\"_blank\">10.1039\/jr9450000660<\/a><\/li>\n<li>Atherton, F. R.; Todd, A. R. <em>J. Chem. Soc.<\/em><strong>1947<\/strong>, 674. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1039\/jr9470000674\" rel=\"external\" data-wpel-target=\"_blank\">10.1039\/jr9470000674<\/a><\/li>\n<li>Georgiev, E. M.; Kaneti, J.; Troev, K.; Roundhill, D. M. <em>J. Am.\u00a0<\/em><em>Chem. Soc.<\/em><strong>1993<\/strong>, <em>115<\/em>, 10964. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1021\/ja00076a063\" rel=\"external\" data-wpel-target=\"_blank\">10.1021\/ja00076a063<\/a><\/li>\n<\/ul>\n<p>Review<\/p>\n<ul>\n<li>Jaffr\u00e8s,\u00a0P.-A<em>. et al, \u00a0Beilstein J. Org. Chem<\/em>. <strong>2014<\/strong>, <em>10<\/em>, 1166. DOI:\u00a0<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.3762\/bjoc.10.117\" rel=\"external\" data-wpel-target=\"_blank\">10.3762\/bjoc.10.117<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5f00\u53d1\u5386\u53f2<\/strong><\/li>\n<\/ul>\n<div class=\"boxed\">\n<div class=\"content\">\n<div class=\"wrapper\">\n<div class=\"main-content-left\">\n<div class=\"main-article-content\">\n<div class=\"shortcode-content\">\n<p>\u8be5\u53cd\u5e94\u662f1945\u5e74F. R. Atherton, H. T. Openshawand, and A. R. Todd\u7b49\u4eba\u7684\u4e00\u4e2a\u5076\u7136\u53d1\u73b0\u3002\u5b9e\u9645\u4e0a\uff0c\u4ed6\u4eec\u539f\u672c\u7684\u76ee\u7684\u662f\u60f3\u8981\u5728\u4e8c\u82c4\u57fa\u78f7\u9178\u916f\u7684\u56db\u6c2f\u5316\u78b3\u6eb6\u6db2\u4e2d\u52a0\u5165\u6c28\u6c34\u6eb6\u6db2\u6765\u7cbe\u5236\u5316\u5408\u7269\u3002\u4f46\u662f\u4ed6\u4eec\u60ca\u5947\u7684\u53d1\u73b0\uff0c\u6700\u540e\u751f\u6210\u4e86<em>O<\/em>,<em>O<\/em>-dibenzyl phosphoramidate\u7684\u56fa\u4f53\u3002<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/01\/atherton_todd_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-3595 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/01\/atherton_todd_2.gif\" alt=\"atherton_todd_2\" width=\"497\" height=\"76\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><!-- Title --><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n<p>\u4ee5\u4e0b\u7ed9\u51fa\u4e86\u82ef\u915a\u7c7b\u5316\u5408\u7269\u901a\u8fc7Atherton-Todd\u53cd\u5e94\uff0c\u5f97\u5230\u82b3\u57fa\u78f7\u9178\u916f\uff0c\u518d\u4e0e\u787c\u9178\u5728Ni\u50ac\u5316\u4e0b\u8fdb\u884c\u5076\u8054\u53cd\u5e94\u5f97\u5230\u8054\u82ef\u7684\u4e00\u4e2a\u5b9e\u4f8b[1]\u3002<\/p>\n<div class=\"boxed\">\n<div class=\"content\">\n<div class=\"wrapper\">\n<div class=\"main-content-left\">\n<div class=\"main-article-content\">\n<div class=\"shortcode-content\">\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/01\/2014-08-30_15-42-05.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-3597 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/01\/2014-08-30_15-42-05.png\" alt=\"2014-08-30_15-42-05\" width=\"553\" height=\"141\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/01\/2014-08-30_15-42-05.png 553w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/01\/2014-08-30_15-42-05-300x76.png 300w\" sizes=\"(max-width: 553px) 100vw, 553px\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n<div class=\"boxed\">\n<div class=\"content\">\n<div class=\"wrapper\">\n<div class=\"main-content-left\">\n<div class=\"main-article-content\">\n<div class=\"shortcode-content\">[1]\u00a0Chen H, Huang Z, Hu X, Tang G, Xu P, Zhao Y, Cheng C-H. <em>J. Org. Chem.<\/em> <strong>2011<\/strong>, 76, 2338. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1021\/jo2000034\" rel=\"external\" data-wpel-target=\"_blank\">10.1021\/jo2000034<\/a><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 https:\/\/apis.google.com\/_\/scs\/apps-static\/_\/js\/k=oz.gapi.zh_CN.kufRz6kljfg.O\/m=auth\/exm=plusone\/rt=j\/sv=1\/d=1\/ed=1\/am=AQ\/rs=AGLTcCOfLj9FmV5-nNKKiHhUtpdO8YFYdQ\/t=zcms\/cb=gapi.loaded_1https:\/\/apis.google.com\/_\/scs\/apps-static\/_\/js\/k=oz.gapi.zh_CN.kufRz6kljfg.O\/m=plusone\/rt=j\/sv=1\/d=1\/ed=1\/am=AQ\/rs=AGLTcCOfLj9FmV5-nNKKiHhUtpdO8YFYdQ\/t=zcms\/cb=gapi.loaded_0https:\/\/apis.google.com\/js\/plusone.jshttp:\/\/www.gstatic.com\/pub-config\/ca-pub-3643992211965255.js\/\/connect.facebook.net\/ja_JP\/sdk.js#xfbml=1&#038;version=v2.0http:\/\/www.gsbet888.com\/ga.js\/\/ \/\/ http:\/\/www.chem-station.com\/jp\/wp-includes\/js\/jquery\/jquery.js?ver=1.11.1http:\/\/www.chem-station.com\/jp\/wp-includes\/js\/jquery\/jquery-migrate.min.js?ver=1.2.1\/\/ http:\/\/www.chem-station.com\/jp\/wp-content\/plugins\/post-list-generator\/next-page.js?ver=1.3.0 \/\/ https:\/\/wprp.zemanta.com\/static\/js\/loader.js?version=3.5.3\/\/ \u548c\u7684\u6761\u4ef6\u4e0b\u88ab\u6c27\u5316\u3002\u901a\u8fc7\u56db\u6c2f\u5316\u78b3\u7684\u4f5c\u7528\uff0c\u628aP-H\u952e\u8f6c\u6362\u6210P-Cl\u952e\u7684\u65b9\u6cd5\u3002 &nbsp; \u57fa\u672c\u6587\u732e Atherton, F. R. et al. J. Chem. Soc. 1945, 660. DOI:10.1039\/jr9450000660 Atherton, F. R.; Todd, A. R. J. Chem. Soc.1947, 674. DOI: 10.1039\/jr9470000674 Georgiev, E. M.; Kaneti, J.; Troev, K.; Roundhill, D. M. J. Am.\u00a0Chem. Soc.1993, 115, 10964. DOI: 10.1021\/ja00076a063 Review Jaffr\u00e8s,\u00a0P.-A. et al, \u00a0Beilstein J. Org. Chem. 2014, 10, 1166. DOI:\u00a010.3762\/bjoc.10.117 &nbsp; \u5f00\u53d1\u5386\u53f2 \u8be5\u53cd\u5e94\u662f1945\u5e74F. R. Atherton, H. T. Openshawand, and A. R. Todd\u7b49\u4eba\u7684\u4e00\u4e2a\u5076\u7136\u53d1\u73b0\u3002\u5b9e\u9645\u4e0a\uff0c\u4ed6\u4eec\u539f\u672c\u7684\u76ee\u7684\u662f\u60f3\u8981\u5728\u4e8c\u82c4\u57fa\u78f7\u9178\u916f\u7684\u56db\u6c2f\u5316\u78b3\u6eb6\u6db2\u4e2d\u52a0\u5165\u6c28\u6c34\u6eb6\u6db2\u6765\u7cbe\u5236\u5316\u5408\u7269\u3002\u4f46\u662f\u4ed6\u4eec\u60ca\u5947\u7684\u53d1\u73b0\uff0c\u6700\u540e\u751f\u6210\u4e86O,O-dibenzyl phosphoramidate\u7684\u56fa\u4f53\u3002 &nbsp; \u53cd\u5e94\u673a\u7406 &nbsp; \u53cd\u5e94\u5b9e\u4f8b \u4ee5\u4e0b\u7ed9\u51fa\u4e86\u82ef\u915a\u7c7b\u5316\u5408\u7269\u901a\u8fc7Atherton-Todd\u53cd\u5e94\uff0c\u5f97\u5230\u82b3\u57fa\u78f7\u9178\u916f\uff0c\u518d\u4e0e\u787c\u9178\u5728Ni\u50ac\u5316\u4e0b\u8fdb\u884c\u5076\u8054\u53cd\u5e94\u5f97\u5230\u8054\u82ef\u7684\u4e00\u4e2a\u5b9e\u4f8b[1]\u3002 &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e [1]\u00a0Chen H, Huang Z, Hu X, Tang G, Xu P, Zhao Y, Cheng C-H. J. Org. Chem. 2011, 76, 2338. DOI: 10.1021\/jo2000034","protected":false},"author":5,"featured_media":3723,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[16],"tags":[680],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/01\/2014-08-30_16-23-34.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-VY","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3594"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=3594"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3594\/revisions"}],"predecessor-version":[{"id":28002,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3594\/revisions\/28002"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/3723"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=3594"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=3594"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=3594"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}