{"id":36064,"date":"2020-12-02T09:15:24","date_gmt":"2020-12-02T01:15:24","guid":{"rendered":"\/\/www.gsbet888.com\/?p=36064"},"modified":"2020-12-02T09:15:55","modified_gmt":"2020-12-02T01:15:55","slug":"%e5%8f%af%e8%a7%81%e5%85%89%e8%af%b1%e5%af%bc%e5%96%b9%e5%96%94%e5%95%89%e9%85%ae%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0aza-paterno-buchi%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2020\/12\/%e5%8f%af%e8%a7%81%e5%85%89%e8%af%b1%e5%af%bc%e5%96%b9%e5%96%94%e5%95%89%e9%85%ae%e7%9a%84%e4%b8%8d%e5%af%b9%e7%a7%b0aza-paterno-buchi%e5%8f%8d%e5%ba%94.html","title":{"rendered":"\u53ef\u89c1\u5149\u8bf1\u5bfc\u55b9\u5594\u5549\u916e\u7684\u4e0d\u5bf9\u79f0Aza Patern\u00f2-B\u00fcchi\u53cd\u5e94"},"content":{"rendered":"
\u8fd1\u65e5\uff0c\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66\uff08Technische Universit\u00e4t M\u00fcnchen\uff09Thorsten Bach\u8bfe\u9898\u7ec4\u5728Angew. Chem. Int. Ed.\u4e0a\u53d1\u8868\u8bba\u6587\uff0c\u4f7f\u752810 mol\uff05\u7684\u624b\u6027\u5149\u654f\u5242\uff08sensitizer\uff09\uff0c\u4e8e420 nm\u6ce2\u957f\u7167\u5c04\u4e0b\uff0c\u5b9e\u73b03-\u53d6\u4ee3\u7684\u55b9\u5594\u5549\u916e\uff08Quinoxalinones\uff09\u4e0e\u82ef\u4e59\u70ef\u7684\u4e0d\u5bf9\u79f0Aza Patern\u00f2-B\u00fcchi\u53cd\u5e94\uff0c\u83b7\u5f9714\u4e2a\u4ea7\u7269\uff0c\u4ea7\u7387\u4e3a50-99\uff05\uff0cee\u4e3a86-98\uff05\u3002\u540c\u65f6\uff0c\u4f5c\u8005\u8ba4\u4e3a\u8be5\u53cd\u5e94\u7684\u673a\u7406\u662f\u4e9a\u80fa\u5e95\u7269\u548c\u50ac\u5316\u5242\u4e4b\u95f4\u53d1\u751f\u4e86\u4e09\u91cd\u6001\u80fd\u91cf\u8f6c\u79fb\u3002<\/p>\n
Enantioselective, Visible Light-mediated Aza Patern\u00f2-B\u00fcchiReactions of Quinoxalinones
\nXinyao Li, Johannes Gro\u00dfkopf, Christian Jandl, and Thorsten Bach
\nAngew. Chem. Int. Ed. ASAP DOI:10.1002\/anie.202013276\u00a0https:\/\/doi.org\/10.1002\/ange.202013276<\/a><\/p><\/blockquote>\n
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\u6b63\u6587<\/h4>\n
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\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5927\u591a\u6570\u5149\u5316\u5b66\u5408\u6210\u7684\u6c2e\u6742\u73af\u4e01\u70f7\u5747\u4e3a\u5916\u6d88\u65cb\u6df7\u5408\u7269\uff0c\u57fa\u4e8e\u8f74\u5411\u624b\u6027\u9170\u80fa\u7684\u4f7f\u7528\u662f\u83b7\u5f97\u5bf9\u6620\u4f53\u5bcc\u96c6\u5316\u5408\u7269\u6709\u6548\u65b9\u6cd5\uff0c\u8be5\u624b\u6027\u53ef\u5728Aza Patern\u00f2-B\u00fcchi\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u8fdb\u884c\u624b\u6027\u8f6c\u79fb\u3002\u5c3d\u7ba1\u6709\u963b\u8f6c\u9009\u62e9\u6027\uff08atropselective\uff09\u7684\u5149\u5316\u5b66\u53cd\u5e94\uff0c\u4f46\u5b83\u4eec\u4f9d\u8d56\u4e8e\u624b\u6027\u5e95\u7269\u7684\u4f7f\u7528\uff0c\u4e0d\u80fd\u63d0\u4f9b\u50ac\u5316\u5bf9\u6620\u9009\u62e9\u6027\u8fc7\u7a0b\u7684\u9009\u62e9\u3002\u5728\u6b64\uff0c\u6155\u5c3c\u9ed1\u5de5\u4e1a\u5927\u5b66Thorsten Bach\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u4f7f\u7528\u624b\u6027\u4e09\u91cd\u6001\u5149\u654f\u5242\uff0c\u5b9e\u73b0\u55b9\u5594\u5549\u916e\u4e0e\u82ef\u4e59\u70ef\u7684\u4e0d\u5bf9\u79f0Aza Patern\u00f2-B\u00fcchi\u53cd\u5e94\uff0c\u4ece\u800c\u5408\u6210\u5149\u5b66\u7eaf\u7684\u624b\u6027\u6c2e\u6742\u73af\u4e01\u70f7\u5316\u5408\u7269\u3002
\n\u9996\u5148\uff0c\u4f5c\u8005\u4ee53-\u7532\u57fa-\u55b9\u5594\u5549\u916e\uff081a\uff09\u4f5c\u4e3a\u4e9a\u80fa\u7ec4\u5206\uff0c\u82ef\u4e59\u70ef\u4e3a\u70ef\u70c3\uff0c\u8fdb\u884c\u4e86\u76f8\u5173Aza Patern\u00f2-B\u00fcchi\u53cd\u5e94\u7684\u6761\u4ef6\u7b5b\u9009\uff08Table 1\uff09\u3002\u53cd\u5e94\u7684\u6700\u4f73\u6761\u4ef6\u4e3a\uff1a\u4f7f\u752810 mol%\u7684\u5149\u654f\u52422\uff0c\u4e8e420 nm\u6ce2\u957f\u8f90\u5c04\u4e0b\uff0c\u5728-25 \u2103\u7684DCE\u4e2d\u53cd\u5e94\uff0c\u5373\u53ef\u83b7\u5f9798%\u6536\u7387\u548c93% ee\u7684\u76ee\u6807\u4ea7\u72693a\u3002<\/p>\n
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\u7d27\u63a5\u7740\uff0c\u4f5c\u8005\u5bf9\u5206\u5b50\u5185\u7684Aza Patern\u00f2-B\u00fcchi\u53cd\u5e94\u8fdb\u884c\u4e86\u7814\u7a76\uff08Scheme 3\uff09\u3002\u4ee5\u5316\u5408\u72694\u4e3a\u5e95\u7269\uff0c\u4f7f\u7528\u975e\u624b\u60279-\u567b\u5428\u916e\uff08TXT\uff09\u4f5c\u4e3a\u5149\u654f\u5242\uff0c\u53ef\u751f\u6210\u9884\u671f\u7684\u56db\u73af\u4ea7\u7269rac-5\u3002\u82e5\u4f7f\u7528\u624b\u6027\u567b\u5428\u916e2\u65f6\uff0c\u5219\u4ee5\u76f8\u540c\u7684\u6536\u7387\u548c\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u83b7\u5f97\u4ea7\u72695\u3002\u5728\u8fd9\u79cd\u60c5\u51b5\u4e0b\uff0c\u5e95\u7269\u5728\u975e\u6781\u6027\u6eb6\u5242\u4e2d\u7684\u6eb6\u89e3\u5ea6\u9ad8\u4e8e\u4e0e\u55b9\u5594\u5549\u916e1\u8fdb\u884c\u5206\u5b50\u95f4\u53cd\u5e94\u3002\u56e0\u6b64\uff0c\u4f7f\u7528\u4e09\u6c1f\u7532\u82ef\u548c\u516d\u6c1f\u95f4\u4e8c\u7532\u82ef\uff08HFX\uff09\u7684\u6df7\u5408\u6eb6\u5242\uff0c\u53ef\u5728\u4f4e\u81f3-65 \u2103\u7684\u6e29\u5ea6\u4e0b\u8fdb\u884c\u8f90\u7167\u3002\u5728\u8fd9\u4e9b\u6761\u4ef6\u4e0b\uff0c\u4ea7\u72695b\u7684\u5bf9\u6620\u9009\u62e9\u6027\u5f88\u9ad8\uff0894\uff05ee\uff09\u3002\u800c\u7535\u5b50\u5bcc\u96c6\u8f83\u5c11\u7684\u672b\u7aef\u70ef\u70c34a\uff0c\u83b7\u5f97\u7684\u4ea7\u72695a\u7684\u5bf9\u6620\u9009\u62e9\u6027\u504f\u4f4e\uff0873\uff05ee\uff09\u3002<\/p>\n
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