{"id":36820,"date":"2021-01-21T08:00:18","date_gmt":"2021-01-21T00:00:18","guid":{"rendered":"\/\/www.gsbet888.com\/?p=36820"},"modified":"2021-01-19T22:27:00","modified_gmt":"2021-01-19T14:27:00","slug":"yamamoto%e9%85%af%e5%8c%96","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2021\/01\/yamamoto%e9%85%af%e5%8c%96.html","title":{"rendered":"Yamamoto\u916f\u5316"},"content":{"rendered":"

\u6982\u8981<\/strong><\/h4>\n

Yamamoto\u916f\u5316 (Yamamoto esterification)\u662f\u5728Lewis\u9178\u50ac\u5316\u5242\u4e09\u6c1f\u7532\u78fa\u9178\u94aa\u4ee5\u53ca\u5bf9\u785d\u57fa\u82ef\u7532\u9178\u9150\u5b58\u5728\u4e0b\uff0c\u7fa7\u9178\u4e0e\u4e00\u7ea7\u3001\u4e8c\u7ea7\u4ee5\u53ca\u4e09\u7ea7\u9187\u6216\u915a\u4e4b\u95f4\u8fdb\u884c\u7684\u5206\u5b50\u95f4\u6216\u5206\u5b50\u5185\u916f\u5316\u53cd\u5e94[1]-[4]<\/sup>\u3002\u8be5\u53cd\u5e94\u7531\u65e5\u672cNagoya\u5927\u5b66\u5de5\u5b66\u9662 (\u540d\u53e4\u5c4b\u5927\u5b66\u5de5\u5b66\u7814\u7a76\u79d1, Graduate School of Engineering, Nagoya University)\u7684Yamamoto (\u5c71\u672c \u5c1a,\u00a0Yamamoto Hisashi)\u7814\u7a76\u7ec4\u57281995\u5e74\u9996\u6b21\u62a5\u9053[1]<\/sup>\u3002\u540c\u65f6\uff0c\u7531\u4e8eYamamoto\u916f\u5316\u8fc7\u7a0b\u80fd\u591f\u6709\u6548\u5730\u5e94\u7528\u4e8e\u03c9-\u7f9f\u57fa\u7fa7\u9178\u5e95\u7269\u7684\u9009\u62e9\u6027\u5185\u916f\u5316\u8fc7\u7a0b\uff0c\u5e76\u53ef\u4ee5\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u5927\u73af\u5185\u916f\u7c7b\u5316\u5408\u7269\u7684\u6784\u5efa\u3002\u56e0\u6b64\uff0c\u4e0a\u8ff0\u53cd\u5e94\u53c8\u79f0\u4e3aYamamoto\u5927\u73af\u5185\u916f\u5316 (Yamamoto macrolactonization)\u3002<\/p>\n

\"\"<\/a><\/p>\n

Yamamoto\u916f\u5316\u53cd\u5e94\u5177\u6709\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0e\u4f18\u826f\u7684\u53cd\u5e94\u6536\u7387\u3002\u4e3a\u916f\u7c7b\u4e0e\u5927\u73af\u5185\u916f\u7c7b\u5206\u5b50\u7684\u6784\u5efa\u5f00\u8f9f\u4e86\u5168\u65b0\u7684\u65b9\u6cd5\u3002<\/p>\n

\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n[1] K. Ishihara, M. Rubota, H. Kurihara, H. Yamamoto, J. Am. Chem. Soc. 1995, 117, 4413. doi: 10.1021\/ja00120a030<\/a>.<\/p>\n[2] K. Ishihara, M. Rubota, H. Kurihara, H. Yamamoto, J. Am. Chem. Soc. 1995, 117, 6639. doi: 10.1021\/ja00129a047<\/a>.<\/p>\n[3] K. Ishihara, M. Kubota, H. Kurihara, H. Yamamoto, J. Org. Chem. 1996, 61, 4560. doi: 10.1021\/jo952237x<\/a>.<\/p>\n[4] A. Parenty, X. Moreau, J.-M. Campagne, Chem. Rev. 2006, 106, 911. doi: 10.1021\/cr0301402<\/a>.<\/p>\n

\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n

\"\"<\/a><\/p>\n

\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n

\u4e00\u7ea7\u9187\u7fa7\u9178\u916f\u7684\u5408\u6210[1], [3]<\/sup><\/p>\n

\"\"<\/a><\/p>\n

\u4e8c\u7ea7\u9187\u7fa7\u9178\u916f\u7684\u5408\u6210[1], [3]<\/sup><\/p>\n

\"\"<\/a><\/p>\n

\u4e09\u7ea7\u9187\u7fa7\u9178\u916f\u7684\u5408\u6210[1], [3]<\/sup><\/p>\n

\"\"<\/a><\/p>\n

\u915a\u916f\u7684\u5408\u6210[1], [3]<\/sup><\/p>\n

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\u5927\u73af\u5185\u916f\u7684\u5408\u6210[1]-[3]<\/sup><\/p>\n

\"\"<\/a><\/p>\n

\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n

\"\"\"\"<\/a><\/p>\n

\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n[1] K. Ishihara, M. Rubota, H. Kurihara, H. Yamamoto, J. Am. Chem. Soc. 1995, 117, 4413. doi: 10.1021\/ja00120a030<\/a>.<\/p>\n[2] K. Ishihara, M. Rubota, H. Kurihara, H. Yamamoto, J. Am. Chem. Soc. 1995, 117, 6639. doi: 10.1021\/ja00129a047<\/a>.<\/p>\n[3] K. Ishihara, M. Kubota, H. Kurihara, H. Yamamoto, J. Org. Chem. 1996, 61, 4560. doi: 10.1021\/jo952237x<\/a>.<\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 Yamamoto\u916f\u5316 (Yamamoto esterification)\u662f\u5728Lewis\u9178\u50ac\u5316\u5242\u4e09\u6c1f\u7532\u78fa\u9178\u94aa\u4ee5\u53ca\u5bf9\u785d\u57fa\u82ef\u7532\u9178\u9150\u5b58\u5728\u4e0b\uff0c\u7fa7\u9178\u4e0e\u4e00\u7ea7\u3001\u4e8c\u7ea7\u4ee5\u53ca\u4e09\u7ea7\u9187\u6216\u915a\u4e4b\u95f4\u8fdb\u884c\u7684\u5206\u5b50\u95f4\u6216\u5206\u5b50\u5185\u916f\u5316\u53cd\u5e94[1]-[4]\u3002\u8be5\u53cd\u5e94\u7531\u65e5\u672cNagoya\u5927\u5b66\u5de5\u5b66\u9662 (\u540d\u53e4\u5c4b\u5927\u5b66\u5de5\u5b66\u7814\u7a76\u79d1, Graduate School of Engineering, Nagoya University)\u7684Yamamoto (\u5c71\u672c \u5c1a,\u00a0Yamamoto Hisashi)\u7814\u7a76\u7ec4\u57281995\u5e74\u9996\u6b21\u62a5\u9053[1]\u3002\u540c\u65f6\uff0c\u7531\u4e8eYamamoto\u916f\u5316\u8fc7\u7a0b\u80fd\u591f\u6709\u6548\u5730\u5e94\u7528\u4e8e\u03c9-\u7f9f\u57fa\u7fa7\u9178\u5e95\u7269\u7684\u9009\u62e9\u6027\u5185\u916f\u5316\u8fc7\u7a0b\uff0c\u5e76\u53ef\u4ee5\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u5927\u73af\u5185\u916f\u7c7b\u5316\u5408\u7269\u7684\u6784\u5efa\u3002\u56e0\u6b64\uff0c\u4e0a\u8ff0\u53cd\u5e94\u53c8\u79f0\u4e3aYamamoto\u5927\u73af\u5185\u916f\u5316 (Yamamoto macrolactonization)\u3002 Yamamoto\u916f\u5316\u53cd\u5e94\u5177\u6709\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0e\u4f18\u826f\u7684\u53cd\u5e94\u6536\u7387\u3002\u4e3a\u916f\u7c7b\u4e0e\u5927\u73af\u5185\u916f\u7c7b\u5206\u5b50\u7684\u6784\u5efa\u5f00\u8f9f\u4e86\u5168\u65b0\u7684\u65b9\u6cd5\u3002 \u57fa\u672c\u6587\u732e [1] K. Ishihara, M. Rubota, H. Kurihara, H. Yamamoto, J. Am. Chem. Soc. 1995, 117, 4413. doi: 10.1021\/ja00120a030. [2] K. Ishihara, M. Rubota, H. Kurihara, H. Yamamoto, J. Am. Chem. Soc. 1995, 117, 6639. doi: 10.1021\/ja00129a047. [3] K. Ishihara, M. Kubota, H. Kurihara, H. Yamamoto, J. Org. Chem. 1996, 61, 4560. doi: 10.1021\/jo952237x. [4] A. Parenty, X. Moreau, J.-M. Campagne, Chem. Rev. 2006, 106, 911. doi: 10.1021\/cr0301402. \u53cd\u5e94\u673a\u7406 \u53cd\u5e94\u5b9e\u4f8b \u4e00\u7ea7\u9187\u7fa7\u9178\u916f\u7684\u5408\u6210[1], [3] \u4e8c\u7ea7\u9187\u7fa7\u9178\u916f\u7684\u5408\u6210[1], [3] \u4e09\u7ea7\u9187\u7fa7\u9178\u916f\u7684\u5408\u6210[1], [3] \u915a\u916f\u7684\u5408\u6210[1], [3] \u5927\u73af\u5185\u916f\u7684\u5408\u6210[1]-[3] \u5b9e\u9a8c\u6b65\u9aa4 \u53c2\u8003\u6587\u732e [1] K. Ishihara, M. Rubota, H. Kurihara, H. Yamamoto, J. Am. Chem. […]","protected":false},"author":21,"featured_media":36809,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[3292,3290,3293,3291,3294,3295],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2021\/01\/2-4.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-9zS","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/36820"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/21"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=36820"}],"version-history":[{"count":1,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/36820\/revisions"}],"predecessor-version":[{"id":36821,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/36820\/revisions\/36821"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/36809"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=36820"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=36820"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=36820"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}