cis<\/em>-1,5-\u5df1\u4e8c\u7094-3-\u70ef\u7c7b\u5316\u5408\u7269\u4f1a\u53d1\u751f\u73af\u5316\u800c\u751f\u6210\u82ef\u7684\u884d\u751f\u7269\uff0c\u8fd9\u662f\u5361\u91cc\u5947\u9709\u7d20Calicheamicin\u7b49\u70ef\u4e8c\u7094\u7c7b\u5316\u5408\u7269\u5207\u65adDNA\u65f6\u7684\u5173\u952e\u53cd\u5e94\u3002<\/p>\n\u5229\u7528\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\u5f00\u53d1C-H\u952e\u6d3b\u5316\u6cd5\u5e94<\/b><\/p>\n
1970\u5e74\u4ee3\u5f00\u59cb\u6d89\u53ca\u6709\u673a\u91d1\u5c5e\u5316\u5b66–\u73b0\u4ee3\u5316\u5b66\u4e00\u5927\u7814\u7a76\u9886\u57df\uff0c\u4ed6\u662fC-H\u952e\u6d3b\u5316\u53cd\u5e94\u4e2d\u5177\u6709\u5353\u8d8a\u8d21\u732e[1] \u7684\u6770\u51fa\u5316\u5b66\u5bb6\u4e4b\u4e00\u3002<\/p>\n
\u4e8c\u8302\u9506-\u9170\u4e9a\u80fa\u7edc\u5408\u7269\u5316\u5b66<\/b><\/p>\n
<\/p>\n
\u76f8\u5173\u6587\u732e<\/h4>\n[1] Janowicz, A. H.; Bergman R. G.\u00a0J. Am. Chem. Soc.\u00a0<\/i>1982<\/b>,\u00a0104<\/i>, 352.<\/p>\n
<\/p>\n
\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u7f57\u4f2f\u7279\u30fb\u4e54\u6cbb\u30fb\u4f2f\u683c\u66fc\uff08Robert George Bergman\u30011942\u5e745\u670823\u65e5-\uff09\u662f\u7f8e\u56fd\u6709\u673a\u5316\u5b66\u5bb6(\u5199\u771f\uff1aBergman Group)\u3002\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u6559\u6388\u3002 \u7ecf\u5386 1942 \u751f\u4e8e \u4f0a\u5229\u8bfa\u4f0a \u829d\u52a0\u54e5 1963 Carleton College \u5b66\u58eb 1966 \u5a01\u65af\u5eb7\u661f\u5dde\u5927\u5b66\u5316\u5b66\u79d1 \u535a\u58eb (Jerome A. Berson\u6559\u6388) 1966 \u54e5\u4f26\u6bd4\u4e9a\u5927\u5b66\u535a\u58eb\u7814\u7a76\u5458 (Ronald Breslow\u6559\u6388) 1968 \u52a0\u5dde\u7406\u5de5\u5b66\u9662 \u6559\u6388 1977 \u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821 \u6559\u6388 \u83b7\u5956\u7ecf\u5386 1969 Alfred P. Sloan Fellowship 1970 Camille and Henry Dreyfus Foundation Teacher-Scholar Award 1978 California Institute of Technology Student Government Award for Excellence in Teaching 1984 membership in the National Academy of Sciences and the American Academy of Arts and Sciences 1986 the second American Chemical Society Award in Organometallic Chemistry 1987 ACS Arthur C. Cope Scholar award 1994 E.O. Lawrence Award in Chemistry (U.S. Department of Energy\uff09 1996 American Chemical Society Arthur C. Cope Award 2003 ACS […]","protected":false},"author":3,"featured_media":8952,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[212],"tags":[687,686,411],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/Robert-G-Bergman-570x321.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-Xs","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3686"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=3686"}],"version-history":[{"count":4,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3686\/revisions"}],"predecessor-version":[{"id":27992,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3686\/revisions\/27992"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/8952"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=3686"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=3686"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=3686"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}