{"id":3768,"date":"2015-02-25T21:00:17","date_gmt":"2015-02-25T13:00:17","guid":{"rendered":"\/\/www.gsbet888.com\/?p=3768"},"modified":"2019-08-02T18:55:51","modified_gmt":"2019-08-02T10:55:51","slug":"post-3768","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2015\/02\/post-3768.html","title":{"rendered":"\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u7cbe\u5bc6\u5408\u6210"},"content":{"rendered":"<p>\u8fd1\u51e0\u5e74\u6765\uff0c\u88ab\u79f0\u4e3a\u300c<strong><span class=\"wp_keywordlink_affiliate\">\u8d85\u5206\u5b50\u805a\u5408\u7269<\/span>(supramolecular polymers)<\/strong>\u300d\u7684\u6750\u6599\u4f5c\u4e3a\u667a\u80fd\u8f6f\u6750\u6599\u5907\u53d7\u77a9\u76ee\u3002<\/p>\n<p>\u201c\u901a\u5e38\u7684\u201d\u805a\u5408\u7269\uff08\u9ad8\u5206\u5b50\uff09\u662f\u7531\u8bb8\u591a\u5355\u4f53\uff08momoner: \u5355\u4f53\uff09\u901a\u8fc7\u5171\u4ef7\u952e\u800c\u8fde\u63a5\u8d77\u6765\u5f62\u6210\u7684\uff0c\u4e0e\u6b64\u76f8\u5bf9\uff0c\u8d85\u5206\u5b50\u805a\u5408\u7269\u662f\u7531\u5355\u4f53\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u6216\u8005\u03c0\u2014\u03c0\u76f8\u4e92\u4f5c\u7528\u7b49\u975e\u5171\u4ef7\u952e\u800c\u7ed3\u5408\u8d77\u6765\u7684\u3002<\/p>\n<p>\u56e0\u4e3a\u662f\u975e\u5171\u4ef7\u952e\u4f5c\u7528\uff0c\u6839\u636e\u4e0d\u540c\u6761\u4ef6\u53ef\u80fd\u5bb9\u6613\u56de\u5230\u5355\u4f53\uff0c\u4f46\u662f\u901a\u8fc7\u4e00\u4e9b\u4e0d\u53ef\u9006\u7684\u8fc7\u7a0b\uff0c\u662f\u53ef\u4ee5\u7b80\u5355\u5408\u6210\u6709\u79e9\u5e8f\u7684\u805a\u5408\u7269\u6750\u6599\u7684\u3002\u56e0\u4e3a\u8fd9\u4e9b\u5355\u4f53\u6240\u5177\u6709\u7684\u81ea\u53d1\u5f62\u6210\u975e\u5171\u4ef7\u952e\u7684\u6027\u8d28\u4f7f\u5f97\u4ed6\u4eec\u81ea\u5df1\u7ec4\u88c5\u8d77\u6765\uff0c\u53ea\u9700\u8981\u5728\u9002\u5f53\u6761\u4ef6\u4e0b\u6df7\u5408\uff0c\u4fbf\u53ef\u5f62\u6210\u805a\u5408\u7269\u4e86\u3002<\/p>\n<p>\u5177\u6709\u8fd9\u6837\u72ec\u7279\u7684\u6027\u8d28\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\uff0c\u5728\u5408\u6210\u4e0a\u7684\u95ee\u9898\u4e4b\u4e00\u662f\uff0c\u957f\u5ea6\u8fd8\u6709\u5206\u5b50\u91cf\u7684\u63a7\u5236\u7cbe\u5bc6\u5408\u6210\u6bd4\u8f83\u56f0\u96be\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u524d\u4e00\u9635\u3001\u5c31\u8fd9\u4e2a\u95ee\u9898\uff0c\u79d1\u5b66\u5bb6\u4eec\u53d1\u73b0\u4e86\u4e00\u7c7b\u65b0\u7684\u7cbe\u5bc6\u5408\u6210\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u65b9\u6cd5\uff0c\u89e3\u51b3\u4e86\u8fd9\u4e00\u56f0\u6270\u3002\u662f\u7531\u7406\u7814<a href=\"http:\/\/www.riken.jp\/research\/labs\/cems\/supramol_chem\/emerg_soft_matter_funct\/\">\u521b\u53d1<\/a><a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/www.riken.jp\/research\/labs\/cems\/supramol_chem\/emerg_soft_matter_funct\/\" rel=\"external\" data-wpel-target=\"_blank\">\u7269\u6027\u79d1\u5b66\u7814\u7a76\u4e2d\u5fc3\u521b\u53d1\u8f6f\u6027\u7269\u8d28\u673a\u80fd\u7814\u7a76\u7ec4<\/a>\u7684\u5bae\u5cf6\u5927\u543e\u7814\u7a76\u5458\u3001<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/www.chem-station.com\/chemist-db\/archives\/2008\/09\/-takuzo-aida.php\" rel=\"external\" data-wpel-target=\"_blank\">\u76f8\u7530\u5353\u4e09<\/a>\u7814\u7a76\u7ec4\u957f\uff08\u4e1c\u5927\u9662\u5de5\u30fb\u6559\u6388\uff09\u548c\u59dc\u5fd7\u4ea8\u7814\u7a76\u751f\uff08\u6771\u5927\u9662\u5de5\uff09\u3001\u962a\u5927\u5de5\u5b66\u7814\u7a76\u79d1\u7684<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/www.chem-station.com\/chemist-db\/archives\/2009\/01\/-yoshihisa-inoue.php\" rel=\"external\" data-wpel-target=\"_blank\">\u4e95\u4e0a\u4f73\u4e45<\/a>\u6559\u6388\u7b49\u4eba\u5408\u4f5c\u7814\u7a76\u4e0b\u3001\u4e8eScience\u6742\u5fd7\u4e0a\u62a5\u9053\u4e86\u8fd9\u4e00\u7814\u7a76\u3002<\/p>\n<p>&nbsp;<\/p>\n<blockquote><p>\u201cA rational strategy for the realization of chain-growth supramolecular polymerization\u201d<\/p>\n<p>Kang, J.; Miyajima, D.; Mori, T.; Inoue, Y.; Itoh, Y.; Aida, T\u00a0<em>Science<\/em>\u00a0<strong>2015<\/strong>,\u00a0<em>347<\/em>, 646. DOI:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/www.sciencemag.org\/content\/347\/6222\/646\" rel=\"external\" data-wpel-target=\"_blank\">10.1126\/science.aaa4249<\/a><\/p><\/blockquote>\n<p>&nbsp;<\/p>\n<p>\u90a3\u4e48\u3001\u7a76\u7adf\u5982\u4f55\u80fd\u591f\u63a7\u5236\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u7ed3\u6784\uff0c\u4e0b\u9762\u5c31\u8fd9\u4e00\u95ee\u9898\u7684\u89e3\u51b3\u529e\u6cd5\u6765\u505a\u4ee5\u8bf4\u660e\u3002\u53e6\u5916\u8fd9\u4e00\u6b21\uff0c\u4e5f\u987a\u4fbf\u5bf9\u8fd9\u7bc7science\u8bba\u6587\u7684\u4ee3\u8868\u4f5c\u8005\u4e4b\u4e00\u5bae\u5cf6\u535a\u58eb\u8fdb\u884c\u4e86\u7279\u522b\u4e13\u8bbf\uff0c\u4ece\u4e2d\u83b7\u5f97\u7684\u4e00\u4e9b\u8bc4\u8bba\uff0c\u5c31\u653e\u5728\u4e00\u8d77\u7ed9\u5927\u5bb6\u4ecb\u7ecd\u4e00\u4e0b\u5427\u3002<br \/>\n<span id=\"more-27054\"><\/span><\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li>\u8d85\u5206\u5b50\u805a\u5408\u7684\u7cbe\u5bc6\u5236\u5fa1\u7684\u95ee\u9898\u70b9<\/li>\n<\/ul>\n<p>\u5171\u4ef7\u952e\u7684\u805a\u5408\u7269\u5408\u6210\uff0c\u9700\u8981\u805a\u5408\u5f15\u53d1\u5242\uff0c\u53cd\u5e94\u4f4d\u70b9\u901a\u5e38\u4ec5\u9650\u805a\u5408\u7269\u94fe\u7684\u672b\u7aef\uff0c\u6240\u7528\u7684\u5355\u4f53\u91cf\u7684\u591a\u5c11\u5c31\u80fd\u591f\u51b3\u5b9a\u805a\u5408\u7269\u7684\u957f\u5ea6\u53ca\u5206\u5b50\u91cf\uff08<strong>\u94fe\u589e\u957f\u805a\u5408: chain-growth polymerization<\/strong>\uff09\u3002<\/p>\n<p>\u800c\u8d85\u5206\u5b50\u805a\u5408\u7269\u662f\u5404\u4e2a\u5355\u4f53\u952e\u76f8\u4e92\u4f5c\u7528\u5f00\u59cb\u5f62\u6210\u9aa8\u67b6\uff0c\u4e5f\u5c31\u662f\u8bf4\u5355\u4f53\u672c\u8eab\u662f\u805a\u5408\u5f15\u53d1\u5242\uff0c\u5404\u5904\u5f15\u53d1\u805a\u5408\u4f1a\u540c\u65f6\u8fdb\u884c\uff0c\u4f7f\u5f97\u805a\u5408\u7269\u7684\u957f\u5ea6\u53d8\u5f02\uff08\u56fe1\uff09\u3002\u56e0\u6b64\uff0c\u8d85\u5206\u5b50\u7684\u957f\u5ea6\u4ee5\u53ca\u5927\u5c0f\u7b49\u7cbe\u5bc6\u5236\u5fa1\u5408\u6210\u53d8\u5f97\u56f0\u96be\u3002<\/p>\n<p>\u6700\u8fd1\u3001\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u957f\u5ea6\u53ca\u5206\u5b50\u91cf\u5236\u5fa1\u5408\u6210\u65b9\u6cd5\u4e5f\u6709\u624b\u6cd5\u4e5f\u6709\u62a5\u9053\uff0c\u4e3b\u8981\u662f\u901a\u8fc7\u63a7\u5236\u6e29\u5ea6\u7b49\u7cbe\u5bc6\u5236\u5fa1\u6765\u5b9e\u73b0\u7684[1]\u3002<\/p>\n<div id=\"attachment_3874\" style=\"width: 950px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d1.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3874\" class=\"wp-image-3874 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d1.png\" alt=\"\u672a\u547d\u540d\" width=\"940\" height=\"291\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d1.png 940w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d1-300x93.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d1-680x211.png 680w\" sizes=\"(max-width: 940px) 100vw, 940px\" \/><\/a><p id=\"caption-attachment-3874\" class=\"wp-caption-text\">\u56fe1 \u5229\u7528\u805a\u5408\u5f15\u53d1\u5242\u7684\u5171\u4ef7\u952e\u805a\u5408\u7269\u7684\u7cbe\u5bc6\u805a\u5408\uff08\u4e0a\uff09\u4e0e\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u805a\u5408 \uff08\u4e0b\uff09\u7684\u6982\u7565\u56fe<\/p><\/div>\n<p>&nbsp;<\/p>\n<ul>\n<li>\u00a0\u8bbe\u8ba1\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u7cbe\u5bc6\u805a\u5408<\/li>\n<\/ul>\n<p>\u6784\u9020\u5236\u5fa1\u7684\u5173\u952e\u4e4b\u5904\u548c\u901a\u5e38\u7684\u805a\u5408\u7269\u7684\u94fe\u589e\u957f\u805a\u5408\u76f8\u540c\u3002<\/p>\n<p><strong>\u901a\u8fc7\u7814\u7a76\u300c\u805a\u5408\u5f15\u53d1\u5242\u548c\u5355\u4f53\u300d\u7684\u5173\u7cfb\u6765\u5b8c\u6210\u7cbe\u5bc6\u805a\u5408\uff0c<\/strong>\u8fd9\u6837\u7684\u60f3\u6cd5\u3002<\/p>\n<p>\u4f5c\u8005\u4eec\u7528\u4e86\u542b\u6709\u4e94\u4e2a\u9170\u80fa\u57fa\u7684\u786b\u70f7\u57fa\u4fa7\u94fe\u7684\u7897\u72b6\u70ef\u70c3\u7c7b\u4f3c\u7269\u3001\u8fd9\u4e2a\u5355\u4f53\u7684\u4fa7\u94fe\u4e0a\u542b\u6709\u7684\u9170\u80fa\u57fa\u56e2\u80fd\u591f\u5f62\u6210\u5206\u5b50\u5185\u7684\u73af\u72b6\u6c22\u952e\uff0c\u80fd\u591f\u751f\u6210\u5355\u4e00\u7684\u7a33\u5b9a\u7684\u5355\u4f53\u5e76\u80fd\u591f\u6291\u5236\u5206\u5b50\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u4ece\u800c\u9632\u6b62\u4e86\u5355\u4f53\u95f4\u7684\u81ea\u805a\u3002[2] \u4e5f\u5c31\u662f\u8bf4\u548c\u901a\u5e38\u7684\u805a\u5408\u7269\u5408\u6210\u7684\u5355\u4f53\u662f\u76f8\u540c\u7684\u72b6\u6001\uff0c\u88ab\u79f0\u4e3a\u201c\u4e9a\u7a33\u6001\u5355\u4f53\u201d\uff08\u56fe2\u4e0a\uff09\u3002<\/p>\n<p>\u300c\u4e9a\u7a33\u6001\u5355\u4f53\u300d\u7684\u805a\u5408\u9700\u8981\u805a\u5408\u5f15\u53d1\u5242\uff0c\u8fd9\u6b21\uff0c\u4f5c\u8005\u8bbe\u8ba1\u4e86\u5355\u4f53\u4fa7\u94feN\u539f\u5b50\u7532\u57fa\u5316\u7684\u5206\u5b50\u4f5c\u4e3a\u805a\u5408\u7269\u5f15\u53d1\u5242\u3002\uff08\u56fe2\u4e0b\uff09\u3002<\/p>\n<div id=\"attachment_3873\" style=\"width: 950px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3873\" class=\"wp-image-3873 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d.png\" alt=\"\" width=\"940\" height=\"448\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d.png 940w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d-300x143.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d-680x324.png 680w\" sizes=\"(max-width: 940px) 100vw, 940px\" \/><\/a><p id=\"caption-attachment-3873\" class=\"wp-caption-text\">\u56fe2. 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id=\"attachment_3871\" style=\"width: 950px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/07ff1981fd6abe164c8891acc71cb3662.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3871\" class=\"wp-image-3871 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/07ff1981fd6abe164c8891acc71cb3662.png\" alt=\"07ff1981fd6abe164c8891acc71cb366\" width=\"940\" height=\"510\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/07ff1981fd6abe164c8891acc71cb3662.png 940w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/07ff1981fd6abe164c8891acc71cb3662-300x163.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/07ff1981fd6abe164c8891acc71cb3662-680x369.png 680w\" sizes=\"(max-width: 940px) 100vw, 940px\" \/><\/a><p id=\"caption-attachment-3871\" class=\"wp-caption-text\">\u56fe3. 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href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/3a4f695a458cb0ac0aceaa2eb13ac2dd1.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3872\" class=\"wp-image-3872 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/3a4f695a458cb0ac0aceaa2eb13ac2dd1.png\" alt=\"3a4f695a458cb0ac0aceaa2eb13ac2dd\" width=\"1185\" height=\"489\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/3a4f695a458cb0ac0aceaa2eb13ac2dd1.png 1185w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/3a4f695a458cb0ac0aceaa2eb13ac2dd1-300x124.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/3a4f695a458cb0ac0aceaa2eb13ac2dd1-680x281.png 680w\" sizes=\"(max-width: 1185px) 100vw, 1185px\" \/><\/a><p id=\"caption-attachment-3872\" class=\"wp-caption-text\">\u56fe4. 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id=\"attachment_3876\" style=\"width: 953px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d2.png\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-3876\" class=\"wp-image-3876 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d2.png\" alt=\"\u672a\u547d\u540d\" width=\"943\" height=\"612\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d2.png 943w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d2-300x195.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d2-680x441.png 680w\" sizes=\"(max-width: 943px) 100vw, 943px\" \/><\/a><p id=\"caption-attachment-3876\" class=\"wp-caption-text\">\u56fe5. 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href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-3877 aligncenter\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d3.png\" alt=\"\u672a\u547d\u540d\" width=\"767\" height=\"381\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d3.png 767w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d3-300x149.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/02\/\u672a\u547d\u540d3-680x338.png 680w\" sizes=\"(max-width: 767px) 100vw, 767px\" \/><\/a><\/p>\n<p>\u300c<strong>\u7cbe\u5bc6\u5236\u5fa1\u8d85\u5206\u5b50\u805a\u5408\u300d\u2014\u2014\u662f\u6211\u4eec\u4e00\u76f4\u4ee5\u6765\u7684\u68a6\u60f3<\/strong><\/p>\n<p>\u8fd9\u4e2a\u7814\u7a76\u4e2d\u6700\u96be\u5f97\u5e94\u8be5\u5c31\u662f\u5982\u4f55\u8bc1\u660e\u662f\u300c<strong>\u5206\u5b50\u91cf\u5747\u4e00\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269<\/strong>\u300d\u3002\u5728\u8fd9\u4ee5\u524d\uff0c\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u5927\u5c0f\u7684\u8bc4\u4ef7\u8868\u5f81\u3001\u90fd\u662f\u901a\u8fc7\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u8fd8\u6709\u539f\u5b50\u529b\u663e\u5fae\u955c\uff08AFM\uff09\u76f4\u63a5\u8ba1\u7b97\u7684\u3002\u4f46\u662f\uff0c\u901a\u8fc7\u8fd9\u79cd\u65b9\u6cd5\u5f97\u5230\u7684\u4fe1\u606f\u53ea\u662f\u975e\u5e38\u5c40\u9650\u7684\u4e00\u90e8\u5206\u805a\u5408\u7269\u7684\u4fe1\u606f\uff0c\u6211\u4eec\u5f53\u65f6\u53ea\u80fd\u901a\u8fc7\u5206\u5b50\uff08\u7a7a\u95f4\uff09\u6392\u963b\u8272\u8c31\uff08SEC\uff09\u6765\u89e3\u6790\uff0c\u8fd9\u662f\u8bc4\u4f30\u9ad8\u5206\u5b50\u7684\u6807\u51c6\u65b9\u6cd5\uff0c\u76f8\u6bd4\u8d77\u80fd\u6d88\u9664\u968f\u610f\u6027\uff0c\u5b83\u7684\u4f18\u70b9\u66f4\u5728\u4e8e\u80fd\u9002\u7528\u4e8e\u591a\u79cd\u805a\u5408\u7269\u7684\u8bc4\u4ef7\u3002<\/p>\n<p>\u53e6\u4e00\u65b9\u9762\uff0c\u8fd9\u4e2a\u6d4b\u5b9a\u7684\u95ee\u9898\u5728\u4e8e\uff0c\u7528\u4e8e\u5206\u6790\u7684\u8272\u8c31\u67f1\u5185\u96be\u514d\u4f1a\u53d1\u751f\u8d85\u5206\u5b50\u805a\u5408\u7269\u94fe\u7684\u5207\u65ad\u3001\u5206\u89e3\u7b49\u73b0\u8c61\u3002\u56e0\u4e3a\u8d85\u5206\u5b50\u805a\u5408\u7269\u662f\u5355\u4f53\u4e4b\u95f4\u7684\u975e\u5171\u4ef7\u952e\u7ed3\u5408\uff0c\u5b83\u7684\u7a33\u5b9a\u6027\u4e0e\u6eb6\u5242\u7684\u7c7b\u578b\u6709\u5f88\u5927\u5173\u7cfb\uff0c\u9057\u61be\u7684\u662fSEC\u6240\u7528\u7684\u6eb6\u5242\u4f1a\u4f7f\u5927\u591a\u8d85\u5206\u5b50\u805a\u5408\u7269\u5206\u89e3\u6210\u5355\u4f53\u3002\u6211\u4eec\u53ea\u80fd\u5bf9\u8272\u8c31\u67f1\u7684\u79cd\u7c7b\uff0c\u6eb6\u5242\u7ec4\u6210\u3001\u6d41\u901f\u3001\u5b9e\u9a8c\u6e29\u5ea6\u7b49\u8fdb\u884c\u5f7b\u5e95\u7684\u4f18\u5316\uff0c\u5e76\u4e14\u91cd\u590d\u6027\u8f83\u597d\u7684\u805a\u5408\u7269\u624d\u80fd\u901a\u8fc7SEC\u89e3\u6790\uff0c\u4ec5\u4ec5\u4f18\u5316\u5206\u79bb\u6761\u4ef6\u5c31\u5f97\u82b1\u81f3\u5c11\u4e24\u5468\uff0c\u800c\u4e14\u8fd9\u4e2aSEC\u6d4b\u5b9a\u518d\u52a0\u4e0a\u52a8\u6001\u5149\u6563\u5c04\uff08DLS\uff09\u6d4b\u5b9a\uff0c\u5706\u4e8c\u8272\u6027\uff08CD\uff09\u7b49\u7b49\u7ec4\u5408\u8d77\u6765\u7684\u8bc1\u636e\uff0c\u624d\u8ba9\u6211\u4eec\u6709\u8db3\u591f\u7684\u81ea\u4fe1\u628a\u8bba\u6587\u6295\u51fa\u53bb\u4e86\uff0c\u53ef\u662f\u5ba1\u7a3f\u7f16\u8f91\u4e2d\u7684\u4e00\u4f4d\u8981\u6c42\u6211\u4eec\u505a\u8fdb\u4e00\u6b65\u5206\u6790\u3002<\/p>\n<p>\u62ff\u5230\u8fd9\u4e2a\u610f\u89c1\u540e\u53ea\u80fd\u63a5\u53d7\u73b0\u5b9e\uff0c\u5e76\u4e14\u9759\u4e0b\u6765\u60f3\u60f3\uff0cSEC\u6e2c\u5b9a\u30fbDLS\u6e2c\u5b9a\u30fbCD\u6e2c\u5b9a\u3001\u8fd9\u4e9b\u90fd\u662f\u95f4\u63a5\u7684\u8bc4\u4ef7\u65b9\u6cd5\uff0c\u679c\u7136\u6211\u4eec\u8fd8\u662f\u662f\u9700\u8981\u663e\u5fae\u955c\u7ed9\u51fa\u7684\u8d85\u5206\u5b50\u94fe\u957f\u77ed\u8868\u5f81\u7684\u76f4\u63a5\u8bc1\u636e\uff0c\u5c31\u8fd9\u6837\u91cd\u65b0\u6765\u4e86\u4e00\u904d\u3002\u5728\u6295\u7a3f\u7684\u8bba\u6587\u4e2d\u628a\u539f\u5b50\u529b\u663e\u5fae\u955c\u7684\u89e3\u6790\u7ed3\u679c\u52a0\u4e0a\uff0c\u8fd8\u6709NMR\u8868\u5f81\u7684\u6269\u6563\u7cfb\u6570\u7684\u7ed3\u679c\u4e5f\u52a0\u4e0a\uff0c\u867d\u7136\u5728\u8ffd\u52a0\u5b9e\u9a8c\u8865\u5145\u6570\u636e\u82b1\u4e86\u4e00\u4e9b\u65f6\u95f4\uff0c\u4f46\u662f\u8ba9\u6211\u4eec\u7684\u7814\u7a76\uff08\u8bba\u6587\uff09\u7684\u8d28\u91cf\u53c8\u4e0a\u5347\u4e86\u4e00\u4e2a\u9ad8\u5ea6\uff0c\u73b0\u5728\u7684\u8bdd\uff0c\u53cd\u5012\u8fd8\u8981\u591a\u8c22\u5f53\u65f6\u7ed9\u6211\u4eec\u63d0\u8fd9\u610f\u89c1\u7684\u90a3\u4f4d\u5ba1\u7a3f\u7f16\u8f91\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u8fd9\u4e2a\u7814\u7a76\u603b\u4f53\u8bf4\u6765\u8fd8\u662f\u8fdb\u5c55\u633a\u5feb\u7684\uff0c\u8fd9\u7bc7\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u59dc\u5fd7\u4ea8\u540c\u5b66\u529f\u52b3\u975e\u5e38\u5927\uff0c\u5982\u679c\u6ca1\u6709\u4ed6\uff0c\u8fd9\u4e2a\u7814\u7a76\u7684\u5f00\u59cb\u53ef\u80fd\u90fd\u4e0d\u53ef\u80fd\u3002\u59dc\uff08\u540c\u5b66\uff09\u662f\u975e\u5e38\u4f18\u79c0\u7684\u5927\u5b66\u9662\u751f\uff0c\u5229\u7528\u8ba1\u7b97\u673a\u79d1\u5b66\u5bf9\u5206\u5b50\u95f4\u76f8\u4e92\u4f5c\u7528\u7684\u89e3\u6790\uff1b\u53e6\u5916\u89c2\u6d4b\u5230\u7684\u5706\u4e8c\u8272\u6027\u7684\u7406\u8bba\u89e3\u6790\u5219\u5f97\u5230\u4e86\u5927\u962a\u5927\u5b66\u7684\u68ee\u3000\u76f4\u8001\u5e08\u3001\u4e95\u4e0a\u4f73\u4e45\u8001\u5e08\u3001\u8fd8\u6709\u4e1c\u4eac\u5927\u5b66\u4f0a\u85e4\u5584\u5149\u52a9\u6559\u5f88\u5927\u7684\u5e2e\u52a9\uff0c\u501f\u6b64\u673a\u4f1a\u611f\u8c22\u4ed6\u4eec\u7684\u8d21\u732e\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u8d85\u5206\u5b50\u805a\u5408\u7684\u7cbe\u5bc6\u5236\u5fa1\u5408\u6210\u5b9e\u73b0\u4e86\u4f1a\u600e\u4e48\u6837\u5462\uff1f\u8fd9\u662f\u6211\u4eec\u591a\u5e74\u4ee5\u6765\u4e00\u76f4\u601d\u8003\u7684\u95ee\u9898\uff0c\u6709\u8bb8\u8bb8\u591a\u591a\u597d\u7684\u60f3\u6cd5\uff0c\u4e5f\u51fa\u4e86\u4e00\u4e9b\u6bd4\u8f83\u6709\u610f\u601d\u7684\u6210\u679c\u3002\u628a\u8d85\u5206\u5b50\u5316\u5b66\u7684\u4f18\u70b9\u8fd8\u6709\u9ad8\u5206\u5b50\u5316\u5b66\u81f3\u4eca\u4ee5\u6765\u6240\u79ef\u7d2f\u7684\u77e5\u8bc6\u76f8\u7ed3\u5408\uff0c\u5e0c\u671b\u80fd\u591f\u5728\u65b0\u7684\u5316\u5b66\u9886\u57df\u6709\u6240\u7a81\u7834\u3002<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p>\u6700\u540e\u4e86\uff0c\u518d\u63d0\u4e00\u4e0b\u6211\u4eec\u7814\u7a76\u6240\u7269\u8d28\u6750\u6599\u7814\u7a76\u673a\u6784\uff08NIMS\uff09\u7684\u6749\u5b89\u548c\u61b2\u4e3b\u4efb\u7814\u7a76\u5458\u30fb\u7af9\u5185\u6b63\u4e4b\u7ec4\u957f\u7b49\u4eba\u53bb\u5e74\u5728\u8d85\u5206\u5b50\u805a\u5408\u7269\u957f\u5ea6\u5236\u5fa1\u5408\u6210\u7684\u7814\u7a76\uff08\u53d1\u8868\u5728Nature Chemistry\u00a0<em>Nat. Chem.<\/em><strong>6<\/strong>, 188\u2013195, 2014\uff09\u3002\u4ed6\u4eec\u662f\u5de7\u5999\u5229\u7528\u4e86\u901f\u5ea6\u8bba\u7684\u751f\u6210\u7269\u548c\u70ed\u529b\u5b66\u751f\u6210\u7269\u7684\u7a33\u5b9a\u6027\u6765\u7814\u7a76\uff0c\u4e5f\u662f\u4e00\u7bc7\u975e\u5e38\u6709\u610f\u601d\u7684\u8bba\u6587\u3002\u548c\u6211\u4eec\u7684\u8bba\u6587\u505a\u4e2a\u6bd4\u8f83\u7684\u8bdd\uff0c\u4ed6\u4eec\u66f4\u63a5\u8fd1\u8d85\u5206\u5b50\u5316\u5b66<strong>\u7684\u89c6<\/strong>\u70b9\u6765\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u800c\u6211\u4eec\u5219\u66f4\u4fa7\u91cd\u9ad8\u5206\u5b50\u5316\u5b66\u7684\u89d2\u5ea6\uff0c\u8fd8\u662f\u6709\u6240\u533a\u522b\u7684\u3002<\/p>\n<p style=\"text-align: right\"><span class=\"wp_keywordlink\"><a class=\"ext-link ext-icon-2\" title=\"\u7406\u5316\u5b66\u7814\u7a76\u6240\" href=\"http:\/\/www.riken.jp\/\" rel=\"external\" data-wpel-target=\"_blank\">\u7406\u5316\u5b66\u7814\u7a76\u6240<\/a><\/span>\u3000\u5bae\u5cf6\u5927\u543e<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li>\u53c2\u8003\u6587\u732e<\/li>\n<\/ul>\n[1] Ogi, S.; Sugiyasu, K.; Manna, S.; Samitsu, S.; Takeuchi, M.<em>\u00a0Nat. Chem.\u00a0<\/em><strong>2014<\/strong>,\u00a0<em>6<\/em>, 188. DOI:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/www.nature.com\/nchem\/journal\/v6\/n3\/full\/nchem.1849.html\" rel=\"external\" data-wpel-target=\"_blank\">10.1038\/NCHEM.1849<\/a>\u00a0[2] Kang, J.; Miyajima, D.; Itoh, Y.; Mori, T.; Tanaka, H.; Yamauchi, M.; Inoue, Y.; Harada, S.; Aida, T.<em>J. Am. Chem. Soc.<\/em><strong>2014<\/strong>,\u00a0<em>136<\/em>, 10640. DOI:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja505941b\" rel=\"external\" data-wpel-target=\"_blank\">10.1021\/ja505941b<\/a><\/p><\/blockquote>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u8fd1\u51e0\u5e74\u6765\uff0c\u88ab\u79f0\u4e3a\u300c\u8d85\u5206\u5b50\u805a\u5408\u7269(supramolecular polymers)\u300d\u7684\u6750\u6599\u4f5c\u4e3a\u667a\u80fd\u8f6f\u6750\u6599\u5907\u53d7\u77a9\u76ee\u3002 \u201c\u901a\u5e38\u7684\u201d\u805a\u5408\u7269\uff08\u9ad8\u5206\u5b50\uff09\u662f\u7531\u8bb8\u591a\u5355\u4f53\uff08momoner: \u5355\u4f53\uff09\u901a\u8fc7\u5171\u4ef7\u952e\u800c\u8fde\u63a5\u8d77\u6765\u5f62\u6210\u7684\uff0c\u4e0e\u6b64\u76f8\u5bf9\uff0c\u8d85\u5206\u5b50\u805a\u5408\u7269\u662f\u7531\u5355\u4f53\u901a\u8fc7\u6c22\u952e\u4f5c\u7528\u6216\u8005\u03c0\u2014\u03c0\u76f8\u4e92\u4f5c\u7528\u7b49\u975e\u5171\u4ef7\u952e\u800c\u7ed3\u5408\u8d77\u6765\u7684\u3002 \u56e0\u4e3a\u662f\u975e\u5171\u4ef7\u952e\u4f5c\u7528\uff0c\u6839\u636e\u4e0d\u540c\u6761\u4ef6\u53ef\u80fd\u5bb9\u6613\u56de\u5230\u5355\u4f53\uff0c\u4f46\u662f\u901a\u8fc7\u4e00\u4e9b\u4e0d\u53ef\u9006\u7684\u8fc7\u7a0b\uff0c\u662f\u53ef\u4ee5\u7b80\u5355\u5408\u6210\u6709\u79e9\u5e8f\u7684\u805a\u5408\u7269\u6750\u6599\u7684\u3002\u56e0\u4e3a\u8fd9\u4e9b\u5355\u4f53\u6240\u5177\u6709\u7684\u81ea\u53d1\u5f62\u6210\u975e\u5171\u4ef7\u952e\u7684\u6027\u8d28\u4f7f\u5f97\u4ed6\u4eec\u81ea\u5df1\u7ec4\u88c5\u8d77\u6765\uff0c\u53ea\u9700\u8981\u5728\u9002\u5f53\u6761\u4ef6\u4e0b\u6df7\u5408\uff0c\u4fbf\u53ef\u5f62\u6210\u805a\u5408\u7269\u4e86\u3002 \u5177\u6709\u8fd9\u6837\u72ec\u7279\u7684\u6027\u8d28\u7684\u8d85\u5206\u5b50\u805a\u5408\u7269\uff0c\u5728\u5408\u6210\u4e0a\u7684\u95ee\u9898\u4e4b\u4e00\u662f\uff0c\u957f\u5ea6\u8fd8\u6709\u5206\u5b50\u91cf\u7684\u63a7\u5236\u7cbe\u5bc6\u5408\u6210\u6bd4\u8f83\u56f0\u96be\u3002 &nbsp; \u524d\u4e00\u9635\u3001\u5c31\u8fd9\u4e2a\u95ee\u9898\uff0c\u79d1\u5b66\u5bb6\u4eec\u53d1\u73b0\u4e86\u4e00\u7c7b\u65b0\u7684\u7cbe\u5bc6\u5408\u6210\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u65b9\u6cd5\uff0c\u89e3\u51b3\u4e86\u8fd9\u4e00\u56f0\u6270\u3002\u662f\u7531\u7406\u7814\u521b\u53d1\u7269\u6027\u79d1\u5b66\u7814\u7a76\u4e2d\u5fc3\u521b\u53d1\u8f6f\u6027\u7269\u8d28\u673a\u80fd\u7814\u7a76\u7ec4\u7684\u5bae\u5cf6\u5927\u543e\u7814\u7a76\u5458\u3001\u76f8\u7530\u5353\u4e09\u7814\u7a76\u7ec4\u957f\uff08\u4e1c\u5927\u9662\u5de5\u30fb\u6559\u6388\uff09\u548c\u59dc\u5fd7\u4ea8\u7814\u7a76\u751f\uff08\u6771\u5927\u9662\u5de5\uff09\u3001\u962a\u5927\u5de5\u5b66\u7814\u7a76\u79d1\u7684\u4e95\u4e0a\u4f73\u4e45\u6559\u6388\u7b49\u4eba\u5408\u4f5c\u7814\u7a76\u4e0b\u3001\u4e8eScience\u6742\u5fd7\u4e0a\u62a5\u9053\u4e86\u8fd9\u4e00\u7814\u7a76\u3002 &nbsp; \u201cA rational strategy for the realization of chain-growth supramolecular polymerization\u201d Kang, J.; Miyajima, D.; Mori, T.; Inoue, Y.; Itoh, Y.; Aida, T\u00a0Science\u00a02015,\u00a0347, 646. DOI:10.1126\/science.aaa4249 &nbsp; \u90a3\u4e48\u3001\u7a76\u7adf\u5982\u4f55\u80fd\u591f\u63a7\u5236\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u7ed3\u6784\uff0c\u4e0b\u9762\u5c31\u8fd9\u4e00\u95ee\u9898\u7684\u89e3\u51b3\u529e\u6cd5\u6765\u505a\u4ee5\u8bf4\u660e\u3002\u53e6\u5916\u8fd9\u4e00\u6b21\uff0c\u4e5f\u987a\u4fbf\u5bf9\u8fd9\u7bc7science\u8bba\u6587\u7684\u4ee3\u8868\u4f5c\u8005\u4e4b\u4e00\u5bae\u5cf6\u535a\u58eb\u8fdb\u884c\u4e86\u7279\u522b\u4e13\u8bbf\uff0c\u4ece\u4e2d\u83b7\u5f97\u7684\u4e00\u4e9b\u8bc4\u8bba\uff0c\u5c31\u653e\u5728\u4e00\u8d77\u7ed9\u5927\u5bb6\u4ecb\u7ecd\u4e00\u4e0b\u5427\u3002 &nbsp; \u8d85\u5206\u5b50\u805a\u5408\u7684\u7cbe\u5bc6\u5236\u5fa1\u7684\u95ee\u9898\u70b9 \u5171\u4ef7\u952e\u7684\u805a\u5408\u7269\u5408\u6210\uff0c\u9700\u8981\u805a\u5408\u5f15\u53d1\u5242\uff0c\u53cd\u5e94\u4f4d\u70b9\u901a\u5e38\u4ec5\u9650\u805a\u5408\u7269\u94fe\u7684\u672b\u7aef\uff0c\u6240\u7528\u7684\u5355\u4f53\u91cf\u7684\u591a\u5c11\u5c31\u80fd\u591f\u51b3\u5b9a\u805a\u5408\u7269\u7684\u957f\u5ea6\u53ca\u5206\u5b50\u91cf\uff08\u94fe\u589e\u957f\u805a\u5408: chain-growth polymerization\uff09\u3002 \u800c\u8d85\u5206\u5b50\u805a\u5408\u7269\u662f\u5404\u4e2a\u5355\u4f53\u952e\u76f8\u4e92\u4f5c\u7528\u5f00\u59cb\u5f62\u6210\u9aa8\u67b6\uff0c\u4e5f\u5c31\u662f\u8bf4\u5355\u4f53\u672c\u8eab\u662f\u805a\u5408\u5f15\u53d1\u5242\uff0c\u5404\u5904\u5f15\u53d1\u805a\u5408\u4f1a\u540c\u65f6\u8fdb\u884c\uff0c\u4f7f\u5f97\u805a\u5408\u7269\u7684\u957f\u5ea6\u53d8\u5f02\uff08\u56fe1\uff09\u3002\u56e0\u6b64\uff0c\u8d85\u5206\u5b50\u7684\u957f\u5ea6\u4ee5\u53ca\u5927\u5c0f\u7b49\u7cbe\u5bc6\u5236\u5fa1\u5408\u6210\u53d8\u5f97\u56f0\u96be\u3002 \u6700\u8fd1\u3001\u8d85\u5206\u5b50\u805a\u5408\u7269\u7684\u957f\u5ea6\u53ca\u5206\u5b50\u91cf\u5236\u5fa1\u5408\u6210\u65b9\u6cd5\u4e5f\u6709\u624b\u6cd5\u4e5f\u6709\u62a5\u9053\uff0c\u4e3b\u8981\u662f\u901a\u8fc7\u63a7\u5236\u6e29\u5ea6\u7b49\u7cbe\u5bc6\u5236\u5fa1\u6765\u5b9e\u73b0\u7684[1]\u3002 &nbsp; 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