{"id":38746,"date":"2021-05-26T08:00:34","date_gmt":"2021-05-26T00:00:34","guid":{"rendered":"\/\/www.gsbet888.com\/?p=38746"},"modified":"2021-05-24T15:26:25","modified_gmt":"2021-05-24T07:26:25","slug":"%e5%93%88%e5%b0%94%e6%bb%a8%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e5%a4%8f%e5%90%be%e7%82%af%e5%92%8c%e6%9d%a8%e8%b6%85%e8%af%be%e9%a2%98%e7%bb%84org-lett-%ef%bc%9a-%e9%86%9b%e4%b8%8e%e6%b0%b0%e5%9f%ba","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2021\/05\/%e5%93%88%e5%b0%94%e6%bb%a8%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e5%a4%8f%e5%90%be%e7%82%af%e5%92%8c%e6%9d%a8%e8%b6%85%e8%af%be%e9%a2%98%e7%bb%84org-lett-%ef%bc%9a-%e9%86%9b%e4%b8%8e%e6%b0%b0%e5%9f%ba.html","title":{"rendered":"\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u590f\u543e\u70af\u548c\u6768\u8d85\u8bfe\u9898\u7ec4Org. Lett.\uff1a \u919b\u4e0e\u6c30\u57fa\u82b3\u70c3\u7684\u7535\u5316\u5b66\u8fd8\u539f\u82b3\u57fa\u5316\u53cd\u5e94"},"content":{"rendered":"

\u672c\u6587\u4f5c\u8005\uff1a\u6749\u6749<\/strong><\/p>\n

\u5bfc\u8bfb<\/h4>\n

\u8fd1\u65e5\uff0c\u54c8\u5c14\u6ee8\u5de5\u4e1a\u5927\u5b66\u590f\u543e\u70af\u548c\u6768\u8d85\u8bfe\u9898\u7ec4\u5408\u4f5c\u5728Org<\/em>anic<\/em>\u00a0Lett<\/em>ers<\/em>\u4e0a\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u8102\u80aa\u65cf\/\u82b3\u9999\u65cf\u919b\u4ee5\u53ca\uff08\u6742\uff09\u82b3\u9999\u65cf\u916e\u4e0e\u6c30\u57fa\uff08\u6742\uff09\u82b3\u70c3\u7684\u7535\u5316\u5b66\u8fd8\u539f\u82b3\u57fa\u5316\u53cd\u5e94\uff0c\u4ece\u800c\u4ee5\u4e2d\u7b49\u5230\u826f\u597d\u7684\u6536\u7387\u83b7\u5f97\u76f8\u5e94\u7684\u4ef2\u9187\u548c\u53d4\u9187\u884d\u751f\u7269\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u53cd\u5e94\u8fc7\u7a0b\u6d89\u53ca\u9634\u6781\u8fd8\u539f\u4ea7\u751f\u7fb0\u81ea\u7531\u57fa\uff08ketyl radical\uff09\u4e0e\u6742\u82b3\u57fa\u81ea\u7531\u57fa\u9634\u79bb\u5b50\u7684\u5076\u8054\u8fc7\u7a0b\u3002<\/p>\n

Reductive Arylation of Aliphatic and Aromatic Aldehydes with\u00a0Cyanoarenes by Electrolysis for the Synthesis of Alcohols<\/p>\n

Xiao Zhang, Chao Yang,* Han Gao, Lei Wang, Lin Guo, and Wujiong Xia*<\/p>\n

Org. Lett.<\/em>\u00a0ASAP DOI:10.1021\/acs.orglett.1c00920<\/u><\/a><\/p><\/blockquote>\n

\"\"<\/a><\/p>\n

\u6b63\u6587<\/h4>\n

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\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

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\"\"<\/a><\/p>\n

\u4e3a\u4e86\u8fdb\u4e00\u6b65\u4e86\u89e3\u53cd\u5e94\u7684\u673a\u7406\uff0c\u4f5c\u8005\u8fdb\u884c\u76f8\u5173\u7684\u5bf9\u7167\u5b9e\u9a8c\uff08Scheme 4\uff09\u3002\u9996\u5148\uff0c\u5728\u5faa\u73af\u4f0f\u5b89\u6cd5\uff08CV\uff09\u4e2d\uff0c\u919b\u5e95\u7269\u548c2a<\/strong>\u90fd\u53ef\u80fd\u53d1\u751f\u9634\u6781\u8fd8\u539f\uff0c\u4ece\u800c\u751f\u6210\u76f8\u5e94\u7684\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\u3002\u968f\u540e\uff0c\u5728\u65e0\u9694\u819c\u7535\u89e3\u5b9e\u9a8c\uff08divided-cell experiment\uff09\u4e2d\uff0c\u5c06DABCO\u7f6e\u4e8e\u9633\u6781\uff0c\u4ece\u800c\u83b7\u5f9762\uff05\u6536\u7387\u7684\u76ee\u6807\u4ea7\u72693a<\/strong>\uff08Scheme 4a\uff09\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u77f3\u58a8\u68d2\u9634\u6781\u5468\u56f4\u53d1\u751f\u4e86\u7535\u5316\u5b66\u82b3\u57fa\u5316\u4f5c\u7528\uff0cDABCO\u4ec5\u7528\u4f5c\u727a\u7272\u8fd8\u539f\u5242\uff0c\u800c\u4e0d\u662fPCET\uff08\u8d28\u5b50\u8026\u5408\u7535\u5b50\u8f6c\u79fb\uff09\uff09\u8bd5\u5242\u3002\u6b64\u5916\uff0c\u4e3a\u4e86\u8fdb\u4e00\u6b65\u4e86\u89e3\u53cd\u5e94\u4e2d\u81ea\u7531\u57fa\u7684\u8d77\u6e90\uff0c\u4f5c\u8005\u5728\u6052\u6d41\u4e0b\u4e8e0.1 M n<\/em>Bu4<\/sub>NBF4<\/sub>\/DMF\u4e2d\u5bf9\u620a\u919b\uff081g<\/strong>\uff09\u8fdb\u884c\u4e86\u7535\u5b50\u987a\u78c1\u5171\u632f\uff08EPR\uff09\u5b9e\u9a8c\uff08Scheme 4b\uff09\u3002\u7531\u4e8e\u8102\u80aa\u65cf\u7fb0\u81ea\u7531\u57fa\u7684\u5bff\u547d\u4e0d\u591f\u957f\uff0c\u5728\u620a\u919b\u4e2d\u672a\u68c0\u6d4b\u5230\u660e\u663e\u7684\u4fe1\u53f7\u3002\u5f53\u5c06N<\/em>-\u4e9a\u82c4\u57fa-\u53d4\u4e01\u80faN<\/em>-\u6c27\u5316\u7269\uff08PBN\uff09\u5f15\u5165\u5b9e\u9a8c\u4e2d\uff0c\u901a\u8fc7\u5b9e\u9a8c\u5bf9\u6bd4\uff0c\u5728\u620a\u919b\u548cPBN\u7684\u6df7\u5408\u7269\u4e2d\u89c2\u5bdf\u5230\u4fe1\u53f7\u7684\u5feb\u901f\u589e\u957f\u3002\u8fd9\u4e9b\u7ed3\u679c\u8868\u660e\uff0c\u620a\u919b\u53ef\u5728\u9634\u6781\u88ab\u8fd8\u539f\u4ee5\u4ea7\u751f\u5173\u952e\u7684\u8102\u80aa\u65cf\u7fb0\u81ea\u7531\u57fa\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u6700\u540e\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u53ef\u80fd\u7684\u53cd\u5e94\u673a\u7406\uff08Scheme 5\uff09\u3002\u9996\u5148\uff0c\u7fb0\u57fa\u5316\u5408\u72691<\/strong>\u901a\u8fc7\u9634\u6781\u7535\u89e3\u8fdb\u884c\u5355\u7535\u5b50\u8f6c\u79fb\uff08SET\uff09\u8fc7\u7a0b\uff0c\u5f62\u6210\u5173\u952e\u7684\u7fb0\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53I<\/strong>\u30024-\u6c30\u57fa\u5421\u5576\uff082a<\/strong>\uff09\u7684\u9634\u6781\u8fd8\u539f\u751f\u6210\u81ea\u7531\u57fa\u9634\u79bb\u5b50II<\/strong>\u3002\u968f\u540e\uff0c\u7ecf\u81ea\u7531\u57fa-\u81ea\u7531\u57fa\u5076\u8054\u751f\u6210\u9634\u79bb\u5b50\u4e2d\u95f4\u4f53III<\/strong>\u3002\u6700\u540e\uff0c\u8148\u57fa\u9634\u79bb\u5b50\u7ecf\u6d88\u9664\uff0c\u53ef\u751f\u6210\u6240\u9700\u7684\u5076\u8054\u4ea7\u72693<\/strong>\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u603b\u7ed3<\/h4>\n

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