{"id":3949,"date":"2015-03-06T10:18:07","date_gmt":"2015-03-06T02:18:07","guid":{"rendered":"\/\/www.gsbet888.com\/?p=3949"},"modified":"2019-08-02T18:55:49","modified_gmt":"2019-08-02T10:55:49","slug":"%e5%b7%b4%e9%a1%bf-%e5%87%af%e6%b4%9b%e6%a0%bc%e5%8f%8d%e5%ba%94barton-kellogg-reaction","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2015\/03\/%e5%b7%b4%e9%a1%bf-%e5%87%af%e6%b4%9b%e6%a0%bc%e5%8f%8d%e5%ba%94barton-kellogg-reaction.html","title":{"rendered":"\u5df4\u987f\u2013\u51ef\u6d1b\u683c\u53cd\u5e94(Barton-Kellogg Reaction)"},"content":{"rendered":"<ul>\n<li><strong>\u6982\u8981<\/strong><\/li>\n<\/ul>\n<p>\u91cd\u6c2e\u5316\u5408\u7269\u4e0e\u786b\u916e\u53cd\u5e94\u5f97\u5230\u591a\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210\u624b\u6cd5\u3002\u8be5\u53cd\u5e94\u4e0e<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/www.chem-station.com\/odos\/2009\/06\/mcmurry-mcmurry-coupling.html\" rel=\"external\" data-wpel-target=\"_blank\">McMurry<\/a>\u53cd\u5e94\u4e0d\u540c\u7684\u662f\uff0c\u8be5\u53cd\u5e94\u53ef\u4ee5\u5bf9\u4e0d\u540c\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u5e95\u7269\u4e4b\u95f4\u8fdb\u884c\u5076\u8054\u3002<\/p>\n<p>\u91cd\u6c2e\u5316\u5408\u7269\u53ef\u7531\u916e\u4e0e\u80bc\u7f29\u5408\u4ea7\u751f\u7684\u8159\u518d\u88ab\u6c27\u5316\u5f97\u5230\u3002\u786b\u916e\u7ec4\u5206\u53ef\u7531\u916e\u4e0e\u4e94\u786b\u5316\u4e8c\u78f7\u4f5c\u7528\u5236\u5907\u3002\u53cd\u5e94\u4e2d\u95f4\u4f53\u73af\u786b\u4e59\u70f7\u7684\u8131\u786b\u53ef\u901a\u8fc7\u8bb8\u591a\u81a6\u7c7b\uff08\u5982\u4e09\u82ef\u57fa\u81a6\uff09\u6765\u5b8c\u6210\u3002\u4e5f\u53ef\u4ee5\u7528\u94dc\u7c89\u6765\u8fdb\u884c\u8131\u786b\u3002<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u57fa\u672c\u6587\u732e<\/strong><\/li>\n<\/ul>\n<ul>\n<li>Staudinger, H.; Siegwart, J. <em>Helv Chim. Acta<\/em> <strong>1920<\/strong>, <em>3<\/em>, 833. doi:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1002\/hlca.19200030178\" rel=\"external\" data-wpel-target=\"_blank\">10.1002\/hlca.19200030178<\/a><\/li>\n<li>Barton, D. H. R.; Willis, B. J. <em>J. Chem. Soc. D<\/em> <strong>1970<\/strong>, 1225. doi:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1039\/C29700001225\" rel=\"external\" data-wpel-target=\"_blank\">10.1039\/C29700001225<\/a><\/li>\n<li>Kellogg, R. M.; Wassenaar, S. <em>Tetrahedron Lett.<\/em> <strong>1970<\/strong>, <em>11<\/em>, 1987. doi:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1016\/S0040-4039(01)98134-1\" rel=\"external\" data-wpel-target=\"_blank\">10.1016\/S0040-4039(01)98134-1<\/a><\/li>\n<li>Kellogg, R. M. <em>Tetrahedron<\/em> <strong>1976<\/strong>, <em>32<\/em>, 2165. doi:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1016\/0040-4020(76)85131-9\" rel=\"external\" data-wpel-target=\"_blank\">10.1016\/0040-4020(76)85131-9<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/li>\n<\/ul>\n<p>\u91cd\u6c2e\u5316\u5408\u7269\u4f5c\u4e3a1,3-\u5076\u6781\u4f53\uff0c\u4e0e\u786b\u916e\u53d1\u751f1,3-\u5076\u6781\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u751f\u6210\u567b\u4e8c\u5511\u5549\u73af\u7cfb\u3002\u567b\u4e8c\u5511\u5549\u73af\u4e0d\u7a33\u5b9a\uff0c\u653e\u51fa\u6c2e\u6c14\uff0c\u751f\u6210\u786b\u7fb0\u57fa\u53f6\u7acb\u5fb7\uff0c\u518d\u5206\u5b50\u5185\u73af\u5316\u4e3a\u7a33\u5b9a\u7684\u73af\u786b\u4e59\u70f7\u73af\u7cfb\u3002\u4e09\u82ef\u57fa\u81a6\u5bf9\u73af\u786b\u4e59\u70f7\u8fdb\u884c\u4eb2\u6838\u8fdb\u653b\uff0c\u5f00\u73af\uff0c\u7136\u540e\u4ea7\u751f\u7684\u70f7\u786b\u8d1f\u79bb\u5b50\u518d\u5bf9\u78f7\u539f\u5b50\u884c\u5206\u5b50\u5185\u4eb2\u6838\u8fdb\u653b\uff0c\u4ea7\u751f\u7c7b\u4f3c\u4e8e Wittig\u53cd\u5e94\u7684\u56db\u5143\u786b\u78f7\u6742\u73af\u4e01\u70f7\u4e2d\u95f4\u4f53\uff0c\u5b83\u6700\u540e\u53d1\u751f\u6d88\u9664\u5f97\u5230\u4e09\u82ef\u57fa\u786b\u78f7\u548c\u4ea7\u7269\u70ef\u70c3\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/03\/barton_kellogg_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-3951 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/03\/barton_kellogg_2.gif\" alt=\"barton_kellogg_2\" width=\"488\" height=\"107\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/li>\n<\/ul>\n<p>\u8be5\u53cd\u5e94\u53ef\u4ee5\u7528\u4e8e\u6bd4\u8f83\u626d\u66f2\u7684\u591a\u53d6\u4ee3\u70ef\u70c3\u3002\u4ee5\u4e0b\u7ed9\u51fa\u4e86\u4e00\u4e2a\u5408\u6210\u7684\u5e94\u7528\u5b9e\u4f8b\u3002[1]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/03\/barton_kellogg_3.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-3952 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/03\/barton_kellogg_3.gif\" alt=\"barton_kellogg_3\" width=\"545\" height=\"275\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<ul>\n<li><strong>\u53c2\u8003\u6587\u732e<\/strong><\/li>\n<\/ul>\n[1] Ruangsupapichat, N.; Pollard, M. M.; Harutyunyan, S. R.; Feringa, B. L. <em>Nat. Chem.<\/em> <strong>2011<\/strong>, <em>3<\/em>, 53. doi:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1038\/nchem.872\" rel=\"external\" data-wpel-target=\"_blank\">10.1038\/nchem.872<\/a> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u91cd\u6c2e\u5316\u5408\u7269\u4e0e\u786b\u916e\u53cd\u5e94\u5f97\u5230\u591a\u53d6\u4ee3\u70ef\u70c3\u7684\u5408\u6210\u624b\u6cd5\u3002\u8be5\u53cd\u5e94\u4e0eMcMurry\u53cd\u5e94\u4e0d\u540c\u7684\u662f\uff0c\u8be5\u53cd\u5e94\u53ef\u4ee5\u5bf9\u4e0d\u540c\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u5e95\u7269\u4e4b\u95f4\u8fdb\u884c\u5076\u8054\u3002 \u91cd\u6c2e\u5316\u5408\u7269\u53ef\u7531\u916e\u4e0e\u80bc\u7f29\u5408\u4ea7\u751f\u7684\u8159\u518d\u88ab\u6c27\u5316\u5f97\u5230\u3002\u786b\u916e\u7ec4\u5206\u53ef\u7531\u916e\u4e0e\u4e94\u786b\u5316\u4e8c\u78f7\u4f5c\u7528\u5236\u5907\u3002\u53cd\u5e94\u4e2d\u95f4\u4f53\u73af\u786b\u4e59\u70f7\u7684\u8131\u786b\u53ef\u901a\u8fc7\u8bb8\u591a\u81a6\u7c7b\uff08\u5982\u4e09\u82ef\u57fa\u81a6\uff09\u6765\u5b8c\u6210\u3002\u4e5f\u53ef\u4ee5\u7528\u94dc\u7c89\u6765\u8fdb\u884c\u8131\u786b\u3002 &nbsp; \u57fa\u672c\u6587\u732e Staudinger, H.; Siegwart, J. Helv Chim. Acta 1920, 3, 833. doi:10.1002\/hlca.19200030178 Barton, D. H. R.; Willis, B. J. J. Chem. Soc. D 1970, 1225. doi:10.1039\/C29700001225 Kellogg, R. M.; Wassenaar, S. Tetrahedron Lett. 1970, 11, 1987. doi:10.1016\/S0040-4039(01)98134-1 Kellogg, R. M. Tetrahedron 1976, 32, 2165. doi:10.1016\/0040-4020(76)85131-9 &nbsp; \u53cd\u5e94\u673a\u7406 \u91cd\u6c2e\u5316\u5408\u7269\u4f5c\u4e3a1,3-\u5076\u6781\u4f53\uff0c\u4e0e\u786b\u916e\u53d1\u751f1,3-\u5076\u6781\u73af\u52a0\u6210\u53cd\u5e94\uff0c\u751f\u6210\u567b\u4e8c\u5511\u5549\u73af\u7cfb\u3002\u567b\u4e8c\u5511\u5549\u73af\u4e0d\u7a33\u5b9a\uff0c\u653e\u51fa\u6c2e\u6c14\uff0c\u751f\u6210\u786b\u7fb0\u57fa\u53f6\u7acb\u5fb7\uff0c\u518d\u5206\u5b50\u5185\u73af\u5316\u4e3a\u7a33\u5b9a\u7684\u73af\u786b\u4e59\u70f7\u73af\u7cfb\u3002\u4e09\u82ef\u57fa\u81a6\u5bf9\u73af\u786b\u4e59\u70f7\u8fdb\u884c\u4eb2\u6838\u8fdb\u653b\uff0c\u5f00\u73af\uff0c\u7136\u540e\u4ea7\u751f\u7684\u70f7\u786b\u8d1f\u79bb\u5b50\u518d\u5bf9\u78f7\u539f\u5b50\u884c\u5206\u5b50\u5185\u4eb2\u6838\u8fdb\u653b\uff0c\u4ea7\u751f\u7c7b\u4f3c\u4e8e Wittig\u53cd\u5e94\u7684\u56db\u5143\u786b\u78f7\u6742\u73af\u4e01\u70f7\u4e2d\u95f4\u4f53\uff0c\u5b83\u6700\u540e\u53d1\u751f\u6d88\u9664\u5f97\u5230\u4e09\u82ef\u57fa\u786b\u78f7\u548c\u4ea7\u7269\u70ef\u70c3\u3002 &nbsp; &nbsp; \u53cd\u5e94\u5b9e\u4f8b \u8be5\u53cd\u5e94\u53ef\u4ee5\u7528\u4e8e\u6bd4\u8f83\u626d\u66f2\u7684\u591a\u53d6\u4ee3\u70ef\u70c3\u3002\u4ee5\u4e0b\u7ed9\u51fa\u4e86\u4e00\u4e2a\u5408\u6210\u7684\u5e94\u7528\u5b9e\u4f8b\u3002[1] &nbsp; &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e [1] Ruangsupapichat, N.; Pollard, M. M.; Harutyunyan, S. R.; Feringa, B. L. Nat. Chem. 2011, 3, 53. doi:10.1038\/nchem.872","protected":false},"author":5,"featured_media":3950,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[374,134,717],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/03\/2014-10-25_23-28-08.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-11H","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3949"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=3949"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3949\/revisions"}],"predecessor-version":[{"id":27980,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/3949\/revisions\/27980"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/3950"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=3949"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=3949"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=3949"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}