\u5bfc\u8bed<\/h4>\n

\u8102\u80aa\u9187\u7684\u9009\u62e9\u6027\u50ac\u5316\u78b3\u6c22\u952e\u5b98\u80fd\u56e2\u53ef\u4ee5\u5c06\u5e7f\u6cdb\u5b58\u5728\u7684\u9187\u7c7b\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u5177\u6709\u9ad8\u9644\u52a0\u503c\u7684\u590d\u6742\u7ed3\u6784\u5206\u5b50\uff0c\u56e0\u6b64\u8be5\u7c7b\u8f6c\u5316\u4e5f\u5f15\u8d77\u4e86\u5316\u5b66\u5bb6\u4eec\u7684\u5173\u6ce8\u3002\u901a\u8fc7\u6c27\u81ea\u7531\u57fa\u7684\u751f\u6210\u4ee5\u53ca1,5-<\/span>\u6c22\u8fc1\u79fb\u5b9e\u73b0\u9187\u7c7b\u5316\u5408\u7269\u7684\u8fdc\u7aef\u78b3\u6c22\u952e\u5b98\u80fd\u56e2\u5316\uff0c\u662f\u5176\u4e2d\u5f88\u7ecf\u5178\u7684\u65b9\u6cd5\u3002\u5e38\u7528\u7684\u7b56\u7565\u662f\u5c06\u9187\u7c7b\u5316\u5408\u7269\u8f6c\u5316\u6210\u4e3aO-N<\/span>\u5316\u5408\u7269\u3001\u9ad8\u4ef7\u5364\u3001\u8fc7\u6c27\u5316\u7269\u3001\u70f7\u6c27\u57fa\u94c5\u7b49\uff0c\u4ee5\u5b9e\u73b0\u9187\u7684\u201c\u6d3b\u5316\u201d\u4fc3\u8fdb\u6c27\u81ea\u7531\u57fa\u7684\u751f\u6210\u3002\u82cf\u5dde\u5927\u5b66\u6731\u6668\u6559\u6388\u3001\u5357\u5f00\u5927\u5b66\u9648\u5f13\u6559\u6388\u3001\u5317\u4eac\u5927\u5b66\u7126\u5b81\u6559\u6388\u3001\uff08\u4ece\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u8fc1\u5165\uff09\u4e0a\u6d77\u6709\u673a\u6240\u5de6\u667a\u4f1f\u6559\u6388\u7b49\u4eba\u901a\u8fc7\u4f7f\u7528Ir<\/span>\u3001Ru<\/span>\u3001Ag<\/span>\u3001Ce<\/span>\u7b49\u50ac\u5316\u5242\u4fc3\u8fdb\u6e38\u79bb\u9187\u751f\u6210\u6c27\u81ea\u7531\u57fa\u53ca1,5-<\/span>\u6c22\u8fc1\u79fb\uff0c\u5b9e\u73b0\u4e86\u6e38\u79bb\u9187\u7684\u8fdc\u7aef\u78b3\u6c22\u952e\u5b98\u80fd\u56e2\u5316\u8f6c\u5316\u3002\u5982\u4f55\u4f7f\u7528\u5ec9\u4ef7\u91d1\u5c5e\u4f5c\u50ac\u5316\u5242\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u8fd1\u65e5\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u7684\u65b0\u65b9\u6cd5\uff0c\u8102\u80aa\u9187\u5728\u94c1\u7684\u50ac\u5316\u4e0b\u751f\u6210\u6c27\u81ea\u7531\u57fa\u3001\u968f\u540e1,5-<\/span>\u6c22\u8fc1\u79fb\u3001\u5b98\u80fd\u56e2\u5316\uff0c\u8fdb\u800c\u5b9e\u73b0\u4e86\u5e7f\u6cdb\u6613\u5f97\u7684\u8102\u80aa\u9187\u7684\u8fdc\u7aef\u80fa\u5316\u53cd\u5e94\u3002<\/p>\n

<\/a>

\u56fe1. \u6e38\u79bb\u8102\u80aa\u9187\u7684\u8fdc\u7a0b\u5b98\u80fd\u56e2\u6982\u5ff5<\/p><\/div>\n

Iron-Catalyzed Photoinduced Remote C(sp^{3<\/sup>)\u2500H Amination of Free Alcohols.<\/span><\/p>\n}

\n

\n

Ni Xiong<\/span>,\u00a0<\/span>Yang Li<\/span>*<\/strong>,\u00a0and\u00a0<\/span>Rong Zeng<\/span>*<\/strong><\/p>\n<\/div>\n<\/div>\n

Organic Letters \u00a0ASAP \u00a0<\/span><\/i>DOI:\u00a010.1021\/acs.orglett.1c03488<\/span><\/a><\/p><\/blockquote>\n

\u6b63\u6587<\/h4>\n

\u8fd1\u5e74\u6765\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u56f4\u7ed5\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u53cd\u5e94\u5c55\u5f00\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u5de5\u4f5c\u3002\u8be5\u8bfe\u9898\u7ec4\u524d\u671f\u66fe\u5f00\u53d1\u4e86\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u4e0b\u4e8c\u7ea7\u6216\u4e09\u7ea7\u9187\u7684\u6e29\u548c\u6c27\u5316\u5236\u5907\u82b3\u9999\u9178\uff08Org. Lett<\/em>.2021<\/strong>,23<\/em>, 2915-2920<\/a>\uff09\u3001\u70f7\u57fa\u82ef\u3001\u805a\u82ef\u4e59\u70ef\u6c27\u5316\u5236\u5907\u82ef\u7532\u9178\uff08Chin. J. Chem.<\/em>\u00a02021<\/strong>,\u00a039<\/em>, 3225-3230<\/a>\uff09\u7b49\u3002\u57fa\u4e8e\u5bf9\u524d\u671f\u7814\u7a76\u5de5\u4f5c\u7684\u6df1\u5165\u63a2\u7d22\uff0c\u8fd1\u65e5\uff0c\u8be5\u56e2\u961f\u53c8\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u6e38\u79bb\u8102\u80aa\u9187\u7684\u9009\u62e9\u6027\u78b3\u6c22\u952e\u80fa\u5316\u53cd\u5e94\u6765\u6784\u5efa\u590d\u6742\u5206\u5b50\u7684\u65b0\u65b9\u6cd5\u3002<\/p>\n

<\/a>

\u56fe2. \u94c1\u5149\u50ac\u5316\u6e38\u79bb\u8102\u80aa\u9187\u7684\u8fdc\u7a0b\u80fa\u5316\uff08\u56fe\u7247\u6765\u6e90:Org. Lett.<\/em>\uff09<\/p><\/div>\n

<\/p>\n

\u8be5\u53cd\u5e94\u5177\u6709\u826f\u597d\u7684\u6b65\u9aa4\u3001\u539f\u5b50\u7ecf\u6d4e\u6027\u53ca\u5e7f\u6cdb\u7684\u5e95\u7269\u8303\u56f4\u3002\u5728\u53ef\u89c1\u5149\u4fc3\u8fdb\u94c1\u50ac\u5316\u4e0b\uff0c\u4e0d\u540c\u7684\u6e38\u79bb\u8102\u80aa\u9187\u90fd\u53ef\u4ee5\u5b9e\u73b0\u8fdc\u7aef\u80fa\u5316\u53cd\u5e94\uff0c\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\u5730\u5f97\u5230\u76f8\u5e94\u7684\u6c28\u57fa\u9187\u7c7b\u884d\u751f\u7269\uff08\u56fe3\uff09\u3002<\/p>\n

<\/a>

\u56fe3. \u8102\u80aa\u9187\u5e95\u7269\u8303\u56f4\uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09<\/p><\/div>\n

<\/p>\n

\u6b64\u5916\uff0c\u4e0d\u540c\u7684\u5076\u6c2e\u7c7b\u5316\u5408\u7269\u4e5f\u53ef\u4ee5\u53c2\u4e0e\u53cd\u5e94\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u6c28\u57fa\u9187\u7c7b\u4ea7\u7269\uff08\u56fe4\uff09\u3002<\/p>\n

<\/a>

\u56fe4. \u5076\u6c2e\u5e95\u7269\u8303\u56f4\uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09<\/p><\/div>\n

<\/p>\n

\u901a\u8fc7\u7b80\u5355\u7684\u53cd\u5e94\u673a\u7406\u63a2\u7d22\uff0c\u4f5c\u8005\u4e5f\u63d0\u51fa\u4e86\u8be5\u53cd\u5e94\u7684\u50ac\u5316\u5faa\u73af\uff08\u56fe5<\/span>\uff09\u3002\u8be5\u53cd\u5e94\u7531\u4e09\u4ef7\u94c1\u50ac\u5316\u5242Fe(III)<\/span>\u548c\u8102\u80aa\u9187\u4e4b\u95f4\u7684\u5149\u8bf1\u5bfc\u7535\u8377\u8f6c\u79fb\u6765\u5f15\u53d1\uff0c\u901a\u8fc7\u5f62\u6210Fe(II)<\/span>\u7269\u79cd\u4fc3\u4f7f\u6c27\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53Int-O<\/span><\/b>\u7684\u751f\u6210\u3002\u5206\u5b50\u51851,5-<\/span>\u6c22\u8f6c\u79fb\uff08HAT<\/span>\uff09\u3001\u63a5\u7740\u4e0eDBAD<\/span>\u53d1\u751f\u81ea\u7531\u57fa\u52a0\u6210\u4ea7\u751f\u6c2e\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53Int-N<\/span><\/b>\u3002\u6700\u540e\uff0c\u5355\u7535\u5b50\u8f6c\u79fb\u751f\u6210\u80fa\u5316\u4ea7\u7269\u7684\u751f\u6210\u4ee5\u53ca\u518d\u751fFe(III)<\/span>\u50ac\u5316\u5242\u3002\u6bd4\u8f83\u9057\u61be\u7684\u662f\uff0c\u5bf9\u4e8e\u6c27\u81ea\u7531\u57fa\u7684\u751f\u6210\u673a\u5236\uff0c\u662f\u901a\u8fc7\u6c2f\u81ea\u7531\u57fa\u8fd8\u662fLMCT<\/span>\u7684\u8fc7\u7a0b\uff0c\u4f5c\u8005\u5e76\u6ca1\u6709\u7ed9\u51fa\u7ed3\u8bba\u3002\u8be5\u5b9e\u9a8c\u5ba4\u4ecd\u5728\u8fdb\u884c\u66f4\u6df1\u5165\u7684\u673a\u7406\u7814\u7a76\u3002<\/p>\n

<\/a>

\u56fe5. \u50ac\u5316\u5faa\u73af\uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09<\/p><\/div>\n

<\/p>\n

\u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u901a\u8fc7\u514b\u7ea7\u653e\u5927\u53cd\u5e94\u3001\u9ebb\u6c27\u5316\u53cd\u5e94\u3001Appel\u53cd\u5e94\u4ee5\u53caTsCl\u4fdd\u62a4\u53cd\u5e94\u7b49\u8fdb\u884c\u4e86\u63a2\u7d22\uff08\u56fe6\uff09\uff0c\u521d\u6b65\u5c55\u793a\u51fa\u4e86\u53cd\u5e94\u7684\u5b9e\u7528\u6027\uff0c\u4e5f\u4e3a\u540e\u7eed\u7684\u8f6c\u5316\u63d0\u4f9b\u4e86\u57fa\u7840\u3002<\/p>\n

<\/a>

\u56fe6. \u4ea7\u7269\u884d\u751f\u5316\uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09<\/p><\/div>\n

\u603b\u7ed3<\/h4>\n

\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u94c1\u57fa\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u7cfb\u7edf\u5b9e\u73b0\u4e86\u6e38\u79bb\u8102\u80aa\u9187\u7684\u8fdc\u7a0bC-H\u952e\u80fa\u5316\u3002\u8be5\u53cd\u5e94\u4f7f\u7528\u5ec9\u4ef7\u6613\u5f97\u7684\u94c1\u50ac\u5316\u5242\uff08FeCl_{3<\/sub>\uff09\uff0c\u7ed3\u5408\u53ef\u89c1\u5149\u50ac\u5316\uff0c\u5177\u6709\u826f\u597d\u7684\u5e95\u7269\u8010\u53d7\u6027\u3001\u6761\u4ef6\u6e29\u548c\u3001\u7eff\u8272\u7ecf\u6d4e\u548c\u533a\u57df\u9009\u62e9\u6027\u826f\u597d\u7b49\u7684\u4f18\u70b9\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cIron-Catalyzed Photoinduced Remote C(sp^{3<\/sup>)\u2500H Amination of Free Alcohols\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8eOrganic Letters<\/em>\u3002\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u718a\u6ce5\u4e3a\u8be5\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u66fe\u8363\u6559\u6388\u548c\u674e\u6d0b\u6559\u6388\u4e3a\u672c\u5de5\u4f5c\u7684\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n}}

<\/p>\n

\u66fe\u8363\u6559\u6388\u7b80\u4ecb<\/h4>\n

<\/a><\/p>\n

\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6559\u6388\uff0c\u6d77\u5916\u9ad8\u5c42\u6b21\u4eba\u624d\u8ba1\u5212\u3001\u897f\u4ea4\u201c\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212A\u7c7b\u201d\u5165\u9009\u8005\uff0c\u535a\u5bfc\u30022008\u5e74\u4e8e\u6d59\u6c5f\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u540e\u76f4\u535a\u672c\u6821\uff0c\u5e76\u4e8e2013\u5e74\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u9ebb\u751f\u660e\u9662\u58eb\uff0c\u4e3b\u8981\u7814\u7a76\u8054\u70ef\u53c2\u4e0e\u7684\u81ea\u7531\u57fa\u52a0\u6210\u4ee5\u53ca\u78b3\u6c22\u5b98\u80fd\u56e2\u5316\u30022013\u5e74\u81f32016\u5e74\uff0c\u5728\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u4e01\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08\u8463\u5e7f\u5f6c\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u975e\u5f20\u529b\u73af\u916e\u7684\u78b3\u78b3\u952e\u6d3b\u5316\u5076\u8054\u30022016\u5e74\u81f32018\u5e74\uff0c\u5728\u4ee5\u8272\u5217\u5a01\u5179\u66fc\u79d1\u5b66\u7814\u7a76\u6240\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08David Milstein\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3aPincer\u7edc\u5408\u7269\u5408\u6210\u4ee5\u53ca\u5728\u4e00\u6c27\u5316\u4e8c\u6c2e\u6d3b\u5316\u4e2d\u7684\u5e94\u7528\u30022018\u5e74\u8d77\uff0c\u5728\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u4ece\u4e8b\u72ec\u7acb\u7814\u7a76\u5de5\u4f5c\u3002\u76ee\u524d\u5728J. Am. Chem. Soc.<\/em>\u3001Angew. Chem. Int. Ed.<\/em>\u3001ACS Catal.<\/em>\u7b49\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520a\u53d1\u8868\u7cfb\u5217\u8bba\u6587\uff0c\u6388\u6743\u4e2d\u56fd\u4e13\u52293\u9879\u3002<\/p>\n

Email:\u00a0rongzeng@xjtu.edu.cn<\/a>.<\/strong><\/p>\n

\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u7b80\u4ecb\uff1a<\/p>\n

<\/a><\/p>\n

\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u6210\u7acb\u4ee5\u6765\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u57fa\u4e8e\u534f\u540c\u50ac\u5316\u7b56\u7565\u7684\u6709\u673a\u5408\u6210\u65b0\u65b9\u6cd5\u7814\u7a76\uff0c\u4e3b\u8981\u5305\u542b\u60f0\u6027\u952e\u6d3b\u5316\u8f6c\u5316\u3001\u5149\u50ac\u5316\u3001\u6d3b\u6027\u6742\u73af\u5316\u5408\u7269\u5408\u6210\u3001\u6709\u673a\u91d1\u5c5e\u7edc\u5408\u7269\u7684\u5408\u6210\u53ca\u5e94\u7528\u7b49\u3002<\/p>\n

\u66fe\u8363\u8bfe\u9898\u7ec4\u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002Email:\u00a0rongzeng@xjtu.edu.cn<\/a>.<\/p>\n

<\/p>\n

\u6b64\u5916\uff0c\u56e0\u53d1\u5c55\u9700\u8981\uff0c\u66fe\u8363\u8bfe\u9898\u7ec4\u9762\u5411\u793e\u4f1a\u516c\u5f00\u62db\u8058\u9752\u79c0\u4eba\u624d\u4ee5\u53ca\u79d1\u7814\u52a9\u7406\u3002<\/strong><\/p>\n

\u9752\u79c0\u4eba\u624d\u4e2a\u4eba\u5f85\u9047\uff1a\u4eab\u53d7\u5b66\u6821\u63d0\u4f9b\u9752\u79c0\u4eba\u624d\u7684\u4e00\u5207\u5f85\u9047\u3002\u8be6\u60c5\u8bf7\u89c1\uff1a\u5176\u4e2d\uff0cA\u7c7b\u9752\u79c0\u5e74\u85aa30\u4e07\uff1bB\u7c7b\u9752\u79c0\u5e74\u85aa16\u4e07\uff1b\u6b64\u5916\uff0c\u8bfe\u9898\u7ec4\u5956\u52b1\u8865\u52a93-5\u4e07\u3002\uff08\u9752\u79c0A\u6700\u9ad8\u5e74\u85aa35\u4e07\uff09<\/p>\n

\u9752\u79c0\u8ba1\u5212\u8868\u73b0\u4f18\u5f02\u8005\uff0c\u4f18\u5148\u63a8\u8350\u7533\u8bf7\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212\u3002<\/p>\n

\u7814\u7a76\u52a9\u7406\uff1a\u7855\u58eb\u6bd5\u4e1a\u6216\u5373\u5c06\u6bd5\u4e1a\uff1b\u5177\u6709\u6709\u673a\u5316\u5b66\u80cc\u666f\uff1b\u53d1\u8868\u8fc7\u82f1\u6587\u8bba\u6587\uff0c\u6709\u4e00\u5b9a\u7684\u82f1\u6587\u4e66\u5199\u80fd\u529b\u3002\u8868\u73b0\u4f18\u5f02\u8005\u4f18\u5148\u63a8\u8350\u535a\u58eb\u7533\u8bf7\u3002<\/p>\n

<\/p>\n

\u674e\u6d0b\u526f\u6559\u6388\u7b80\u4ecb<\/h4>\n

<\/a><\/p>\n

\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u526f\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022010\u5e74\u4e8e\u5170\u5dde\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u30022015\u5e74\u4e8e\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u53d6\u5f97\u6709\u673a\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u4e01\u594e\u5cad\u9662\u58eb\uff0c\u4e3b\u8981\u4ece\u4e8b\u624b\u6027\u914d\u4f53\u7684\u8bbe\u8ba1\u5408\u6210\u4ee5\u53ca\u4e0d\u5bf9\u79f0\u50ac\u5316\u6c22\u5316\u53cd\u5e94\u7684\u7814\u7a76\u30022017\u5e74\u81f32018\u5e74\u5728\u7f8e\u56fd\u65af\u514b\u91cc\u666e\u65af\u7814\u7a76\u6240\u505a\u8bbf\u95ee\u5b66\u8005\u7814\u7a76\uff0c\u5408\u4f5c\u5bfc\u5e08\u4f59\u91d1\u6743\uff08Jin-Quan Yu\uff09\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u94af\u50ac\u5316C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u30022015\u5e747\u6708\u52a0\u5165\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u4ece\u4e8b\u72ec\u7acb\u7814\u7a76\u5de5\u4f5c\u3002\u4e3b\u8981\u4ece\u4e8b\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u60f0\u6027\u5316\u5b66\u952e\u6d3b\u5316\u53ca\u70ef\u7094\u7684\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u7814\u7a76\u3002\u8fc4\u4eca\u4e3a\u6b62\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520aAngew. Chem. Int. Ed., Org. Lett., Org. Chem. Front., Chem. Eur. J.<\/em>\u7b49\u53d1\u8868\u8bba\u6587\u591a\u7bc7\u3002<\/p>\n

\u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002<\/p>\n

Email:\u00a0yanglee@mail.xjtu.edu.cn<\/a>.<\/p>\n

<\/p>\n

\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<\/strong>Chem-Station\u5316\u5b66\u7a7a\u95f4<\/strong><\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"\u5bfc\u8bed \u8102\u80aa\u9187\u7684\u9009\u62e9\u6027\u50ac\u5316\u78b3\u6c22\u952e\u5b98\u80fd\u56e2\u53ef\u4ee5\u5c06\u5e7f\u6cdb\u5b58\u5728\u7684\u9187\u7c7b\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u5177\u6709\u9ad8\u9644\u52a0\u503c\u7684\u590d\u6742\u7ed3\u6784\u5206\u5b50\uff0c\u56e0\u6b64\u8be5\u7c7b\u8f6c\u5316\u4e5f\u5f15\u8d77\u4e86\u5316\u5b66\u5bb6\u4eec\u7684\u5173\u6ce8\u3002\u901a\u8fc7\u6c27\u81ea\u7531\u57fa\u7684\u751f\u6210\u4ee5\u53ca1,5-\u6c22\u8fc1\u79fb\u5b9e\u73b0\u9187\u7c7b\u5316\u5408\u7269\u7684\u8fdc\u7aef\u78b3\u6c22\u952e\u5b98\u80fd\u56e2\u5316\uff0c\u662f\u5176\u4e2d\u5f88\u7ecf\u5178\u7684\u65b9\u6cd5\u3002\u5e38\u7528\u7684\u7b56\u7565\u662f\u5c06\u9187\u7c7b\u5316\u5408\u7269\u8f6c\u5316\u6210\u4e3aO-N\u5316\u5408\u7269\u3001\u9ad8\u4ef7\u5364\u3001\u8fc7\u6c27\u5316\u7269\u3001\u70f7\u6c27\u57fa\u94c5\u7b49\uff0c\u4ee5\u5b9e\u73b0\u9187\u7684\u201c\u6d3b\u5316\u201d\u4fc3\u8fdb\u6c27\u81ea\u7531\u57fa\u7684\u751f\u6210\u3002\u82cf\u5dde\u5927\u5b66\u6731\u6668\u6559\u6388\u3001\u5357\u5f00\u5927\u5b66\u9648\u5f13\u6559\u6388\u3001\u5317\u4eac\u5927\u5b66\u7126\u5b81\u6559\u6388\u3001\uff08\u4ece\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u8fc1\u5165\uff09\u4e0a\u6d77\u6709\u673a\u6240\u5de6\u667a\u4f1f\u6559\u6388\u7b49\u4eba\u901a\u8fc7\u4f7f\u7528Ir\u3001Ru\u3001Ag\u3001Ce\u7b49\u50ac\u5316\u5242\u4fc3\u8fdb\u6e38\u79bb\u9187\u751f\u6210\u6c27\u81ea\u7531\u57fa\u53ca1,5-\u6c22\u8fc1\u79fb\uff0c\u5b9e\u73b0\u4e86\u6e38\u79bb\u9187\u7684\u8fdc\u7aef\u78b3\u6c22\u952e\u5b98\u80fd\u56e2\u5316\u8f6c\u5316\u3002\u5982\u4f55\u4f7f\u7528\u5ec9\u4ef7\u91d1\u5c5e\u4f5c\u50ac\u5316\u5242\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002\u8fd1\u65e5\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u7684\u65b0\u65b9\u6cd5\uff0c\u8102\u80aa\u9187\u5728\u94c1\u7684\u50ac\u5316\u4e0b\u751f\u6210\u6c27\u81ea\u7531\u57fa\u3001\u968f\u540e1,5-\u6c22\u8fc1\u79fb\u3001\u5b98\u80fd\u56e2\u5316\uff0c\u8fdb\u800c\u5b9e\u73b0\u4e86\u5e7f\u6cdb\u6613\u5f97\u7684\u8102\u80aa\u9187\u7684\u8fdc\u7aef\u80fa\u5316\u53cd\u5e94\u3002 Iron-Catalyzed Photoinduced Remote C(sp3)\u2500H Amination of Free Alcohols. Ni Xiong,\u00a0Yang Li*,\u00a0and\u00a0Rong Zeng* Organic Letters \u00a0ASAP \u00a0DOI:\u00a010.1021\/acs.orglett.1c03488 \u6b63\u6587 \u8fd1\u5e74\u6765\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u56f4\u7ed5\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u53cd\u5e94\u5c55\u5f00\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u5de5\u4f5c\u3002\u8be5\u8bfe\u9898\u7ec4\u524d\u671f\u66fe\u5f00\u53d1\u4e86\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u4e0b\u4e8c\u7ea7\u6216\u4e09\u7ea7\u9187\u7684\u6e29\u548c\u6c27\u5316\u5236\u5907\u82b3\u9999\u9178\uff08Org. Lett. 2021, 23, 2915-2920\uff09\u3001\u70f7\u57fa\u82ef\u3001\u805a\u82ef\u4e59\u70ef\u6c27\u5316\u5236\u5907\u82ef\u7532\u9178\uff08Chin. J. Chem.\u00a02021,\u00a039, 3225-3230\uff09\u7b49\u3002\u57fa\u4e8e\u5bf9\u524d\u671f\u7814\u7a76\u5de5\u4f5c\u7684\u6df1\u5165\u63a2\u7d22\uff0c\u8fd1\u65e5\uff0c\u8be5\u56e2\u961f\u53c8\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u6e38\u79bb\u8102\u80aa\u9187\u7684\u9009\u62e9\u6027\u78b3\u6c22\u952e\u80fa\u5316\u53cd\u5e94\u6765\u6784\u5efa\u590d\u6742\u5206\u5b50\u7684\u65b0\u65b9\u6cd5\u3002 \u8be5\u53cd\u5e94\u5177\u6709\u826f\u597d\u7684\u6b65\u9aa4\u3001\u539f\u5b50\u7ecf\u6d4e\u6027\u53ca\u5e7f\u6cdb\u7684\u5e95\u7269\u8303\u56f4\u3002\u5728\u53ef\u89c1\u5149\u4fc3\u8fdb\u94c1\u50ac\u5316\u4e0b\uff0c\u4e0d\u540c\u7684\u6e38\u79bb\u8102\u80aa\u9187\u90fd\u53ef\u4ee5\u5b9e\u73b0\u8fdc\u7aef\u80fa\u5316\u53cd\u5e94\uff0c\u9ad8\u6548\u3001\u9ad8\u9009\u62e9\u6027\u5730\u5f97\u5230\u76f8\u5e94\u7684\u6c28\u57fa\u9187\u7c7b\u884d\u751f\u7269\uff08\u56fe3\uff09\u3002 \u6b64\u5916\uff0c\u4e0d\u540c\u7684\u5076\u6c2e\u7c7b\u5316\u5408\u7269\u4e5f\u53ef\u4ee5\u53c2\u4e0e\u53cd\u5e94\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u6c28\u57fa\u9187\u7c7b\u4ea7\u7269\uff08\u56fe4\uff09\u3002 \u901a\u8fc7\u7b80\u5355\u7684\u53cd\u5e94\u673a\u7406\u63a2\u7d22\uff0c\u4f5c\u8005\u4e5f\u63d0\u51fa\u4e86\u8be5\u53cd\u5e94\u7684\u50ac\u5316\u5faa\u73af\uff08\u56fe5\uff09\u3002\u8be5\u53cd\u5e94\u7531\u4e09\u4ef7\u94c1\u50ac\u5316\u5242 Fe(III)\u548c\u8102\u80aa\u9187\u4e4b\u95f4\u7684\u5149\u8bf1\u5bfc\u7535\u8377\u8f6c\u79fb\u6765\u5f15\u53d1\uff0c\u901a\u8fc7\u5f62\u6210Fe(II)\u7269\u79cd\u4fc3\u4f7f\u6c27\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53 Int-O\u7684\u751f\u6210\u3002\u5206\u5b50\u5185 1,5-\u6c22\u8f6c\u79fb\uff08HAT\uff09\u3001\u63a5\u7740\u4e0eDBAD\u53d1\u751f\u81ea\u7531\u57fa\u52a0\u6210\u4ea7\u751f\u6c2e\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53 Int-N\u3002\u6700\u540e\uff0c\u5355\u7535\u5b50\u8f6c\u79fb\u751f\u6210\u80fa\u5316\u4ea7\u7269\u7684\u751f\u6210\u4ee5\u53ca\u518d\u751fFe(III)\u50ac\u5316\u5242\u3002\u6bd4\u8f83\u9057\u61be\u7684\u662f\uff0c\u5bf9\u4e8e\u6c27\u81ea\u7531\u57fa\u7684\u751f\u6210\u673a\u5236\uff0c\u662f\u901a\u8fc7\u6c2f\u81ea\u7531\u57fa\u8fd8\u662fLMCT\u7684\u8fc7\u7a0b\uff0c\u4f5c\u8005\u5e76\u6ca1\u6709\u7ed9\u51fa\u7ed3\u8bba\u3002\u8be5\u5b9e\u9a8c\u5ba4\u4ecd\u5728\u8fdb\u884c\u66f4\u6df1\u5165\u7684\u673a\u7406\u7814\u7a76\u3002 \u6700\u540e\uff0c\u4f5c\u8005\u8fd8\u901a\u8fc7\u514b\u7ea7\u653e\u5927\u53cd\u5e94\u3001\u9ebb\u6c27\u5316\u53cd\u5e94\u3001Appel\u53cd\u5e94\u4ee5\u53caTsCl\u4fdd\u62a4\u53cd\u5e94\u7b49\u8fdb\u884c\u4e86\u63a2\u7d22\uff08\u56fe6\uff09\uff0c\u521d\u6b65\u5c55\u793a\u51fa\u4e86\u53cd\u5e94\u7684\u5b9e\u7528\u6027\uff0c\u4e5f\u4e3a\u540e\u7eed\u7684\u8f6c\u5316\u63d0\u4f9b\u4e86\u57fa\u7840\u3002 \u603b\u7ed3 \u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u94c1\u57fa\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u7cfb\u7edf\u5b9e\u73b0\u4e86\u6e38\u79bb\u8102\u80aa\u9187\u7684\u8fdc\u7a0bC-H\u952e\u80fa\u5316\u3002\u8be5\u53cd\u5e94\u4f7f\u7528\u5ec9\u4ef7\u6613\u5f97\u7684\u94c1\u50ac\u5316\u5242\uff08FeCl3\uff09\uff0c\u7ed3\u5408\u53ef\u89c1\u5149\u50ac\u5316\uff0c\u5177\u6709\u826f\u597d\u7684\u5e95\u7269\u8010\u53d7\u6027\u3001\u6761\u4ef6\u6e29\u548c\u3001\u7eff\u8272\u7ecf\u6d4e\u548c\u533a\u57df\u9009\u62e9\u6027\u826f\u597d\u7b49\u7684\u4f18\u70b9\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cIron-Catalyzed Photoinduced Remote C(sp3)\u2500H Amination of Free Alcohols\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8eOrganic Letters\u3002\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u718a\u6ce5\u4e3a\u8be5\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u66fe\u8363\u6559\u6388\u548c\u674e\u6d0b\u6559\u6388\u4e3a\u672c\u5de5\u4f5c\u7684\u901a\u8baf\u4f5c\u8005\u3002 \u66fe\u8363\u6559\u6388\u7b80\u4ecb \u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6559\u6388\uff0c\u6d77\u5916\u9ad8\u5c42\u6b21\u4eba\u624d\u8ba1\u5212\u3001\u897f\u4ea4\u201c\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212A\u7c7b\u201d\u5165\u9009\u8005\uff0c\u535a\u5bfc\u30022008\u5e74\u4e8e\u6d59\u6c5f\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u540e\u76f4\u535a\u672c\u6821\uff0c\u5e76\u4e8e2013\u5e74\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u9ebb\u751f\u660e\u9662\u58eb\uff0c\u4e3b\u8981\u7814\u7a76\u8054\u70ef\u53c2\u4e0e\u7684\u81ea\u7531\u57fa\u52a0\u6210\u4ee5\u53ca\u78b3\u6c22\u5b98\u80fd\u56e2\u5316\u30022013\u5e74\u81f32016\u5e74\uff0c\u5728\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u4e01\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08\u8463\u5e7f\u5f6c\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u975e\u5f20\u529b\u73af\u916e\u7684\u78b3\u78b3\u952e\u6d3b\u5316\u5076\u8054\u30022016\u5e74\u81f32018\u5e74\uff0c\u5728\u4ee5\u8272\u5217\u5a01\u5179\u66fc\u79d1\u5b66\u7814\u7a76\u6240\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08David Milstein\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3aPincer\u7edc\u5408\u7269\u5408\u6210\u4ee5\u53ca\u5728\u4e00\u6c27\u5316\u4e8c\u6c2e\u6d3b\u5316\u4e2d\u7684\u5e94\u7528\u30022018\u5e74\u8d77\uff0c\u5728\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u4ece\u4e8b\u72ec\u7acb\u7814\u7a76\u5de5\u4f5c\u3002\u76ee\u524d\u5728J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001ACS Catal.\u7b49\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520a\u53d1\u8868\u7cfb\u5217\u8bba\u6587\uff0c\u6388\u6743\u4e2d\u56fd\u4e13\u52293\u9879\u3002 Email:\u00a0rongzeng@xjtu.edu.cn. \u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u7b80\u4ecb\uff1a \u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u6210\u7acb\u4ee5\u6765\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u57fa\u4e8e\u534f\u540c\u50ac\u5316\u7b56\u7565\u7684\u6709\u673a\u5408\u6210\u65b0\u65b9\u6cd5\u7814\u7a76\uff0c\u4e3b\u8981\u5305\u542b\u60f0\u6027\u952e\u6d3b\u5316\u8f6c\u5316\u3001\u5149\u50ac\u5316\u3001\u6d3b\u6027\u6742\u73af\u5316\u5408\u7269\u5408\u6210\u3001\u6709\u673a\u91d1\u5c5e\u7edc\u5408\u7269\u7684\u5408\u6210\u53ca\u5e94\u7528\u7b49\u3002 \u66fe\u8363\u8bfe\u9898\u7ec4\u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002Email:\u00a0rongzeng@xjtu.edu.cn. \u6b64\u5916\uff0c\u56e0\u53d1\u5c55\u9700\u8981\uff0c\u66fe\u8363\u8bfe\u9898\u7ec4\u9762\u5411\u793e\u4f1a\u516c\u5f00\u62db\u8058\u9752\u79c0\u4eba\u624d\u4ee5\u53ca\u79d1\u7814\u52a9\u7406\u3002 \u9752\u79c0\u4eba\u624d\u4e2a\u4eba\u5f85\u9047\uff1a\u4eab\u53d7\u5b66\u6821\u63d0\u4f9b\u9752\u79c0\u4eba\u624d\u7684\u4e00\u5207\u5f85\u9047\u3002\u8be6\u60c5\u8bf7\u89c1\uff1a\u5176\u4e2d\uff0cA\u7c7b\u9752\u79c0\u5e74\u85aa30\u4e07\uff1bB\u7c7b\u9752\u79c0\u5e74\u85aa16\u4e07\uff1b\u6b64\u5916\uff0c\u8bfe\u9898\u7ec4\u5956\u52b1\u8865\u52a93-5\u4e07\u3002\uff08\u9752\u79c0A\u6700\u9ad8\u5e74\u85aa35\u4e07\uff09 \u9752\u79c0\u8ba1\u5212\u8868\u73b0\u4f18\u5f02\u8005\uff0c\u4f18\u5148\u63a8\u8350\u7533\u8bf7\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212\u3002 \u7814\u7a76\u52a9\u7406\uff1a\u7855\u58eb\u6bd5\u4e1a\u6216\u5373\u5c06\u6bd5\u4e1a\uff1b\u5177\u6709\u6709\u673a\u5316\u5b66\u80cc\u666f\uff1b\u53d1\u8868\u8fc7\u82f1\u6587\u8bba\u6587\uff0c\u6709\u4e00\u5b9a\u7684\u82f1\u6587\u4e66\u5199\u80fd\u529b\u3002\u8868\u73b0\u4f18\u5f02\u8005\u4f18\u5148\u63a8\u8350\u535a\u58eb\u7533\u8bf7\u3002 \u674e\u6d0b\u526f\u6559\u6388\u7b80\u4ecb \u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u526f\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022010\u5e74\u4e8e\u5170\u5dde\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u30022015\u5e74\u4e8e\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u53d6\u5f97\u6709\u673a\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u4e01\u594e\u5cad\u9662\u58eb\uff0c\u4e3b\u8981\u4ece\u4e8b\u624b\u6027\u914d\u4f53\u7684\u8bbe\u8ba1\u5408\u6210\u4ee5\u53ca\u4e0d\u5bf9\u79f0\u50ac\u5316\u6c22\u5316\u53cd\u5e94\u7684\u7814\u7a76\u30022017\u5e74\u81f32018\u5e74\u5728\u7f8e\u56fd\u65af\u514b\u91cc\u666e\u65af\u7814\u7a76\u6240\u505a\u8bbf\u95ee\u5b66\u8005\u7814\u7a76\uff0c\u5408\u4f5c\u5bfc\u5e08\u4f59\u91d1\u6743\uff08Jin-Quan Yu\uff09\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u94af\u50ac\u5316C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u30022015\u5e747\u6708\u52a0\u5165\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u4ece\u4e8b\u72ec\u7acb\u7814\u7a76\u5de5\u4f5c\u3002\u4e3b\u8981\u4ece\u4e8b\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u60f0\u6027\u5316\u5b66\u952e\u6d3b\u5316\u53ca\u70ef\u7094\u7684\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u7814\u7a76\u3002\u8fc4\u4eca\u4e3a\u6b62\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520aAngew. Chem. Int. Ed., Org. Lett., Org. Chem. Front., Chem. Eur. J.\u7b49\u53d1\u8868\u8bba\u6587\u591a\u7bc7\u3002 \u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002 Email:\u00a0yanglee@mail.xjtu.edu.cn. \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d","protected":false},"author":3,"featured_media":40520,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2235,1271],"tags":[2479,1342,3641,632],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2021\/11\/OL-Cover.jpg","jetpack_shortlink":"https:\/\/wp.me\/p96op1-axl","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/40507"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=40507"}],"version-history":[{"count":4,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/40507\/revisions"}],"predecessor-version":[{"id":40600,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/40507\/revisions\/40600"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/40520"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=40507"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=40507"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=40507"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}