{"id":42253,"date":"2022-07-01T08:00:29","date_gmt":"2022-07-01T00:00:29","guid":{"rendered":"\/\/www.gsbet888.com\/?p=42253"},"modified":"2022-06-30T21:30:30","modified_gmt":"2022-06-30T13:30:30","slug":"%e8%a5%bf%e5%ae%89%e4%ba%a4%e9%80%9a%e5%a4%a7%e5%ad%a6%e6%9b%be%e8%8d%a3%e6%95%99%e6%8e%88%e3%80%81%e6%9d%8e%e6%b4%8b%e5%89%af%e6%95%99%e6%8e%88org-lett-%ef%bc%9a%e6%b8%a9%e5%92%8c%e6%9d%a1%e4%bb%b6","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2022\/07\/%e8%a5%bf%e5%ae%89%e4%ba%a4%e9%80%9a%e5%a4%a7%e5%ad%a6%e6%9b%be%e8%8d%a3%e6%95%99%e6%8e%88%e3%80%81%e6%9d%8e%e6%b4%8b%e5%89%af%e6%95%99%e6%8e%88org-lett-%ef%bc%9a%e6%b8%a9%e5%92%8c%e6%9d%a1%e4%bb%b6.html","title":{"rendered":"\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u3001\u674e\u6d0b\u526f\u6559\u6388Org. Lett.\uff1a\u6e29\u548c\u6761\u4ef6\u4e0b\u785d\u57fa\u82ef\u4e0e\u919b\u3001\u9187\u53cd\u5e94\u5408\u6210\u9170\u80fa"},"content":{"rendered":"<h4 style=\"font-weight: 400;\">\u5bfc\u8bed<\/h4>\n<p style=\"font-weight: 400;\"><strong>\u9170\u80fa<\/strong>\u662f\u6709\u673a\u5316\u5b66\u4e2d\u6700\u91cd\u8981\u7684\u5b98\u80fd\u56e2\u4e4b\u4e00\uff0c\u5728\u6709\u673a\u5408\u6210\u3001\u751f\u547d\u5316\u5b66\u3001\u6709\u673a\u6750\u6599\u5316\u5b66\u548c\u836f\u7269\u5316\u5b66\u4e2d\u90fd\u6709\u7740\u4e3e\u8db3\u8f7b\u91cd\u7684\u4f5c\u7528\u3002\u4f20\u7edf\u4e0a\uff0c\u7edd\u5927\u591a\u6570\u9170\u80fa\u5408\u6210\u4f9d\u8d56\u4e8e\u80fa\u4e0e\u7fa7\u9178\u53ca\u5176\u884d\u751f\u7269(\u5982\u9170\u6c2f\u548c\u9178\u9150)\u7684\u7f29\u5408\u53cd\u5e94\u3002\u5c3d\u7ba1\u8fd9\u4e9b\u65b9\u6cd5\u9ad8\u6548\u65b9\u4fbf\uff0c\u4f46\u901a\u5e38\u9700\u8981\u5316\u5b66\u8ba1\u91cf\u6d3b\u5316\u5242\uff0c\u5e76\u4f1a\u4ea7\u751f\u5f53\u91cf\u4ee5\u4e0a\u7684\u5e9f\u6599\u3002\u9274\u4e8e\u6c28\u57fa\u5316\u5408\u7269\u5f80\u5f80\u662f\u901a\u8fc7\u785d\u57fa\u5316\u5408\u7269\u8fd8\u539f\u6765\u5f97\u5230\u7684\uff0c\u76f4\u63a5\u4f7f\u7528\u785d\u57fa\u82b3\u70c3\u4f5c\u4e3a\u6c2e\u6e90\u5408\u6210\u9170\u80fa\u7c7b\u5316\u5408\u7269\u4fbf\u663e\u5f97\u6781\u6709\u610f\u4e49\u3002\u7136\u800c\uff0c\u5f53\u4f7f\u7528\u785d\u57fa\u5316\u5408\u7269\u4f5c\u4e3a\u80fa\u6e90\uff0c\u8fd9\u7c7b\u53cd\u5e94\u4ecd\u7136\u9700\u8981\u8fc7\u91cf\u7684\u8fd8\u539f\u5242\uff0c\u5982\u950c\u3001\u9530\u3001\u7845\u70f7\u7b49\uff0c\u53bb\u539f\u4f4d\u8fd8\u539f\u5e76\u4fc3\u8fdb\u53cd\u5e94\u7684\u53d1\u751f\u3002\u9488\u5bf9\u5982\u4f55\u907f\u514d\u4f7f\u7528\u8fc7\u91cf\u5f3a\u8fd8\u539f\u5242\u7684\u95ee\u9898\uff0c\u8fd1\u65e5\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u3001\u674e\u6d0b\u526f\u6559\u6388\u4f7f\u7528\u785d\u57fa\u82b3\u70c3\u4f5c\u4e3a\u6c2e\u6e90\uff0c\u62a5\u9053\u4e86\u65e0\u9700\u989d\u5916\u7684\u6c27\u5316\u8fd8\u539f\u8bd5\u5242\u53ca\u6d3b\u5316\u5242\u7684\u9170\u80fa\u5408\u6210\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u901a\u8fc7\u5728\u5149\u7167\u4e0b\uff0c\u4f7f\u7528\u5ec9\u4ef7\u7684\u4e09\u4ef7\u94c1\u4f5c\u4e3a\u50ac\u5316\u5242\u6765\u76f4\u63a5\u5b9e\u73b0\u785d\u57fa\u5316\u5408\u7269\u4e0e\u919b\u3001\u9187\u7684\u5076\u8054\u53cd\u5e94\uff0c\u53d1\u5c55\u4e86\u4e00\u79cd\u5408\u6210\u9170\u80fa\u7684\u65b0\u65b9\u6cd5\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cMild Amide Synthesis Using Nitrobenzene under Neutral Conditions\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8e<em>Org. Lett<\/em>. <strong>2022<\/strong>.\uff08DOI:\u00a010.1021\/acs.orglett.2c01743\uff09\u3002<\/p>\n<p style=\"font-weight: 400;\">\u66fe\u8363\u6559\u6388\u7b80\u4ecb\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/2-19.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42245 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/2-19.png\" alt=\"\" width=\"270\" height=\"404\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/2-19.png 270w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/2-19-200x300.png 200w\" sizes=\"(max-width: 270px) 100vw, 270px\" \/><\/a><\/p>\n<p style=\"font-weight: 400;\">\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6559\u6388\uff0c\u6d77\u5916\u9ad8\u5c42\u6b21\u4eba\u624d\u8ba1\u5212\u3001\u897f\u4ea4\u201c\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212\u201dA\u7c7b\u5165\u9009\u8005\uff0c\u535a\u5bfc\u30022008\u5e74\u4e8e\u6d59\u6c5f\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u540e\u76f4\u535a\u672c\u6821\uff0c\u5e76\u4e8e2013\u5e74\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u9ebb\u751f\u660e\u9662\u58eb\uff0c\u4e3b\u8981\u7814\u7a76\u8054\u70ef\u53c2\u4e0e\u7684\u81ea\u7531\u57fa\u52a0\u6210\u4ee5\u53ca\u78b3\u6c22\u5b98\u80fd\u56e2\u5316\u30022013\u5e74\u81f32016\u5e74\uff0c\u5728\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u4e01\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08\u8463\u5e7f\u5f6c\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u975e\u5f20\u529b\u73af\u916e\u7684\u78b3\u78b3\u952e\u6d3b\u5316\u5076\u8054\u30022016\u5e74\u81f32018\u5e74\uff0c\u5728\u4ee5\u8272\u5217\u5a01\u5179\u66fc\u79d1\u5b66\u7814\u7a76\u6240\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08David Milstein\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3aPincer\u7edc\u5408\u7269\u5408\u6210\u4ee5\u53ca\u5728\u4e00\u6c27\u5316\u4e8c\u6c2e\u6d3b\u5316\u4e2d\u7684\u5e94\u7528\u30022018\u5e74\u56de\u56fd\u540e\u7684\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u5ec9\u4ef7\u91d1\u5c5e\u50ac\u5316\u65b0\u65b9\u6cd5\u7684\u5f00\u53d1\u548c\u5e94\u7528\u3002\u76ee\u524d\u5728<em>J. Am. Chem. Soc.<\/em>\u3001<em>Angew. Chem. Int. Ed.<\/em>\u3001<em>ACS Catal.<\/em>\u7b49\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520a\u53d1\u8868\u7cfb\u5217\u8bba\u6587\uff0c\u6388\u6743\u4e2d\u56fd\u4e13\u52293\u9879\u3002Email:\u00a0<a href=\"mailto:rongzeng@xjtu.edu.cn\">rongzeng@xjtu.edu.cn<\/a>.<\/p>\n<p style=\"font-weight: 400;\">\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/3-17.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42246 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/3-17.png\" alt=\"\" width=\"654\" height=\"491\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/3-17.png 654w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/3-17-300x225.png 300w\" sizes=\"(max-width: 654px) 100vw, 654px\" \/><\/a><\/p>\n<p style=\"font-weight: 400;\">\u66fe\u8363\u8bfe\u9898\u7ec4\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u5ec9\u4ef7\u91d1\u5c5e\u50ac\u5316\u65b0\u65b9\u6cd5\u7684\u5f00\u53d1\u548c\u5e94\u7528\u3002<\/p>\n<p style=\"font-weight: 400;\">\u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002<\/p>\n<p style=\"font-weight: 400;\"><strong>\u6b64\u5916\uff0c\u56e0\u53d1\u5c55\u9700\u8981\uff0c\u66fe\u8363\u8bfe\u9898\u7ec4\u9762\u5411\u793e\u4f1a\u516c\u5f00\u62db\u8058\u9752\u79c0\u4eba\u624d\u4ee5\u53ca\u79d1\u7814\u52a9\u7406\u3002<\/strong><\/p>\n<p style=\"font-weight: 400;\">\u9752\u79c0\u8ba1\u5212\u662f\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u7684\u5e08\u8d44\u535a\u58eb\u540e\u8ba1\u5212\uff0c\u8058\u671f\u5185\u8003\u6838\u5408\u683c\u8f6c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u526f\u6559\u6388\u3002<\/p>\n<p style=\"font-weight: 400;\">\u9752\u79c0\u4eba\u624d\u4e2a\u4eba\u5f85\u9047\uff1a\u4eab\u53d7\u5b66\u6821\u63d0\u4f9b\u9752\u79c0\u4eba\u624d\u7684\u4e00\u5207\u5f85\u9047\u3002\u8be6\u60c5\u8bf7\u89c1\uff1a\u5176\u4e2d\uff0cA\u7c7b\u9752\u79c0\u5e74\u85aa30\u4e07\uff1bB\u7c7b\u9752\u79c0\u5e74\u85aa16-20\u4e07\u3002\u9752\u79c0<\/p>\n<p style=\"font-weight: 400;\">\u9752\u79c0\u8ba1\u5212\u8868\u73b0\u4f18\u5f02\u8005\uff0c\u4f18\u5148\u63a8\u8350\u7533\u8bf7\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212\u3002<\/p>\n<p style=\"font-weight: 400;\">\u7814\u7a76\u52a9\u7406\uff1a\u7855\u58eb\u6bd5\u4e1a\u6216\u5373\u5c06\u6bd5\u4e1a\uff1b\u5177\u6709\u6709\u673a\u5316\u5b66\u80cc\u666f\uff1b\u53d1\u8868\u8fc7\u82f1\u6587\u8bba\u6587\uff0c\u6709\u4e00\u5b9a\u7684\u82f1\u6587\u4e66\u5199\u80fd\u529b\u3002\u8868\u73b0\u4f18\u5f02\u8005\u4f18\u5148\u63a8\u8350\u535a\u58eb\u7533\u8bf7\u3002<\/p>\n<p style=\"font-weight: 400;\">\u8054\u7cfb\u65b9\u5f0fEmail:\u00a0<a href=\"mailto:rongzeng@xjtu.edu.cn\">rongzeng@xjtu.edu.cn<\/a>.<\/p>\n<p style=\"font-weight: 400;\">\u674e\u6d0b\u526f\u6559\u6388\u7b80\u4ecb\uff1a<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/4-15.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42247 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/4-15.png\" alt=\"\" width=\"224\" height=\"295\" \/><\/a><\/p>\n<p style=\"font-weight: 400;\">\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u526f\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022010\u5e74\u4e8e\u5170\u5dde\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u30022015\u5e74\u4e8e\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u53d6\u5f97\u6709\u673a\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u4e01\u594e\u5cad\u9662\u58eb\uff0c\u4e3b\u8981\u4ece\u4e8b\u624b\u6027\u914d\u4f53\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u4e0d\u5bf9\u79f0\u50ac\u5316\u6c22\u5316\u53cd\u5e94\u7684\u7814\u7a76\u30022017\u5e74\u81f32018\u5e74\u5728\u7f8e\u56fd\u65af\u514b\u91cc\u666e\u65af\u7814\u7a76\u6240\u505a\u8bbf\u95ee\u5b66\u8005\u7814\u7a76\uff0c\u5408\u4f5c\u5bfc\u5e08\u4f59\u91d1\u6743\uff08Jin-Quan Yu\uff09\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u94af\u50ac\u5316C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u30022015\u5e747\u6708\u52a0\u5165\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u4ece\u4e8b\u72ec\u7acb\u7814\u7a76\u5de5\u4f5c\u3002\u4e3b\u8981\u4ece\u4e8b\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u60f0\u6027\u5316\u5b66\u952e\u6d3b\u5316\u53ca\u70ef\u7094\u7684\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u7814\u7a76\u3002\u8fc4\u4eca\u4e3a\u6b62\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520a<em>Angew. Chem. Int. Ed<\/em>.\u3001<em>Org. Lett<\/em>.\u3001<em>Org. Chem. Front.<\/em>\u3001<em>Chem. -Eur. J<\/em>.\u7b49\u53d1\u8868\u8bba\u6587\u591a\u7bc7\u3002<\/p>\n<p style=\"font-weight: 400;\">\u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002<\/p>\n<p style=\"font-weight: 400;\">Email: yanglee@mail.xjtu.edu.cn\u3002<\/p>\n<p style=\"font-weight: 400;\">\u524d\u6cbf\u79d1\u7814\u6210\u679c\uff1a\u6e29\u548c\u6761\u4ef6\u4e0b\u785d\u57fa\u82ef\u76f4\u63a5\u5408\u6210\u9170\u80fa<\/p>\n<p style=\"font-weight: 400;\">\u8fd1\u5e74\u6765\uff0c\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5df2\u7ecf\u6210\u4e3a\u4e00\u79cd\u5f3a\u5927\u800c\u72ec\u7279\u7684\u5de5\u5177\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u56f4\u7ed5\u5149\u4fc3\u94c1\u50ac\u5316\u5c55\u5f00\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u5de5\u4f5c\u3002\u76ee\u524d\u5df2\u7ecf\u5728\u8be5\u7814\u7a76\u65b9\u5411\u53d6\u5f97\u4e86\u8bf8\u591a\u8fdb\u5c55\u5e76\u5728\u56fd\u5185\u5916\u77e5\u540d\u5b66\u672f\u671f\u520a\u53d1\u8868\u591a\u7bc7\u7814\u7a76\u8bba\u6587\uff08<em>Org. Lett<\/em>. <strong>2021<\/strong>, <em>23<\/em>, 2915-2920; <em>Chin. J. Chem<\/em>. <strong>2021<\/strong>, <em>39<\/em>, 3225-3230; <em>Org. Lett<\/em>. <strong>2021<\/strong>, <em>23<\/em>, 8968-8972; <em>Org. Lett<\/em>. <strong>2022<\/strong>, <em>24<\/em>, 977-982; <em>Org. Chem. Front<\/em>. <strong>2022<\/strong>, DOI: 10.1039\/D2QO00709F\uff09\u3002\u8fd1\u65e5\uff0c\u56e2\u961f\u53c8\u5728\u8be5\u7814\u7a76\u9886\u57df\u53d6\u5f97\u4e86\u65b0\u8fdb\u5c55\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u94c1\u5149\u50ac\u5316\u785d\u57fa\u82ef\u4f5c\u4e3a\u6c2e\u6e90\u5408\u6210\u9170\u80fa\u7684\u65b0\u65b9\u6cd5\uff08\u56fe 1\uff09\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/5-10.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42248 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/5-10.png\" alt=\"\" width=\"677\" height=\"249\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/5-10.png 677w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/5-10-300x110.png 300w\" sizes=\"(max-width: 677px) 100vw, 677px\" \/><\/a><\/p>\n<p style=\"font-weight: 400; text-align: center;\">\u56fe1. \u785d\u57fa\u82ef\u4f5c\u4e3a\u6c2e\u6e90\u5408\u6210\u9170\u80fa<\/p>\n<p style=\"font-weight: 400; text-align: center;\">\uff08\u56fe\u7247\u6765\u6e90: <em>Org. Lett.<\/em>\uff09<\/p>\n<p style=\"font-weight: 400;\">\u4f5c\u8005\u9996\u5148\u901a\u8fc7\u785d\u57fa\u82ef\u548c\u82ef\u7532\u919b\u8f6c\u5316\u5408\u6210\u9170\u80fa\u7684\u53cd\u5e94\u8fdb\u884c\u4e86\u4f18\u5316\uff0c\u5e76\u5f97\u5230\u4e86\u6700\u4f18\u7684\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u591f\u4ee578%\u7684\u5206\u79bb\u4ea7\u7387\u5f97\u5230\u9170\u80fa\uff0c\u8868\u660e\u5149\u4fc3\u94c1\u50ac\u5316\u5177\u6709\u8f83\u9ad8\u7684\u6d3b\u6027\u3002\u968f\u540e\u5bf9\u8be5\u53cd\u5e94\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u7814\u7a76\u3002\u4e00\u7cfb\u5217\u542b\u7ed9\u7535\u5b50\u6216\u5438\u7535\u5b50\u57fa\u56e2\u7684\u82b3\u9999\u919b\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u4ea7\u7387\u987a\u5229\u5730\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u9170\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u542b\u6709\u567b\u5429\u73af\u3001\u544b\u5583\u73af\u3001\u82ef\u5e76\u544b\u5583\u73af\u3001\u82ef\u5e76\u567b\u5429\u73af\u6216\u5421\u5511\u73af\u7b49\u6742\u73af\u7684\u82b3\u9999\u919b\u4e5f\u53ef\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u6742\u82b3\u9170\u80fa\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8102\u80aa\u919b\u4e00\u822c\u8f83\u96be\u8f6c\u5316\uff0c\u4f46\u5728\u8be5\u4f53\u7cfb\u4e2d\uff0c\u53cd\u5e94\u4e5f\u80fd\u987a\u5229\u8fdb\u884c\uff08\u56fe2\uff09\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/6-10.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42249 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/6-10.png\" alt=\"\" width=\"652\" height=\"885\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/6-10.png 652w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/6-10-221x300.png 221w\" sizes=\"(max-width: 652px) 100vw, 652px\" \/><\/a><\/p>\n<p style=\"font-weight: 400; text-align: center;\">\u56fe2. \u919b\u7684\u5e95\u7269\u8303\u56f4<\/p>\n<p style=\"font-weight: 400; text-align: center;\">\uff08\u56fe\u7247\u6765\u6e90: <em>Org. Lett.<\/em>\uff09<\/p>\n<p style=\"font-weight: 400;\">\u968f\u540e\uff0c\u4f5c\u8005\u63a2\u7a76\u4e86\u50ac\u5316\u4f53\u7cfb\u5bf9\u785d\u57fa\u82b3\u9999\u65cf\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\uff08\u56fe3\uff09\u3002\u542b\u6709\u5364\u7d20\u539f\u5b50\uff08F\u3001Cl\u3001Br\u548cI\uff09\u7684\u785d\u57fa\u82ef\u4ee5\u826f\u597d\u7684\u4ea7\u7387\u987a\u5229\u5730\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u9170\u80fa\u3002\u6b64\u5916\uff0c\u7532\u6c27\u57fa\u3001\u8148\u3001\u82ef\u786b\u57fa\u3001\u65b0\u620a\u6c27\u57fa\u548c\u9170\u57fa\u7b49\u591a\u79cd\u542b\u6742\u539f\u5b50\u5b98\u80fd\u56e2\u4e5f\u53ef\u4ee5\u5f88\u597d\u7684\u5f97\u5230\u517c\u5bb9\uff0c\u5e76\u8f6c\u5316\u5f97\u5230\u76f8\u5e94\u7684\u4ea7\u7269\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/7-9.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42250 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/7-9.png\" alt=\"\" width=\"575\" height=\"662\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/7-9.png 575w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/7-9-261x300.png 261w\" sizes=\"(max-width: 575px) 100vw, 575px\" \/><\/a><\/p>\n<p style=\"font-weight: 400; text-align: center;\">\u56fe3. \u785d\u57fa\u82b3\u9999\u65cf\u5e95\u7269\u8303\u56f4<\/p>\n<p style=\"font-weight: 400; text-align: center;\">\uff08\u56fe\u7247\u6765\u6e90: <em>Org. Lett.<\/em>\uff09<\/p>\n<p style=\"font-weight: 400;\">\u6b64\u5916\uff0c\u8be5\u50ac\u5316\u4f53\u7cfb\u8fd8\u53ef\u4ee5\u4ee5\u9187\u4e3a\u8d77\u59cb\u539f\u6599\u5408\u6210\u9170\u80fa\u3002\u4e00\u7cfb\u5217\u542b\u7ed9\u7535\u5b50\u6216\u5438\u7535\u5b50\u57fa\u56e2\u7684\u82c4\u57fa\u9187\u4e0e\u785d\u57fa\u82ef\u53cd\u5e94\uff0c\u4ee5\u4e2d\u7b49\u7684\u4ea7\u7387\u987a\u5229\u8f6c\u5316\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff08\u56fe4\uff09\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/8-9.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42251 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/8-9.png\" alt=\"\" width=\"556\" height=\"427\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/8-9.png 556w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/8-9-300x230.png 300w\" sizes=\"(max-width: 556px) 100vw, 556px\" \/><\/a><\/p>\n<p style=\"font-weight: 400; text-align: center;\">\u56fe4. \u9187\u5e95\u7269\u8303\u56f4<\/p>\n<p style=\"font-weight: 400; text-align: center;\">\uff08\u56fe\u7247\u6765\u6e90: <em>Org. Lett.<\/em>\uff09<\/p>\n<p style=\"font-weight: 400;\">\u6700\u540e\uff0c\u901a\u8fc7\u4e00\u7cfb\u5217\u673a\u7406\u5b9e\u9a8c\uff0c\u4f5c\u8005\u4e5f\u63d0\u51fa\u4e86\u8be5\u53cd\u5e94\u7684\u50ac\u5316\u5faa\u73af\uff08\u56fe5\uff09\u3002\u4e09\u4ef7\u94c1\u50ac\u5316\u5242\u5728\u5149\u7167\u4e0b\u901a\u8fc7\u914d\u4f53-\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb(LMCT)\u8fc7\u7a0b\u751f\u6210\u6c2f\u81ea\u7531\u57fa\u548cFe(II)\u3002\u968f\u540e\uff0c\u4e00\u65b9\u9762\uff0c\u6c2f\u81ea\u7531\u57fa\u548cDCE\u4e4b\u95f4\u7684\u6c22\u539f\u5b50\u8f6c\u79fb\uff0c\u751f\u6210<strong>Int-I<\/strong>\u548cHCl\u3002<strong>Int-I<\/strong>\u53ef\u4ee5\u901a\u8fc7\u4e2d\u95f4\u4f53<strong>Int-II<\/strong>\u4fc3\u8fdb\u785d\u57fa\u82ef\u8fd8\u539f\u4e3a<strong>Int-III<\/strong>\u7269\u79cd\uff0c\u8be5\u7269\u79cd\u53ef\u4ee5\u4e3a\u4e9a\u785d\u57fa\u82ef\u3001\u5076\u6c2e\u82ef\u3001\u5076\u6c2e\u82ef\u7b49\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u6c2f\u81ea\u7531\u57fa\u8fd8\u53ef\u4ee5\u4ece\u82ef\u7532\u919b\u4e2d\u652b\u53d6\u6c22\u539f\u5b50\u751f\u6210\u9170\u57fa\u81ea\u7531\u57fa(<strong>Int-IV<\/strong>)\uff0c\u5b83\u53ef\u4ee5\u4e0e<strong>Int-III<\/strong><strong>\u76f4\u63a5<\/strong>\u53cd\u5e94\u751f\u6210<strong>Int-V<\/strong>\u6216\u4e0e\u6c2f\u81ea\u7531\u57fa\u5076\u8054\u751f\u6210\u9170\u6c2f<strong>Int-VII<\/strong>\u3002\u63a5\u4e0b\u6765\uff0c<strong>Int-V<\/strong>\u5728\u94c1\u50ac\u5316\u4f53\u7cfb\u4e0b\u5c06\u518d\u751f\u4e09\u4ef7\u94c1\u548c<strong>Int-VI<\/strong>\uff0c\u9170\u6c2f<strong>Int-VII<\/strong>\u4e0e<strong>Int-III<\/strong>\u7684\u76f4\u63a5\u53cd\u5e94\u4e5f\u53ef\u4ee5\u751f\u6210<strong>Int-VI<\/strong>\u3002\u6700\u540e\uff0c<strong>Int-VI<\/strong>\u5728\u8be5\u6761\u4ef6\u4e0b\u88ab\u8fd8\u539f\u751f\u6210\u6700\u7ec8\u7684\u9170\u80fa\u4ea7\u7269<strong>3<\/strong>\u3002\u5f53\u4f7f\u7528\u82c4\u9187\u4f5c\u4e3a\u5e95\u7269\u65f6\uff0c\u9996\u5148\u53d1\u751f\u7684\u662f\u785d\u57fa\u82ef\u6c27\u5316\u9187\u751f\u6210\u76f8\u5e94\u7684\u919b\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/9-6.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-42252 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/9-6.png\" alt=\"\" width=\"664\" height=\"383\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/9-6.png 664w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/9-6-300x173.png 300w\" sizes=\"(max-width: 664px) 100vw, 664px\" \/><\/a><\/p>\n<p style=\"font-weight: 400; text-align: center;\">\u56fe5. \u50ac\u5316\u5faa\u73af<\/p>\n<p style=\"font-weight: 400; text-align: center;\">\uff08\u56fe\u7247\u6765\u6e90: <em>Org. Lett.<\/em>\uff09<\/p>\n<h4 style=\"font-weight: 400;\">\u603b\u7ed3<\/h4>\n<p style=\"font-weight: 400;\">\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u3001\u674e\u6d0b\u526f\u6559\u6388\u57fa\u4e8e\u5149\u4fc3\u94c1\u50ac\u5316\uff0c\u53d1\u5c55\u4e86\u919b\u3001\u9187\u4e0e\u785d\u57fa\u82ef\u7684\u76f4\u63a5\u5076\u8054\u5408\u6210\u9170\u80fa\u7c7b\u5316\u5408\u7269\u7684\u4e00\u79cd\u65b0\u65b9\u6cd5\u3002\u8be5\u53cd\u5e94\u4f7f\u7528\u5ec9\u4ef7\u6613\u5f97\u7684\u94c1\u50ac\u5316\u5242\uff0c\u7ed3\u5408\u53ef\u89c1\u5149\u50ac\u5316\uff0c\u5177\u6709\u826f\u597d\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u548c\u5b98\u80fd\u56e2\u5bb9\u5fcd\u6027\u3001\u65e0\u9700\u989d\u5916\u7684\u6c27\u5316\u5242\u548c\u6d3b\u5316\u8bd5\u5242\u4ee5\u53ca\u7eff\u8272\u7ecf\u6d4e\u7b49\u7684\u4f18\u70b9\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cMild Amide Synthesis Using Nitrobenzene under Neutral Conditions\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8e<em>Organic Letters<\/em>\u3002\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u535a\u58eb\u7814\u7a76\u751f\u718a\u6ce5\u4e3a\u8be5\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\uff0c\u5316\u5b66\u5b66\u9662\u4e24\u4f4d\u672c\u79d1\u751f\u8463\u6c85\u742a\u548c\u5f90\u658c\u4e3a\u8be5\u8bba\u6587\u7684\u5171\u540c\u7b2c\u4e8c\u4f5c\u8005\uff0c\u66fe\u8363\u6559\u6388\u548c\u674e\u6d0b\u526f\u6559\u6388\u4e3a\u672c\u5de5\u4f5c\u7684\u901a\u8baf\u4f5c\u8005\u3002<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"\u5bfc\u8bed \u9170\u80fa\u662f\u6709\u673a\u5316\u5b66\u4e2d\u6700\u91cd\u8981\u7684\u5b98\u80fd\u56e2\u4e4b\u4e00\uff0c\u5728\u6709\u673a\u5408\u6210\u3001\u751f\u547d\u5316\u5b66\u3001\u6709\u673a\u6750\u6599\u5316\u5b66\u548c\u836f\u7269\u5316\u5b66\u4e2d\u90fd\u6709\u7740\u4e3e\u8db3\u8f7b\u91cd\u7684\u4f5c\u7528\u3002\u4f20\u7edf\u4e0a\uff0c\u7edd\u5927\u591a\u6570\u9170\u80fa\u5408\u6210\u4f9d\u8d56\u4e8e\u80fa\u4e0e\u7fa7\u9178\u53ca\u5176\u884d\u751f\u7269(\u5982\u9170\u6c2f\u548c\u9178\u9150)\u7684\u7f29\u5408\u53cd\u5e94\u3002\u5c3d\u7ba1\u8fd9\u4e9b\u65b9\u6cd5\u9ad8\u6548\u65b9\u4fbf\uff0c\u4f46\u901a\u5e38\u9700\u8981\u5316\u5b66\u8ba1\u91cf\u6d3b\u5316\u5242\uff0c\u5e76\u4f1a\u4ea7\u751f\u5f53\u91cf\u4ee5\u4e0a\u7684\u5e9f\u6599\u3002\u9274\u4e8e\u6c28\u57fa\u5316\u5408\u7269\u5f80\u5f80\u662f\u901a\u8fc7\u785d\u57fa\u5316\u5408\u7269\u8fd8\u539f\u6765\u5f97\u5230\u7684\uff0c\u76f4\u63a5\u4f7f\u7528\u785d\u57fa\u82b3\u70c3\u4f5c\u4e3a\u6c2e\u6e90\u5408\u6210\u9170\u80fa\u7c7b\u5316\u5408\u7269\u4fbf\u663e\u5f97\u6781\u6709\u610f\u4e49\u3002\u7136\u800c\uff0c\u5f53\u4f7f\u7528\u785d\u57fa\u5316\u5408\u7269\u4f5c\u4e3a\u80fa\u6e90\uff0c\u8fd9\u7c7b\u53cd\u5e94\u4ecd\u7136\u9700\u8981\u8fc7\u91cf\u7684\u8fd8\u539f\u5242\uff0c\u5982\u950c\u3001\u9530\u3001\u7845\u70f7\u7b49\uff0c\u53bb\u539f\u4f4d\u8fd8\u539f\u5e76\u4fc3\u8fdb\u53cd\u5e94\u7684\u53d1\u751f\u3002\u9488\u5bf9\u5982\u4f55\u907f\u514d\u4f7f\u7528\u8fc7\u91cf\u5f3a\u8fd8\u539f\u5242\u7684\u95ee\u9898\uff0c\u8fd1\u65e5\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u3001\u674e\u6d0b\u526f\u6559\u6388\u4f7f\u7528\u785d\u57fa\u82b3\u70c3\u4f5c\u4e3a\u6c2e\u6e90\uff0c\u62a5\u9053\u4e86\u65e0\u9700\u989d\u5916\u7684\u6c27\u5316\u8fd8\u539f\u8bd5\u5242\u53ca\u6d3b\u5316\u5242\u7684\u9170\u80fa\u5408\u6210\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u901a\u8fc7\u5728\u5149\u7167\u4e0b\uff0c\u4f7f\u7528\u5ec9\u4ef7\u7684\u4e09\u4ef7\u94c1\u4f5c\u4e3a\u50ac\u5316\u5242\u6765\u76f4\u63a5\u5b9e\u73b0\u785d\u57fa\u5316\u5408\u7269\u4e0e\u919b\u3001\u9187\u7684\u5076\u8054\u53cd\u5e94\uff0c\u53d1\u5c55\u4e86\u4e00\u79cd\u5408\u6210\u9170\u80fa\u7684\u65b0\u65b9\u6cd5\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cMild Amide Synthesis Using Nitrobenzene under Neutral Conditions\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u4e8eOrg. Lett. 2022.\uff08DOI:\u00a010.1021\/acs.orglett.2c01743\uff09\u3002 \u66fe\u8363\u6559\u6388\u7b80\u4ecb\uff1a \u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u6559\u6388\uff0c\u6d77\u5916\u9ad8\u5c42\u6b21\u4eba\u624d\u8ba1\u5212\u3001\u897f\u4ea4\u201c\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212\u201dA\u7c7b\u5165\u9009\u8005\uff0c\u535a\u5bfc\u30022008\u5e74\u4e8e\u6d59\u6c5f\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u540e\u76f4\u535a\u672c\u6821\uff0c\u5e76\u4e8e2013\u5e74\u53d6\u5f97\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u9ebb\u751f\u660e\u9662\u58eb\uff0c\u4e3b\u8981\u7814\u7a76\u8054\u70ef\u53c2\u4e0e\u7684\u81ea\u7531\u57fa\u52a0\u6210\u4ee5\u53ca\u78b3\u6c22\u5b98\u80fd\u56e2\u5316\u30022013\u5e74\u81f32016\u5e74\uff0c\u5728\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u4e01\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08\u8463\u5e7f\u5f6c\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u975e\u5f20\u529b\u73af\u916e\u7684\u78b3\u78b3\u952e\u6d3b\u5316\u5076\u8054\u30022016\u5e74\u81f32018\u5e74\uff0c\u5728\u4ee5\u8272\u5217\u5a01\u5179\u66fc\u79d1\u5b66\u7814\u7a76\u6240\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\uff0c\u5408\u4f5c\u5bfc\u5e08David Milstein\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3aPincer\u7edc\u5408\u7269\u5408\u6210\u4ee5\u53ca\u5728\u4e00\u6c27\u5316\u4e8c\u6c2e\u6d3b\u5316\u4e2d\u7684\u5e94\u7528\u30022018\u5e74\u56de\u56fd\u540e\u7684\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u5ec9\u4ef7\u91d1\u5c5e\u50ac\u5316\u65b0\u65b9\u6cd5\u7684\u5f00\u53d1\u548c\u5e94\u7528\u3002\u76ee\u524d\u5728J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u3001ACS Catal.\u7b49\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520a\u53d1\u8868\u7cfb\u5217\u8bba\u6587\uff0c\u6388\u6743\u4e2d\u56fd\u4e13\u52293\u9879\u3002Email:\u00a0rongzeng@xjtu.edu.cn. \u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\uff1a \u66fe\u8363\u8bfe\u9898\u7ec4\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u5ec9\u4ef7\u91d1\u5c5e\u50ac\u5316\u65b0\u65b9\u6cd5\u7684\u5f00\u53d1\u548c\u5e94\u7528\u3002 \u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002 \u6b64\u5916\uff0c\u56e0\u53d1\u5c55\u9700\u8981\uff0c\u66fe\u8363\u8bfe\u9898\u7ec4\u9762\u5411\u793e\u4f1a\u516c\u5f00\u62db\u8058\u9752\u79c0\u4eba\u624d\u4ee5\u53ca\u79d1\u7814\u52a9\u7406\u3002 \u9752\u79c0\u8ba1\u5212\u662f\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u7684\u5e08\u8d44\u535a\u58eb\u540e\u8ba1\u5212\uff0c\u8058\u671f\u5185\u8003\u6838\u5408\u683c\u8f6c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u526f\u6559\u6388\u3002 \u9752\u79c0\u4eba\u624d\u4e2a\u4eba\u5f85\u9047\uff1a\u4eab\u53d7\u5b66\u6821\u63d0\u4f9b\u9752\u79c0\u4eba\u624d\u7684\u4e00\u5207\u5f85\u9047\u3002\u8be6\u60c5\u8bf7\u89c1\uff1a\u5176\u4e2d\uff0cA\u7c7b\u9752\u79c0\u5e74\u85aa30\u4e07\uff1bB\u7c7b\u9752\u79c0\u5e74\u85aa16-20\u4e07\u3002\u9752\u79c0 \u9752\u79c0\u8ba1\u5212\u8868\u73b0\u4f18\u5f02\u8005\uff0c\u4f18\u5148\u63a8\u8350\u7533\u8bf7\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u9752\u5e74\u62d4\u5c16\u4eba\u624d\u8ba1\u5212\u3002 \u7814\u7a76\u52a9\u7406\uff1a\u7855\u58eb\u6bd5\u4e1a\u6216\u5373\u5c06\u6bd5\u4e1a\uff1b\u5177\u6709\u6709\u673a\u5316\u5b66\u80cc\u666f\uff1b\u53d1\u8868\u8fc7\u82f1\u6587\u8bba\u6587\uff0c\u6709\u4e00\u5b9a\u7684\u82f1\u6587\u4e66\u5199\u80fd\u529b\u3002\u8868\u73b0\u4f18\u5f02\u8005\u4f18\u5148\u63a8\u8350\u535a\u58eb\u7533\u8bf7\u3002 \u8054\u7cfb\u65b9\u5f0fEmail:\u00a0rongzeng@xjtu.edu.cn. \u674e\u6d0b\u526f\u6559\u6388\u7b80\u4ecb\uff1a \u897f\u5b89\u4ea4\u901a\u5927\u5b66\u5316\u5b66\u5b66\u9662\u526f\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\u30022010\u5e74\u4e8e\u5170\u5dde\u5927\u5b66\u53d6\u5f97\u5b66\u58eb\u5b66\u4f4d\u30022015\u5e74\u4e8e\u4e0a\u6d77\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u53d6\u5f97\u6709\u673a\u5316\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u6211\u56fd\u8457\u540d\u6709\u673a\u5316\u5b66\u5bb6\u4e01\u594e\u5cad\u9662\u58eb\uff0c\u4e3b\u8981\u4ece\u4e8b\u624b\u6027\u914d\u4f53\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u4e0d\u5bf9\u79f0\u50ac\u5316\u6c22\u5316\u53cd\u5e94\u7684\u7814\u7a76\u30022017\u5e74\u81f32018\u5e74\u5728\u7f8e\u56fd\u65af\u514b\u91cc\u666e\u65af\u7814\u7a76\u6240\u505a\u8bbf\u95ee\u5b66\u8005\u7814\u7a76\uff0c\u5408\u4f5c\u5bfc\u5e08\u4f59\u91d1\u6743\uff08Jin-Quan Yu\uff09\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411\u4e3a\u94af\u50ac\u5316C-H\u952e\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u30022015\u5e747\u6708\u52a0\u5165\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u4ece\u4e8b\u72ec\u7acb\u7814\u7a76\u5de5\u4f5c\u3002\u4e3b\u8981\u4ece\u4e8b\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u60f0\u6027\u5316\u5b66\u952e\u6d3b\u5316\u53ca\u70ef\u7094\u7684\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\u7814\u7a76\u3002\u8fc4\u4eca\u4e3a\u6b62\u56fd\u9645\u4e3b\u6d41\u5b66\u672f\u671f\u520aAngew. Chem. Int. Ed.\u3001Org. Lett.\u3001Org. Chem. Front.\u3001Chem. -Eur. J.\u7b49\u53d1\u8868\u8bba\u6587\u591a\u7bc7\u3002 \u6b22\u8fce\u7855\u58eb\u7814\u7a76\u751f\u3001\u535a\u58eb\u7814\u7a76\u751f\u7684\u79ef\u6781\u62a5\u8003\u3002 Email: yanglee@mail.xjtu.edu.cn\u3002 \u524d\u6cbf\u79d1\u7814\u6210\u679c\uff1a\u6e29\u548c\u6761\u4ef6\u4e0b\u785d\u57fa\u82ef\u76f4\u63a5\u5408\u6210\u9170\u80fa \u8fd1\u5e74\u6765\uff0c\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5df2\u7ecf\u6210\u4e3a\u4e00\u79cd\u5f3a\u5927\u800c\u72ec\u7279\u7684\u5de5\u5177\uff0c\u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u8bfe\u9898\u7ec4\u56f4\u7ed5\u5149\u4fc3\u94c1\u50ac\u5316\u5c55\u5f00\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u5de5\u4f5c\u3002\u76ee\u524d\u5df2\u7ecf\u5728\u8be5\u7814\u7a76\u65b9\u5411\u53d6\u5f97\u4e86\u8bf8\u591a\u8fdb\u5c55\u5e76\u5728\u56fd\u5185\u5916\u77e5\u540d\u5b66\u672f\u671f\u520a\u53d1\u8868\u591a\u7bc7\u7814\u7a76\u8bba\u6587\uff08Org. Lett. 2021, 23, 2915-2920; Chin. J. Chem. 2021, 39, 3225-3230; Org. Lett. 2021, 23, 8968-8972; Org. Lett. 2022, 24, 977-982; Org. Chem. Front. 2022, DOI: 10.1039\/D2QO00709F\uff09\u3002\u8fd1\u65e5\uff0c\u56e2\u961f\u53c8\u5728\u8be5\u7814\u7a76\u9886\u57df\u53d6\u5f97\u4e86\u65b0\u8fdb\u5c55\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u94c1\u5149\u50ac\u5316\u785d\u57fa\u82ef\u4f5c\u4e3a\u6c2e\u6e90\u5408\u6210\u9170\u80fa\u7684\u65b0\u65b9\u6cd5\uff08\u56fe 1\uff09\u3002 \u56fe1. \u785d\u57fa\u82ef\u4f5c\u4e3a\u6c2e\u6e90\u5408\u6210\u9170\u80fa \uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09 \u4f5c\u8005\u9996\u5148\u901a\u8fc7\u785d\u57fa\u82ef\u548c\u82ef\u7532\u919b\u8f6c\u5316\u5408\u6210\u9170\u80fa\u7684\u53cd\u5e94\u8fdb\u884c\u4e86\u4f18\u5316\uff0c\u5e76\u5f97\u5230\u4e86\u6700\u4f18\u7684\u53cd\u5e94\u6761\u4ef6\uff0c\u80fd\u591f\u4ee578%\u7684\u5206\u79bb\u4ea7\u7387\u5f97\u5230\u9170\u80fa\uff0c\u8868\u660e\u5149\u4fc3\u94c1\u50ac\u5316\u5177\u6709\u8f83\u9ad8\u7684\u6d3b\u6027\u3002\u968f\u540e\u5bf9\u8be5\u53cd\u5e94\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u7814\u7a76\u3002\u4e00\u7cfb\u5217\u542b\u7ed9\u7535\u5b50\u6216\u5438\u7535\u5b50\u57fa\u56e2\u7684\u82b3\u9999\u919b\u4ee5\u4e2d\u7b49\u81f3\u826f\u597d\u7684\u4ea7\u7387\u987a\u5229\u5730\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u9170\u80fa\u7c7b\u5316\u5408\u7269\uff0c\u542b\u6709\u567b\u5429\u73af\u3001\u544b\u5583\u73af\u3001\u82ef\u5e76\u544b\u5583\u73af\u3001\u82ef\u5e76\u567b\u5429\u73af\u6216\u5421\u5511\u73af\u7b49\u6742\u73af\u7684\u82b3\u9999\u919b\u4e5f\u53ef\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u6742\u82b3\u9170\u80fa\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u8102\u80aa\u919b\u4e00\u822c\u8f83\u96be\u8f6c\u5316\uff0c\u4f46\u5728\u8be5\u4f53\u7cfb\u4e2d\uff0c\u53cd\u5e94\u4e5f\u80fd\u987a\u5229\u8fdb\u884c\uff08\u56fe2\uff09\u3002 \u56fe2. \u919b\u7684\u5e95\u7269\u8303\u56f4 \uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09 \u968f\u540e\uff0c\u4f5c\u8005\u63a2\u7a76\u4e86\u50ac\u5316\u4f53\u7cfb\u5bf9\u785d\u57fa\u82b3\u9999\u65cf\u5e95\u7269\u7684\u9002\u7528\u8303\u56f4\uff08\u56fe3\uff09\u3002\u542b\u6709\u5364\u7d20\u539f\u5b50\uff08F\u3001Cl\u3001Br\u548cI\uff09\u7684\u785d\u57fa\u82ef\u4ee5\u826f\u597d\u7684\u4ea7\u7387\u987a\u5229\u5730\u8f6c\u5316\u4e3a\u76f8\u5e94\u7684\u9170\u80fa\u3002\u6b64\u5916\uff0c\u7532\u6c27\u57fa\u3001\u8148\u3001\u82ef\u786b\u57fa\u3001\u65b0\u620a\u6c27\u57fa\u548c\u9170\u57fa\u7b49\u591a\u79cd\u542b\u6742\u539f\u5b50\u5b98\u80fd\u56e2\u4e5f\u53ef\u4ee5\u5f88\u597d\u7684\u5f97\u5230\u517c\u5bb9\uff0c\u5e76\u8f6c\u5316\u5f97\u5230\u76f8\u5e94\u7684\u4ea7\u7269\u3002 \u56fe3. \u785d\u57fa\u82b3\u9999\u65cf\u5e95\u7269\u8303\u56f4 \uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09 \u6b64\u5916\uff0c\u8be5\u50ac\u5316\u4f53\u7cfb\u8fd8\u53ef\u4ee5\u4ee5\u9187\u4e3a\u8d77\u59cb\u539f\u6599\u5408\u6210\u9170\u80fa\u3002\u4e00\u7cfb\u5217\u542b\u7ed9\u7535\u5b50\u6216\u5438\u7535\u5b50\u57fa\u56e2\u7684\u82c4\u57fa\u9187\u4e0e\u785d\u57fa\u82ef\u53cd\u5e94\uff0c\u4ee5\u4e2d\u7b49\u7684\u4ea7\u7387\u987a\u5229\u8f6c\u5316\u5f97\u5230\u76ee\u6807\u4ea7\u7269\uff08\u56fe4\uff09\u3002 \u56fe4. \u9187\u5e95\u7269\u8303\u56f4 \uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09 \u6700\u540e\uff0c\u901a\u8fc7\u4e00\u7cfb\u5217\u673a\u7406\u5b9e\u9a8c\uff0c\u4f5c\u8005\u4e5f\u63d0\u51fa\u4e86\u8be5\u53cd\u5e94\u7684\u50ac\u5316\u5faa\u73af\uff08\u56fe5\uff09\u3002\u4e09\u4ef7\u94c1\u50ac\u5316\u5242\u5728\u5149\u7167\u4e0b\u901a\u8fc7\u914d\u4f53-\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb(LMCT)\u8fc7\u7a0b\u751f\u6210\u6c2f\u81ea\u7531\u57fa\u548cFe(II)\u3002\u968f\u540e\uff0c\u4e00\u65b9\u9762\uff0c\u6c2f\u81ea\u7531\u57fa\u548cDCE\u4e4b\u95f4\u7684\u6c22\u539f\u5b50\u8f6c\u79fb\uff0c\u751f\u6210Int-I\u548cHCl\u3002Int-I\u53ef\u4ee5\u901a\u8fc7\u4e2d\u95f4\u4f53Int-II\u4fc3\u8fdb\u785d\u57fa\u82ef\u8fd8\u539f\u4e3aInt-III\u7269\u79cd\uff0c\u8be5\u7269\u79cd\u53ef\u4ee5\u4e3a\u4e9a\u785d\u57fa\u82ef\u3001\u5076\u6c2e\u82ef\u3001\u5076\u6c2e\u82ef\u7b49\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u6c2f\u81ea\u7531\u57fa\u8fd8\u53ef\u4ee5\u4ece\u82ef\u7532\u919b\u4e2d\u652b\u53d6\u6c22\u539f\u5b50\u751f\u6210\u9170\u57fa\u81ea\u7531\u57fa(Int-IV)\uff0c\u5b83\u53ef\u4ee5\u4e0eInt-III\u76f4\u63a5\u53cd\u5e94\u751f\u6210Int-V\u6216\u4e0e\u6c2f\u81ea\u7531\u57fa\u5076\u8054\u751f\u6210\u9170\u6c2fInt-VII\u3002\u63a5\u4e0b\u6765\uff0cInt-V\u5728\u94c1\u50ac\u5316\u4f53\u7cfb\u4e0b\u5c06\u518d\u751f\u4e09\u4ef7\u94c1\u548cInt-VI\uff0c\u9170\u6c2fInt-VII\u4e0eInt-III\u7684\u76f4\u63a5\u53cd\u5e94\u4e5f\u53ef\u4ee5\u751f\u6210Int-VI\u3002\u6700\u540e\uff0cInt-VI\u5728\u8be5\u6761\u4ef6\u4e0b\u88ab\u8fd8\u539f\u751f\u6210\u6700\u7ec8\u7684\u9170\u80fa\u4ea7\u72693\u3002\u5f53\u4f7f\u7528\u82c4\u9187\u4f5c\u4e3a\u5e95\u7269\u65f6\uff0c\u9996\u5148\u53d1\u751f\u7684\u662f\u785d\u57fa\u82ef\u6c27\u5316\u9187\u751f\u6210\u76f8\u5e94\u7684\u919b\u3002 \u56fe5. \u50ac\u5316\u5faa\u73af \uff08\u56fe\u7247\u6765\u6e90: Org. Lett.\uff09 \u603b\u7ed3 \u897f\u5b89\u4ea4\u901a\u5927\u5b66\u66fe\u8363\u6559\u6388\u3001\u674e\u6d0b\u526f\u6559\u6388\u57fa\u4e8e\u5149\u4fc3\u94c1\u50ac\u5316\uff0c\u53d1\u5c55\u4e86\u919b\u3001\u9187\u4e0e\u785d\u57fa\u82ef\u7684\u76f4\u63a5\u5076\u8054\u5408\u6210\u9170\u80fa\u7c7b\u5316\u5408\u7269\u7684\u4e00\u79cd\u65b0\u65b9\u6cd5\u3002\u8be5\u53cd\u5e94\u4f7f\u7528\u5ec9\u4ef7\u6613\u5f97\u7684\u94c1\u50ac\u5316\u5242\uff0c\u7ed3\u5408\u53ef\u89c1\u5149\u50ac\u5316\uff0c\u5177\u6709\u826f\u597d\u7684\u5e95\u7269\u9002\u7528\u8303\u56f4\u548c\u5b98\u80fd\u56e2\u5bb9\u5fcd\u6027\u3001\u65e0\u9700\u989d\u5916\u7684\u6c27\u5316\u5242\u548c\u6d3b\u5316\u8bd5\u5242\u4ee5\u53ca\u7eff\u8272\u7ecf\u6d4e\u7b49\u7684\u4f18\u70b9\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cMild Amide Synthesis Using Nitrobenzene under Neutral [&hellip;]","protected":false},"author":26,"featured_media":42248,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1271],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/06\/5-10.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-aZv","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/42253"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=42253"}],"version-history":[{"count":1,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/42253\/revisions"}],"predecessor-version":[{"id":42254,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/42253\/revisions\/42254"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/42248"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=42253"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=42253"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=42253"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}