{"id":43208,"date":"2022-10-13T08:00:52","date_gmt":"2022-10-13T00:00:52","guid":{"rendered":"\/\/www.gsbet888.com\/?p=43208"},"modified":"2022-10-02T16:00:05","modified_gmt":"2022-10-02T08:00:05","slug":"angew%ef%bc%9a%e6%9c%89%e6%9c%ba%e5%85%89%e5%82%ac%e5%8c%96%e7%9a%84%e5%8c%ba%e5%9f%9f%e9%80%89%e6%8b%a9%e6%80%a7c-h%e7%83%b7%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6%e7%a0%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2022\/10\/angew%ef%bc%9a%e6%9c%89%e6%9c%ba%e5%85%89%e5%82%ac%e5%8c%96%e7%9a%84%e5%8c%ba%e5%9f%9f%e9%80%89%e6%8b%a9%e6%80%a7c-h%e7%83%b7%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6%e7%a0%94.html","title":{"rendered":"Angew\uff1a\u6709\u673a\u5149\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\u7814\u7a76"},"content":{"rendered":"<p>\u672c\u6587\u4f5c\u8005:\u00a0<em><i>C<\/i><\/em><em><i>oca<\/i><\/em><em><i>\u00a0<\/i><\/em><em><i>or<\/i><\/em><em><i>\u00a0P<\/i><\/em><em><i>epsi<\/i><\/em><\/p>\n<h2><strong><b>\u5bfc\u8bfb<\/b><\/strong><\/h2>\n<p>\u8fd1\u65e5\uff0c\u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u8212\u4f1f\u7814\u7a76\u56e2\u961f\u5728<em><i>Angew. Chem. Int. Ed.<\/i><\/em>\u4e0a\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u91c7\u7528\u6d3b\u5316\u6216\u672a\u6d3b\u5316\u70ef\u57fa\u5316\u5408\u7269\u4e0e\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u4e4b\u95f4\u7684\u65e0\u91d1\u5c5e\u5149\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u7ebf\u6027\u70f7\u57fa\u5316\u7684\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u7684\u6784\u5efa\u3002<\/p>\n<blockquote><p>Organophotocatalytic Regioselective C\u2212H Alkylation of Electron-Rich Arenes Using Activated and Unactivated Alkenes<\/p>\n<p>B. Chen, Y. Du, W. Shu, <em><i>Angew. Chem. Int. Ed.<\/i><\/em><strong><b>2022<\/b><\/strong>, <em><i>61<\/i><\/em>, e202200773. doi: <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202200773\"><u>10.1002\/anie.202200773<\/u><\/a>.<\/p><\/blockquote>\n<h2><strong><b>\u6b63\u6587<\/b><\/strong><\/h2>\n<p>\u82b3\u9999\u5316\u5408\u7269\u53c2\u4e0e\u7684\u76f4\u63a5C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\u662f\u83b7\u5f97\u70f7\u57fa\u5316\u82b3\u9999\u5206\u5b50\u7684\u91cd\u8981\u7b56\u7565\u4e4b\u4e00 (Scheme 1)<sup>\u00a0[<\/sup><sup>1]-<\/sup><sup>[<\/sup><sup>9]<\/sup>\u3002\u7136\u800c\uff0c\u5728\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u5b9e\u73b0\u5404\u7c7b\u82b3\u9999\u5206\u5b50\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u8fc7\u7a0b\uff0c\u76ee\u524d\u4ecd\u9762\u4e34\u5de8\u5927\u7684\u6311\u6218\u3002\u8fd9\u91cc\u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u8212\u4f1f\u56e2\u961f\u6210\u529f\u8bbe\u8ba1\u51fa\u4e00\u79cd\u5168\u65b0\u7684\u91c7\u7528\u6d3b\u5316\u6216\u672a\u6d3b\u5316\u70ef\u57fa\u5316\u5408\u7269\u4e0e\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u4e4b\u95f4\u7684\u65e0\u91d1\u5c5e\u5149\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-43210 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-689.png\" alt=\"\" width=\"1210\" height=\"1394\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-689.png 1210w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-689-260x300.png 260w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-689-680x783.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-689-768x885.png 768w\" sizes=\"(max-width: 1210px) 100vw, 1210px\" \/><\/p>\n<p>\u9996\u5148\uff0c\u4f5c\u8005\u91c7\u75283-\u7532\u6c27\u57fa\u567b\u5429\u00a0(1a)\u4e0e1,1-\u4e8c\u82ef\u57fa\u4e59\u70ef(2a)\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u533a\u57df\u9009\u62e9\u6027C-H\u2009\u70f7\u57fa\u5316\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528Mes-3,6-<em><i>t<\/i><\/em>-Bu<sub>2<\/sub>-Acr-Ph<sup>+<\/sup>BF<sub>4<\/sub><sup>&#8211;<\/sup>\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\uff0c2-NH<sub>2<\/sub>-4-ClPhSH\u4f5c\u4e3aHAT\u50ac\u5316\u5242\uff0c\u82ef\u4e09\u6c1f\u7532\u70f7\u4f5c\u4e3a\u6eb6\u5242\uff0c\u84dd\u5149LED\u8f90\u5c04\u4e0b\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a\u5ba4\u6e29\uff0c\u8fdb\u800c\u83b7\u5f97\u76f8\u5e94\u7684C-H\u2009\u70f7\u57fa\u5316\u4ea7\u72693a\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-43211 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-885.png\" alt=\"\" width=\"1185\" height=\"1477\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-885.png 1185w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-885-241x300.png 241w, 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srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-1296.png 1210w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-1296-300x225.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-1296-680x509.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-1296-768x575.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2022\/10\/Coca-or-Pepsi-20220608-1296-265x197.png 265w\" sizes=\"(max-width: 1210px) 100vw, 1210px\" \/><\/p>\n<h2><strong><b>\u603b\u7ed3<\/b><\/strong><\/h2>\n<p>\u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u8212\u4f1f\u7814\u7a76\u56e2\u961f\u6210\u529f\u8bbe\u8ba1\u51fa\u4e00\u79cd\u5168\u65b0\u7684\u91c7\u7528\u6d3b\u5316\u6216\u672a\u6d3b\u5316\u70ef\u57fa\u5316\u5408\u7269\u4e0e\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u4e4b\u95f4\u7684\u65e0\u91d1\u5c5e\u5149\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u7ebf\u6027\u70f7\u57fa\u5316\u7684\u5bcc\u7535\u5b50\u82b3\u9999\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u7b56\u7565\u5177\u6709\u4f18\u826f\u7684\u5e95\u7269\u5e94\u7528\u8303\u56f4\u4ee5\u53ca\u4f18\u826f\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u7b49\u4f18\u52bf\u3002<\/p>\n<h2><strong><b>\u53c2\u8003\u6587\u732e<\/b><\/strong><\/h2>\n<ul>\n<li>[1] a) C. Perego, P. Ingallina, <em><i>Green Chem.<\/i><\/em>\u00a0<strong><b>2004<\/b><\/strong>, <em><i>6<\/i><\/em>, 274. doi: <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2004\/GC\/b403277m\"><u>10.1039\/B403277M.<\/u><\/a><\/li>\n<li>b) G. Busca, <em><i> Rev. <\/i><\/em><strong><b>2007<\/b><\/strong>, <em><i>107<\/i><\/em>, 5366. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/cr068042e\"><u>10.1021\/cr068042e.<\/u><\/a><\/li>\n<li>c) G. Evano, C. Theunissen, <em><i> Chem. Int. Ed. <\/i><\/em><strong><b>2019<\/b><\/strong>, <em><i>58<\/i><\/em>, 7558. doi: <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/ange.201806631\"><u>10.1002\/ange.201806631<\/u><\/a>.<\/li>\n<li>[2] N. O. Calloway, <em><i>Chem. Rev. <\/i><\/em><strong><b>1935<\/b><\/strong>, <em><i>17<\/i><\/em>, 327. doi:<a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/cr60058a002\"><u>\u00a010.1021\/cr60058a002<\/u><\/a>.<\/li>\n<li>[3] a) R. M. Roberts, G. P. Anderson, Jr., A. A. Khalaf, C. Low, <em><i>J. Org. Chem.<\/i><\/em><strong><em><b><i>\u00a0<\/i><\/b><\/em><\/strong><strong><b>1971<\/b><\/strong>, <em><i>36<\/i><\/em>, 3342. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jo00821a016\"><u>10.1021\/jo00821a016<\/u><\/a>.<\/li>\n<li>b) J. Kischel, I. Jovel, K. Mertins, A. Zapf, M. Beller, <em><i> Lett. <\/i><\/em><strong><b>2006<\/b><\/strong>, <em><i>8<\/i><\/em>, 19. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ol0523143\"><u>10.1021\/ol0523143<\/u><\/a>.<\/li>\n<li>c) M. Noji, T. Ohno, K. Fuji, N. Futaba, H. Tajima, K. Ishii, <em><i>Org. Chem.<\/i><\/em><b><i><\/i><\/b><strong><b>2003<\/b><\/strong>, <em><i>68<\/i><\/em>, 9340. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jo034255h\"><u>10.1021\/jo034255h<\/u><\/a>.<\/li>\n<li>[4] a) T. S. Sorensen, <em><i>J. Am. Chem. Soc.<\/i><\/em>\u00a0<strong><b>1967<\/b><\/strong>, <em><i>89<\/i><\/em>, 3782. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/ja00991a019\"><u>10.1021\/ja00991a019<\/u><\/a>.<\/li>\n<li>b) G. A. Olah, S. J. Kuhn,<em><i> Org. Chem.<\/i><\/em><strong><b>1964<\/b><\/strong>, <em><i>29<\/i><\/em>, 2317. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/abs\/10.1021\/jo01031a051\"><u>10.1021\/jo01031a051<\/u><\/a>.<\/li>\n<li>c) C. Perego, P. Ingallina, <em><i> Today <\/i><\/em><strong><b>2002<\/b><\/strong>, <em><i>73<\/i><\/em>, 3-2. doi: <a href=\"https:\/\/linkinghub.elsevier.com\/retrieve\/pii\/S0920586101005119\"><u>10.1016\/S0920-5861(01)00511-9<\/u><\/a>.<\/li>\n<li>[5] Z. Dong, Z. Ren, S. J. Thompson, Y. Xu, G. Dong, <em><i>Chem. Rev.<\/i><\/em>\u00a0<strong><b>2017<\/b><\/strong>, <em><i>117<\/i><\/em>, 9333. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.chemrev.6b00574\"><u>10.1021\/acs.chemrev.6b00574<\/u><\/a>.<\/li>\n<li>[6] A. DeAngelis, V. W. Shurtleff, O. Dmitrenko, J. M. Fox, <em><i>J. Am. Chem. Soc.<\/i><\/em><strong><em><b><i>\u00a0<\/i><\/b><\/em><\/strong><strong><b>2011<\/b><\/strong>,<em><i>\u00a0133<\/i><\/em>, 1650. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/ja1093309\"><u>10.1021\/ja1093309<\/u><\/a>.<\/li>\n<li>[7] F. Hu, Y. Xia, C. Ma, Y. Zhang, J. Wang, <em><i>Chem. Commun.<\/i><\/em>\u00a0<strong><b>2015<\/b><\/strong>, <em><i>51<\/i><\/em>, 7986. doi: <a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2015\/CC\/C5CC00497G\"><u>10.1039\/C5CC00497G<\/u><\/a>.<\/li>\n<li>[8] L. W. Ciszewski, J. Durka, D. Gryko, <em><i>Org. Lett.<\/i><\/em>\u00a0<strong><b>2019<\/b><\/strong>, <em><i>21<\/i><\/em>, 7028. doi: <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acs.orglett.9b02612\"><u>10.1021\/acs.orglett.9b02612<\/u><\/a>.<\/li>\n<li>[9] N. Holmberg-Douglas, N. P. R. Onuska, D. A. Nicewicz, <em><i>Angew. Chem. Int. Ed.<\/i><\/em>\u00a0<strong><b>2020<\/b><\/strong>, <em><i>59<\/i><\/em>, 7425. doi: <a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202000684\"><u>10.1002\/anie.202000684<\/u><\/a>.<\/li>\n<\/ul>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/p>\n","protected":false},"excerpt":{"rendered":"\u672c\u6587\u4f5c\u8005:\u00a0Coca\u00a0or\u00a0Pepsi \u5bfc\u8bfb \u8fd1\u65e5\uff0c\u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u8212\u4f1f\u7814\u7a76\u56e2\u961f\u5728Angew. Chem. Int. Ed.\u4e0a\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u91c7\u7528\u6d3b\u5316\u6216\u672a\u6d3b\u5316\u70ef\u57fa\u5316\u5408\u7269\u4e0e\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u4e4b\u95f4\u7684\u65e0\u91d1\u5c5e\u5149\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u7ebf\u6027\u70f7\u57fa\u5316\u7684\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u7684\u6784\u5efa\u3002 Organophotocatalytic Regioselective C\u2212H Alkylation of Electron-Rich Arenes Using Activated and Unactivated Alkenes B. Chen, Y. Du, W. Shu, Angew. Chem. Int. Ed.2022, 61, e202200773. doi: 10.1002\/anie.202200773. \u6b63\u6587 \u82b3\u9999\u5316\u5408\u7269\u53c2\u4e0e\u7684\u76f4\u63a5C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\u662f\u83b7\u5f97\u70f7\u57fa\u5316\u82b3\u9999\u5206\u5b50\u7684\u91cd\u8981\u7b56\u7565\u4e4b\u4e00 (Scheme 1)\u00a0[1]-[9]\u3002\u7136\u800c\uff0c\u5728\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u5b9e\u73b0\u5404\u7c7b\u82b3\u9999\u5206\u5b50\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u8fc7\u7a0b\uff0c\u76ee\u524d\u4ecd\u9762\u4e34\u5de8\u5927\u7684\u6311\u6218\u3002\u8fd9\u91cc\u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u8212\u4f1f\u56e2\u961f\u6210\u529f\u8bbe\u8ba1\u51fa\u4e00\u79cd\u5168\u65b0\u7684\u91c7\u7528\u6d3b\u5316\u6216\u672a\u6d3b\u5316\u70ef\u57fa\u5316\u5408\u7269\u4e0e\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u4e4b\u95f4\u7684\u65e0\u91d1\u5c5e\u5149\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\u3002 \u9996\u5148\uff0c\u4f5c\u8005\u91c7\u75283-\u7532\u6c27\u57fa\u567b\u5429\u00a0(1a)\u4e0e1,1-\u4e8c\u82ef\u57fa\u4e59\u70ef(2a)\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u533a\u57df\u9009\u62e9\u6027C-H\u2009\u70f7\u57fa\u5316\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528Mes-3,6-t-Bu2-Acr-Ph+BF4&#8211;\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\uff0c2-NH2-4-ClPhSH\u4f5c\u4e3aHAT\u50ac\u5316\u5242\uff0c\u82ef\u4e09\u6c1f\u7532\u70f7\u4f5c\u4e3a\u6eb6\u5242\uff0c\u84dd\u5149LED\u8f90\u5c04\u4e0b\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a\u5ba4\u6e29\uff0c\u8fdb\u800c\u83b7\u5f97\u76f8\u5e94\u7684C-H\u2009\u70f7\u57fa\u5316\u4ea7\u72693a\u3002 \u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u5404\u7c7b\u82b3\u9999\u5e95\u7269 (Scheme 2)\u4ee5\u53ca\u70ef\u57fa\u5e95\u7269 (Scheme 3)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002 \u4e4b\u540e\uff0c\u4f5c\u8005\u5c06\u8fd9\u4e00\u5168\u65b0\u7684\u5149\u50ac\u5316C-H\u6d3b\u5316\u7b56\u7565\u8fdb\u4e00\u6b65\u5e94\u7528\u4e8e\u82b3\u9999\u5316\u5408\u7269\u4e0e\u7094\u57fa\u5316\u5408\u7269\u4e4b\u95f4\u7684\u533a\u57df\u4e0e\u7acb\u4f53\u9009\u62e9\u6027C-H\u70ef\u57fa\u5316\u8fc7\u7a0b (Scheme 4)\u3002 \u4e3a\u9610\u660e\u53cd\u5e94\u673a\u7406\uff0c\u4f5c\u8005\u8fdb\u884c\u4e00\u7cfb\u5217\u76f8\u5173\u7684\u63a7\u5236\u5b9e\u9a8c\u7814\u7a76 (Scheme 5)\uff0c\u9996\u5148\uff0c\u4f5c\u8005\u901a\u8fc7\u81ea\u7531\u57fa\u6dec\u706d (Scheme 5a)\u4ee5\u53ca\u81ea\u7531\u57fa\u949f (Scheme 5b-5c)\u5b9e\u9a8c\u7684\u76f8\u5173\u7814\u7a76\u8868\u660e\uff0c\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u6d89\u53ca\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\u3002\u5e76\u4e14\uff0cHAT\u8fc7\u7a0b\u4e3a\u5feb\u901f\u7684\u53cd\u5e94\u6b65\u9aa4\u3002\u6700\u540e\uff0c\u8be5\u5c0f\u7ec4\u901a\u8fc7\u7ade\u4e89\u5b9e\u9a8c\u8fdb\u4e00\u6b65\u8868\u660e\uff0c\u4e0e11\u76f8\u6bd4\uff0c\u82b3\u9999\u5316\u5408\u72691a\u5bf9\u4e8e\u5149\u50ac\u5316\u5242\u7684\u6dec\u706d\u66f4\u4e3a\u6709\u6548\u3002 \u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 6)\u3002 \u603b\u7ed3 \u5357\u65b9\u79d1\u6280\u5927\u5b66\u7684\u8212\u4f1f\u7814\u7a76\u56e2\u961f\u6210\u529f\u8bbe\u8ba1\u51fa\u4e00\u79cd\u5168\u65b0\u7684\u91c7\u7528\u6d3b\u5316\u6216\u672a\u6d3b\u5316\u70ef\u57fa\u5316\u5408\u7269\u4e0e\u5bcc\u7535\u5b50\u82b3\u9999\u5316\u5408\u7269\u4e4b\u95f4\u7684\u65e0\u91d1\u5c5e\u5149\u50ac\u5316\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u7ebf\u6027\u70f7\u57fa\u5316\u7684\u5bcc\u7535\u5b50\u82b3\u9999\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u533a\u57df\u9009\u62e9\u6027C-H\u70f7\u57fa\u5316\u7b56\u7565\u5177\u6709\u4f18\u826f\u7684\u5e95\u7269\u5e94\u7528\u8303\u56f4\u4ee5\u53ca\u4f18\u826f\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u7b49\u4f18\u52bf\u3002 \u53c2\u8003\u6587\u732e [1] a) C. Perego, P. Ingallina, Green Chem.\u00a02004, 6, 274. doi: 10.1039\/B403277M. b) G. Busca, Rev. 2007, 107, 5366. doi: 10.1021\/cr068042e. c) G. Evano, C. Theunissen, Chem. Int. Ed. 2019, 58, 7558. doi: 10.1002\/ange.201806631. [2] N. O. Calloway, Chem. Rev. 1935, 17, 327. doi:\u00a010.1021\/cr60058a002. [3] a) R. M. Roberts, G. 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