{"id":44538,"date":"2023-02-11T08:00:22","date_gmt":"2023-02-11T00:00:22","guid":{"rendered":"\/\/www.gsbet888.com\/?p=44538"},"modified":"2023-02-24T15:16:09","modified_gmt":"2023-02-24T07:16:09","slug":"%e3%80%8cspotlight-research%e3%80%8dmeerwein%e7%9b%90%e5%9e%8b%e6%b0%a7%e6%ad%a3%e7%a6%bb%e5%ad%90%e4%b8%8e%e7%94%b2%e9%86%87%e7%bb%93%e5%90%88%e5%ae%9e%e7%8e%b0%e8%8a%b3%e7%83%83%e7%9a%84%e7%94%b2","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2023\/02\/%e3%80%8cspotlight-research%e3%80%8dmeerwein%e7%9b%90%e5%9e%8b%e6%b0%a7%e6%ad%a3%e7%a6%bb%e5%ad%90%e4%b8%8e%e7%94%b2%e9%86%87%e7%bb%93%e5%90%88%e5%ae%9e%e7%8e%b0%e8%8a%b3%e7%83%83%e7%9a%84%e7%94%b2.html","title":{"rendered":"\u300cSpotlight Research\u300dMeerwein\u76d0\u578b\u6c27\u6b63\u79bb\u5b50\u4e0e\u7532\u9187\u7ed3\u5408\u5b9e\u73b0\u82b3\u70c3\u7684\u7532\u57fa\u5316"},"content":{"rendered":"

\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a<\/b><\/strong><\/p>\n

\u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u6765\u81ea\u5fb7\u56fd\u67cf\u6797\u5de5\u4e1a\u5927\u5b66\u7684\u4f55\u6d9b\u4e3a\u6211\u4eec\u5206\u4eab\u3002<\/p>\n

2023\u5e742\u67081\u65e5\uff0cJACS<\/em><\/strong>\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u5fb7\u56fd\u67cf\u6797\u5de5\u4e1a\u5927\u5b66Martin Oestreich\u6559\u6388\u56e2\u961f\u9898\u4e3a\u300cCatalytically Generated Meerwein\u2019s Salt-Type Oxonium Ions for Friedel\u2013Crafts C(sp2)\u2013H Methylation with Methanol\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u6587\u7ae0\u4e2d\uff0cMartin Oestreich\u6559\u6388\u56e2\u961f\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\uff0c\u5229\u7528\u5ec9\u4ef7\u6613\u5f97\u4e14\u6613\u4e8e\u64cd\u4f5c\u7684\u7532\u9187\u4e3a\u7532\u57fa\u5316\u8bd5\u5242\u5b9e\u73b0\u4e86\u5404\u7c7b\u82b3\u73af\u7684\u7532\u57fa\u5316\u53cd\u5e94\u3002\u7531\u6297\u8861\u9634\u79bb\u5b50\u7a33\u5b9a\u7684\u7845\u6b63\u79bb\u5b50\u6216\u82b3\u57fa\u6b63\u79bb\u5b50\u5f15\u53d1\uff0c\u901a\u8fc7\u4e0e\u7532\u9187\u7ed3\u5408\u5f62\u6210\u4e86\u5177\u6709\u8f83\u5f3a\u7532\u57fa\u5316\u80fd\u529b\u7684\u7c7b\u4f3cMeerwein\u76d0\u7684\u6c27\u6b63\u79bb\u5b50\uff0c\u4ece\u800c\u5b9e\u73b0\u82b3\u73af\u7684\u7532\u57fa\u5316\u3002<\/p>\n

\"\"<\/p>\n

\u201cCatalytically Generated Meerwein\u2019s Salt-Type Oxonium Ions for Friedel\u2013Crafts C(sp2)\u2013H Methylation with Methanol<\/p>\n

Tao He, Hendrik F. T. Klare*, and Martin Oestreich*<\/p>\n

J. Am. Chem. Soc.<\/i><\/em>, 2023, <\/b><\/strong>ASAP, doi:10.1021\/jacs.2c13341\u00a0<\/u><\/a>\u201d<\/p><\/blockquote>\n

Q1. <\/b><\/strong>\u8bf7\u5bf9<\/b><\/strong>\u201c<\/b><\/strong>Copper-CatalyzedHighlyEnantioselective Addition of a Silicon Nucleophile to3-Substituted 2H-Azirines Using an Si\u2013B Reagent<\/b><\/strong>\u201d\u4f5c<\/b><\/strong>\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002<\/b><\/strong><\/h4>\n

\u8be5\u5de5\u4f5c\u4e2d\uff0cMartin Oestreich\u6559\u6388\u56e2\u961f\u901a\u8fc7\u50ac\u5316\u624b\u6bb5\uff0c\u4ee5\u5ec9\u4ef7\u6613\u5f97\u4e14\u6613\u4e8e\u64cd\u4f5c\u7684\u7532\u9187\u4f5c\u4e3a\u7532\u57fa\u5316\u8bd5\u5242\uff0c\u5728\u6e29\u548c\u7684\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e86\u5404\u7c7b\u82b3\u73af\u7684\u7532\u57fa\u5316\u3002\u8be5\u53cd\u5e94\u7531\u6297\u8861\u9634\u79bb\u5b50\u7a33\u5b9a\u7684\u7845\u6b63\u79bb\u5b50\u6216\u82b3\u57fa\u6b63\u79bb\u5b50\u5f15\u53d1\uff0c\u901a\u8fc7\u4e0e\u7532\u9187\u7ed3\u5408\u5f62\u6210\u4e86\u5177\u6709\u8f83\u5f3a\u7532\u57fa\u5316\u80fd\u529b\u7684\u7c7b\u4f3cMeerwein\u76d0\u7684\u6c27\u6b63\u79bb\u5b50\uff0c\u4ece\u800c\u5b9e\u73b0\u82b3\u73af\u7684\u7532\u57fa\u5316\u3002\u8be5\u53cd\u5e94\u53ef\u4ee5\u5728\u56db\u53d6\u4ee3\u7845\u70f7\u4f5c\u4e3a\u6dfb\u52a0\u5242\u7684\u201c\u7845\u7b56\u7565\u201d\u4e0b\u9ad8\u6548\u5730\u8fdb\u884c\uff0c\u7279\u522b\u662f\u5728\u76f8\u5bf9\u66f4\u7f3a\u7535\u5b50\u7684\u5364\u4ee3\u82b3\u73af\u7684\u7532\u57fa\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u3002\u9664\u7532\u9187\u4e4b\u5916\u7684\u5176\u4ed6\u975e\u6d3b\u5316\u7684\u4e00\u7ea7\u9187\u4e5f\u88ab\u53d1\u73b0\u6709\u826f\u597d\u7684\u9002\u7528\u6027\u3002\u6b64\u5916\uff0c\u53cc\u70f7\u57fa\u919a\u5728\u201c\u7845\u7b56\u7565\u201d\u4e0b\u4e5f\u88ab\u8bc1\u660e\u662f\u4e00\u7c7b\u8f83\u597d\u7684\u70f7\u57fa\u5316\u8bd5\u5242\u3002<\/p>\n

Q2.<\/b><\/strong>\u00a0\u6709\u5173\u672c\u6b21\u7814\u7a76\u7684\u65f6\u5019\u9047\u5230\u8fc7\u600e\u6837\u7684\u56f0\u96be\u5462\uff1f\u53c8\u662f\u600e\u6837\u514b\u670d\u7684\u5462<\/b><\/strong><\/h4>\n

\u672c\u6b21\u7814\u7a76\u4e2d\u9047\u5230\u7684\u4e3b\u8981\u56f0\u96be\u5728\u4e8e\u5b9e\u9a8c\u7684\u4e00\u4e9b\u5177\u4f53\u64cd\u4f5c\u3002\u7531\u4e8e\u7845\u6b63\u79bb\u5b50\u548c\u82b3\u57fa\u6b63\u79bb\u5b50\u7684\u5f3a\u9178\u6027\u51b3\u5b9adonor\u654f\u611f\u6027\uff0c\u5bfc\u81f4\u5b83\u4eec\u5fc5\u987b\u50a8\u5b58\u5728\u5bf9\u6c34\u6c27\u503c\u8f83\u9ad8\u7684\u624b\u5957\u7bb1\u4e2d\uff0c\u800c\u5404\u70f7\u57fa\u5316\u8bd5\u5242\u5982\u9187\u548c\u919a\u7b49\u662f\u826f\u597d\u7684donor\u56e0\u800c\u65e0\u6cd5\u5728\u624b\u5957\u7bb1\u4e2d\u64cd\u4f5c\uff0c\u8fd9\u5bfc\u81f4\u6211\u4eec\u5fc5\u987b\u5bf9\u5177\u4f53\u7684\u5b9e\u9a8c\u64cd\u4f5c\u8fdb\u884c\u4fee\u6b63\u3002\u540e\u6765\u6211\u4eec\u51b3\u5b9a\u5728\u624b\u5957\u7bb1\u4e2d\u79f0\u53d6\u7845\u6b63\u79bb\u5b50\u548c\u82b3\u57fa\u6b63\u79bb\u5b50\uff0c\u52a0\u5165\u5e72\u71e5\u7684\u82b3\u57fa\u6eb6\u5242\u8fdb\u884c\u4e00\u5b9a\u7684\u77ed\u6682\u4fdd\u62a4\uff0c\u7136\u540e\u79fb\u51fa\u624b\u5957\u7bb1\u5feb\u901f\u52a0\u5165\u9187\/\u919a\u7c7b\u70f7\u57fa\u5316\u8bd5\u5242\u540e\u8fdb\u884c\u5bc6\u5c01\u3002\u5173\u4e8e\u6b64\u7ec6\u8282\uff0c\u5ba1\u7a3f\u4eba\u66fe\u95ee\u53ca\uff0c\u8be6\u7ec6\u4fe1\u606f\u6211\u4eec\u5df2\u653e\u5165SI\u4e2d\u3002<\/p>\n

Q<\/strong>3.<\/strong>\u00a0<\/strong>\u672c\u6b21\u7814\u7a76\u4e3b\u4f53\uff0c\u6709\u6ca1\u6709\u4ec0\u4e48\u8ba9\u60a8\u611f\u89c9\u7279\u522b\u8f9b\u82e6\u548c\u70e7\u8111\u5462\uff1f<\/strong><\/h4>\n

\u672c\u6b21\u7814\u7a76\u4e2d\uff0c\u8f83\u4e3a\u8f9b\u82e6\u548c\u70e7\u8111\u7684\u5730\u65b9\u5728\u4e8e\u53d1\u73b0\u201c\u7845\u7b56\u7565\u201d\u548c\u201c\u975e\u7845\u7b56\u7565\u201d\u7684\u7ec6\u5fae\u5dee\u522b\u3001\u7845\u539f\u5b50\uff08\u56db\u53d6\u4ee3\u7845\u70f7\uff09\u7684\u53bb\u5411\u4ee5\u53ca\u53cd\u5e94\u673a\u7406\u7684\u63ed\u793a\u3002\u8fd9\u5bfc\u81f4\u5728\u6bcf\u4e2a\u5e95\u7269\u6269\u5c55\u7684\u4f8b\u5b50\u4e2d\uff0c\u6211\u4eec\u5747\u9700\u63a2\u7d22\u548c\u5bf9\u6bd4\u4e24\u79cd\u7b56\u7565\u7684\u5dee\u522b\uff0c\u6700\u7ec8\u83b7\u5f97\u4e00\u4e9b\u6709\u5173\u53cd\u5e94\u673a\u7406\u7684\u4fe1\u606f\u3002<\/p>\n

Q<\/b><\/strong>4.<\/b><\/strong>\u00a0<\/b><\/strong>\u5c06<\/b><\/strong>\u6765\u60f3\u7ee7\u7eed\u7814<\/b><\/strong>\u7a76\u5316\u5b66\u7684\u54ea\u4e2a\u65b9\u5411\u5462\uff1f<\/b><\/strong><\/h4>\n

\u5982\u679c\u53ef\u4ee5\uff0c\u5c06\u6765\u8fd8\u60f3\u5728\u6b63\u79bb\u5b50\u5316\u5b66\u9886\u57df\u4e2d\u7ee7\u7eed\u7814\u7a76\u3002<\/p>\n

Q<\/b><\/strong>5.<\/b><\/strong>\u00a0<\/b><\/strong>\u6700\u540e\uff0c\u6709\u4ec0\u4e48\u60f3\u5bf9\u5404\u4f4d\u8bfb\u8005\u8bf4\u7684\u5417\uff1f<\/b><\/strong><\/h4>\n

\u79d1\u7814\uff0c\u90fd\u662f\u4e00\u4e2a\u9010\u6b65\u79ef\u7d2f\u7684\u8fc7\u7a0b\uff0c\u65e0\u8bba\u7ed3\u679c\u6210\u8d25\u3002<\/p>\n

\u4f5c\u8005\u6559\u80b2\u80cc\u666f\u7b80\u4ecb<\/b><\/strong><\/h4>\n

\"\"<\/p>\n

\u6559\u80b2\u80cc\u666f\uff1a<\/b><\/strong><\/p>\n

2010.09-2014.06 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u5316\u5b66\u7cfb \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u5b66 \u58eb<\/p>\n

2014.09-2019.01 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u6e05\u534e\u5927\u5b66\u751f\u547d\u79d1\u5b66\u5b66\u9662 \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u535a \u58eb<\/p>\n

2019.07-\u81f3\u4eca \u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0\u00a0Technische Universit\u00e4t Berlin (\u5fb7\u56fd\uff0c\u67cf\u6797) \u00a0\u00a0\u535a\u58eb\u540e<\/p>\n

\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a \u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u6765\u81ea\u5fb7\u56fd\u67cf\u6797\u5de5\u4e1a\u5927\u5b66\u7684\u4f55\u6d9b\u4e3a\u6211\u4eec\u5206\u4eab\u3002 2023\u5e742\u67081\u65e5\uff0cJACS\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u5fb7\u56fd\u67cf\u6797\u5de5\u4e1a\u5927\u5b66Martin Oestreich\u6559\u6388\u56e2\u961f\u9898\u4e3a\u300cCatalytically Generated Meerwein\u2019s Salt-Type Oxonium Ions for Friedel\u2013Crafts C(sp2)\u2013H Methylation with Methanol\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u6587\u7ae0\u4e2d\uff0cMartin Oestreich\u6559\u6388\u56e2\u961f\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\uff0c\u5229\u7528\u5ec9\u4ef7\u6613\u5f97\u4e14\u6613\u4e8e\u64cd\u4f5c\u7684\u7532\u9187\u4e3a\u7532\u57fa\u5316\u8bd5\u5242\u5b9e\u73b0\u4e86\u5404\u7c7b\u82b3\u73af\u7684\u7532\u57fa\u5316\u53cd\u5e94\u3002\u7531\u6297\u8861\u9634\u79bb\u5b50\u7a33\u5b9a\u7684\u7845\u6b63\u79bb\u5b50\u6216\u82b3\u57fa\u6b63\u79bb\u5b50\u5f15\u53d1\uff0c\u901a\u8fc7\u4e0e\u7532\u9187\u7ed3\u5408\u5f62\u6210\u4e86\u5177\u6709\u8f83\u5f3a\u7532\u57fa\u5316\u80fd\u529b\u7684\u7c7b\u4f3cMeerwein\u76d0\u7684\u6c27\u6b63\u79bb\u5b50\uff0c\u4ece\u800c\u5b9e\u73b0\u82b3\u73af\u7684\u7532\u57fa\u5316\u3002 \u201cCatalytically Generated Meerwein\u2019s Salt-Type Oxonium Ions for Friedel\u2013Crafts C(sp2)\u2013H Methylation with Methanol Tao He, Hendrik F. T. Klare*, and Martin Oestreich* J. Am. Chem. Soc., 2023, ASAP, doi:10.1021\/jacs.2c13341\u00a0\u201d Q1. \u8bf7\u5bf9\u201cCopper-CatalyzedHighlyEnantioselective Addition of a Silicon Nucleophile to3-Substituted 2H-Azirines Using an Si\u2013B Reagent\u201d\u4f5c\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002 \u8be5\u5de5\u4f5c\u4e2d\uff0cMartin 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