{"id":45551,"date":"2023-04-28T08:10:23","date_gmt":"2023-04-28T00:10:23","guid":{"rendered":"\/\/www.gsbet888.com\/?p=45551"},"modified":"2023-04-28T08:36:16","modified_gmt":"2023-04-28T00:36:16","slug":"%e3%80%8cspotlight-research%e3%80%8d%e8%8b%9d%e4%ba%8c%e9%85%b0%e4%ba%9a%e8%83%ba-%e7%8e%af%e7%8a%b6n%e8%9e%ba%e7%83%af%ef%bc%9a%e7%ba%a2%e8%89%b2%e5%9c%86%e5%81%8f%e6%8c%af%e5%8f%91%e5%85%89","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/%e7%83%ad%e7%82%b9%e7%a0%94%e7%a9%b6\/2023\/04\/%e3%80%8cspotlight-research%e3%80%8d%e8%8b%9d%e4%ba%8c%e9%85%b0%e4%ba%9a%e8%83%ba-%e7%8e%af%e7%8a%b6n%e8%9e%ba%e7%83%af%ef%bc%9a%e7%ba%a2%e8%89%b2%e5%9c%86%e5%81%8f%e6%8c%af%e5%8f%91%e5%85%89.html","title":{"rendered":"\u300cSpotlight Research\u300d\u82dd\u4e8c\u9170\u4e9a\u80fa-\u73af\u72b6[n]\u87ba\u70ef\uff1a\u7ea2\u8272\u5706\u504f\u632f\u53d1\u5149\u4f53"},"content":{"rendered":"<p><strong><b>\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a<\/b><\/strong><\/p>\n<p>\u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u6765\u81ea\u7ef4\u5c14\u8328\u5821\u5927\u5b66\u7684\u7530\u5c0f\u797a\u535a\u58eb\u4e3a\u6211\u4eec\u5206\u4eab\u3002<\/p>\n<p>2023\u5e744\u670821\u65e5\uff0c<strong><em>JACS<\/em><\/strong>\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea<strong><b>\u5fb7\u56fd\u7ef4\u5c14\u8328\u5821\u5927\u5b66<\/b><\/strong><strong><b>Frank W\u00fcrthner<\/b><\/strong><strong><b>\u6559\u6388\u56e2\u961f<\/b><\/strong>\u9898\u4e3a\u300cNaphthalimide-Annulated [n]Helicenes: Red Circularly Polarized Light Emitters\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4f5c\u8005\u5229\u7528\u81ea\u5df1\u5b9e\u9a8c\u5ba4\u53d1\u5c55\u7684\u94af\u50ac\u5316\u76843+3\u53cd\u5e94\uff0c\u5c06\u8418\u9170\u4e9a\u80fa\u7684\u7ed3\u6784\u5f15\u5165\u5230\u4e86\u87ba\u70ef\u4e2d\uff0c\u4f7f\u5f97\u5408\u6210\u5f97\u5230\u7684\u87ba\u70ef\u884d\u751f\u7269\u5177\u6709\u7c7b\u4f3c\u4e8e\u82dd\u4e8c\u9170\u4e9a\u80fa\u7684\u6027\u8d28\uff0c\u5176\u8367\u5149\u91cf\u5b50\u4ea7\u7387\u8fbe\u5230\u4e8670%\u5de6\u53f3\u3002\u4ece\u800c\u4f7f\u5f97\u5176cpl\u4eae\u5ea6\u8fbe\u5230\u4e8666\uff0c\u5c55\u73b0\u51fa\u4e86\u5728\u624b\u6027\u5149\u7535\u5b50\u5b66\u4e2d\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-45553 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/a61f6bad55af2a0507b935719057f5f4.png\" alt=\"\" width=\"839\" height=\"401\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/a61f6bad55af2a0507b935719057f5f4.png 839w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/a61f6bad55af2a0507b935719057f5f4-300x143.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/a61f6bad55af2a0507b935719057f5f4-680x325.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/a61f6bad55af2a0507b935719057f5f4-768x367.png 768w\" sizes=\"(max-width: 839px) 100vw, 839px\" \/><\/p>\n<blockquote><p>\u201cNaphthalimide-Annulated [n]Helicenes: Red Circularly Polarized Light Emitters\u201d<\/p>\n<p>Xiaoqi Tian, Kazutaka Shoyama, Bernhard Mahlmeister, Felix Brust, Matthias Stolte, and Frank W\u00fcrthner* <em>J. <i>Am. Chem. Soc.<\/i><\/em>, <strong><b>2023, <\/b><\/strong>ASAP, doi:<a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.3c03441\"><u>10.1021\/jacs.3c03441<\/u><\/a>\u201d<\/p><\/blockquote>\n<h4><strong><b>Q1. <\/b><\/strong><strong><b>\u8bf7\u5bf9<\/b><\/strong><strong><b>\u201c<\/b><\/strong><strong><b>NucleophilesNaphthalimide-Annulated [n]Helicenes: Red Circularly Polarized Light Emitters<\/b><\/strong><strong><b>\u201d\u4f5c<\/b><\/strong><strong><b>\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002<\/b><\/strong><\/h4>\n<p>\u87ba\u70ef\u7c7b\u5316\u5408\u7269\u7531\u4e8e\u5176\u81ea\u8eab\u7684\u87ba\u65cb\u578b\u7ed3\u6784\u5e26\u6765\u7684\u624b\u6027\uff0c\u4f7f\u5f97\u8fd9\u7c7b\u5316\u5408\u7269\u5c55\u73b0\u51fa\u975e\u5e38\u4f18\u5f02\u7684\u624b\u6027\u5149\u5b66\u6027\u8d28\uff0c\u5c24\u5176\u662f\u5706\u504f\u632f\u5149\u6027\u8d28\u3002\u4f46\u662f\u7531\u4e8e\u5927\u90e8\u5206\u7684\u87ba\u70ef\u7c7b\u884d\u751f\u7269\u7684\u8367\u5149\u91cf\u5b50\u4ea7\u7387\u90fd\u6bd4\u8f83\u4f4e\uff0c\u56e0\u6b64\u5927\u5927\u9650\u5236\u4e86\u87ba\u70ef\u7c7b\u884d\u751f\u7269\u4f5c\u4e3a\u53d1\u5149\u6750\u6599\u7684\u5e94\u7528\u3002\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\u6211\u4eec\u5229\u7528\u6211\u4eec\u5b9e\u9a8c\u5ba4\u53d1\u5c55\u7684\u94af\u50ac\u5316\u76843+3\u53cd\u5e94\uff0c\u5c06\u8418\u9170\u4e9a\u80fa\u7684\u7ed3\u6784\u5f15\u5165\u5230\u4e86\u87ba\u70ef\u4e2d\uff0c\u4f7f\u5f97\u5408\u6210\u5f97\u5230\u7684\u87ba\u70ef\u884d\u751f\u7269\u5177\u6709\u7c7b\u4f3c\u4e8e\u82dd\u4e8c\u9170\u4e9a\u80fa\u7684\u6027\u8d28\uff0c\u5176\u8367\u5149\u91cf\u5b50\u4ea7\u7387\u8fbe\u5230\u4e8670%\u5de6\u53f3\u3002\u4ece\u800c\u4f7f\u5f97\u5176cpl\u4eae\u5ea6\u8fbe\u5230\u4e8666\uff0c\u5c55\u73b0\u51fa\u4e86\u5728\u624b\u6027\u5149\u7535\u5b50\u5b66\u4e2d\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<h4><strong><b>Q2.<\/b><\/strong><strong><b>\u00a0\u6709\u5173\u672c\u6b21\u7814\u7a76\u7684\u65f6\u5019\u9047\u5230\u8fc7\u600e\u6837\u7684\u56f0\u96be\u5462\uff1f\u53c8\u662f\u600e\u6837\u514b\u670d\u7684\u5462<\/b><\/strong><\/h4>\n<p>\u8fd9\u4e2a\u8bfe\u9898\u6574\u4f53\u8fdb\u5c55\u7b97\u662f\u6bd4\u8f83\u987a\u5229\u7684\u3002\u5bf9\u6211\u6765\u8bf4\u9047\u5230\u7684\u56f0\u96be\u662f\u7406\u8bba\u8ba1\u7b97\u90e8\u5206\u3002\u4e4b\u524d\u81ea\u5df1\u5f88\u5c11\u63a5\u89e6\u7406\u8bba\u8ba1\u7b97\u7684\u5de5\u4f5c\u3002\u4f46\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\u6211\u4eec\u60f3\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u89e3\u91ca6-\u87ba\u70ef\u884d\u751f\u7269\u4e3a\u4ec0\u4e48\u6bd45-\u87ba\u70ef\u884d\u751f\u7269\u7684\u624b\u6027\u5149\u5b66\u6027\u8d28\u66f4\u4f18\u5f02\u3002\u56e0\u6b64\u6211\u82b1\u4e86\u4e00\u4e9b\u65f6\u95f4\u5b66\u4e60\u7406\u8bba\u8ba1\u7b97\u7684\u77e5\u8bc6\uff0c\u5e76\u6700\u7ec8\u6210\u529f\u7684\u89e3\u91ca\u4e86\u8fd9\u4e00\u73b0\u8c61\u3002<\/p>\n<h4><strong>Q<\/strong><strong>3.<\/strong><strong>\u00a0<\/strong><strong>\u672c\u6b21\u7814\u7a76\u4e3b\u4f53\uff0c\u6709\u6ca1\u6709\u4ec0\u4e48\u8ba9\u60a8\u611f\u89c9\u7279\u522b\u8f9b\u82e6\u548c\u70e7\u8111\u5462\uff1f<\/strong><\/h4>\n<p>\u540c\u4e0a\u4e00\u4e2a\u95ee\u9898\uff0c\u7406\u8bba\u8ba1\u7b97\u5bf9\u6211\u6765\u8bf4\u662f\u6bd4\u8f83\u70e7\u8111\u7684\u90e8\u5206<\/p>\n<h4><strong><b>Q<\/b><\/strong><strong><b>4.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u5c06<\/b><\/strong><strong><b>\u6765\u60f3\u7ee7\u7eed\u7814<\/b><\/strong><strong><b>\u7a76\u5316\u5b66\u7684\u54ea\u4e2a\u65b9\u5411\u5462\uff1f<\/b><\/strong><\/h4>\n<p>\u5c06\u6765\u7684\u7814\u7a76\u5e0c\u671b\u4e13\u6ce8\u4e8e\u5f2f\u66f2\u7c7b\u591a\u73af\u82b3\u70c3\u7684\u8bbe\u8ba1\uff0c\u5408\u6210\u548c\u6027\u8d28\u7814\u7a76\uff0c\u5e76\u5e0c\u671b\u53ef\u4ee5\u5c06\u5176\u4e0e\u8d85\u5206\u5b50\u5316\u5b66\u8fdb\u884c\u7ed3\u5408\u3002<\/p>\n<h4><strong><b>Q<\/b><\/strong><strong><b>5.<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u6700\u540e\uff0c\u6709\u4ec0\u4e48\u60f3\u5bf9\u5404\u4f4d\u8bfb\u8005\u8bf4\u7684\u5417\uff1f<\/b><\/strong><\/h4>\n<p>\u505a\u79d1\u7814\u4e5f\u662f\u65b9\u5411\u6bd4\u52aa\u529b\u66f4\u91cd\u8981\uff0c\u6240\u4ee5\u5c3d\u91cf\u591a\u82b1\u4e00\u4e9b\u65f6\u95f4\u53bb\u601d\u8003\u8bbe\u8ba1\u4e00\u4e2a\u517c\u5177\u65b0\u9896\u6027\u548c\u53ef\u64cd\u4f5c\u6027\u7684\u8bfe\u9898\u662f\u6210\u529f\u7684\u5173\u952e<\/p>\n<h4><strong><b>\u4f5c\u8005\u6559\u80b2\u80cc\u666f\u7b80\u4ecb<\/b><\/strong><\/h4>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-45554 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/83151059550dbb860923869b9d776f18.png\" alt=\"\" width=\"941\" height=\"1255\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/83151059550dbb860923869b9d776f18.png 941w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/83151059550dbb860923869b9d776f18-225x300.png 225w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/83151059550dbb860923869b9d776f18-680x907.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/04\/83151059550dbb860923869b9d776f18-768x1024.png 768w\" sizes=\"(max-width: 941px) 100vw, 941px\" \/><\/p>\n<p><strong><b>\u6559\u80b2\u80cc\u666f\u53ca\u5176\u83b7\u5956\u7ecf\u5386\uff1a<\/b><\/strong><\/p>\n<p>2020\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u5929\u6d25\u5927\u5b66\uff0c\u5bfc\u5e08Jay Siegel\u6559\u6388<\/p>\n<p>2021\u5e743\u6708\u5230\u73b0\u5728\u5728\u7ef4\u5c14\u8328\u5821\u5927\u5b66\u505a\u535a\u58eb\u540e\uff0c\u5408\u4f5c\u5bfc\u5e08Frank W\u00fcrthner\u6559\u6388<\/p>\n<p>2020\u5e74\u83b7\u5f97\u5929\u6d25\u5927\u5b66\u4f18\u79c0\u6bd5\u4e1a\u751f<\/p>\n<p>2021\u5e74\u83b7\u5f97\u5fb7\u56fd\u6d2a\u5821\u5956\u5b66\u91d1<\/p>\n<p>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a \u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u6765\u81ea\u7ef4\u5c14\u8328\u5821\u5927\u5b66\u7684\u7530\u5c0f\u797a\u535a\u58eb\u4e3a\u6211\u4eec\u5206\u4eab\u3002 2023\u5e744\u670821\u65e5\uff0cJACS\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u5fb7\u56fd\u7ef4\u5c14\u8328\u5821\u5927\u5b66Frank W\u00fcrthner\u6559\u6388\u56e2\u961f\u9898\u4e3a\u300cNaphthalimide-Annulated [n]Helicenes: Red Circularly Polarized Light Emitters\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4f5c\u8005\u5229\u7528\u81ea\u5df1\u5b9e\u9a8c\u5ba4\u53d1\u5c55\u7684\u94af\u50ac\u5316\u76843+3\u53cd\u5e94\uff0c\u5c06\u8418\u9170\u4e9a\u80fa\u7684\u7ed3\u6784\u5f15\u5165\u5230\u4e86\u87ba\u70ef\u4e2d\uff0c\u4f7f\u5f97\u5408\u6210\u5f97\u5230\u7684\u87ba\u70ef\u884d\u751f\u7269\u5177\u6709\u7c7b\u4f3c\u4e8e\u82dd\u4e8c\u9170\u4e9a\u80fa\u7684\u6027\u8d28\uff0c\u5176\u8367\u5149\u91cf\u5b50\u4ea7\u7387\u8fbe\u5230\u4e8670%\u5de6\u53f3\u3002\u4ece\u800c\u4f7f\u5f97\u5176cpl\u4eae\u5ea6\u8fbe\u5230\u4e8666\uff0c\u5c55\u73b0\u51fa\u4e86\u5728\u624b\u6027\u5149\u7535\u5b50\u5b66\u4e2d\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002 \u201cNaphthalimide-Annulated [n]Helicenes: Red Circularly Polarized Light Emitters\u201d Xiaoqi Tian, Kazutaka Shoyama, Bernhard Mahlmeister, Felix Brust, Matthias Stolte, and Frank W\u00fcrthner* J. Am. Chem. 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