{"id":46807,"date":"2023-09-16T08:24:41","date_gmt":"2023-09-16T00:24:41","guid":{"rendered":"\/\/www.gsbet888.com\/?p=46807"},"modified":"2023-09-15T09:33:49","modified_gmt":"2023-09-15T01:33:49","slug":"green-chem-%ef%bc%9a%e7%a2%98%e5%82%ac%e5%8c%96dmso%e4%b8%8ecyclobutenones%e7%9a%84%e6%b0%a7%e5%8c%96%e9%87%8d%e6%8e%92%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2023\/09\/green-chem-%ef%bc%9a%e7%a2%98%e5%82%ac%e5%8c%96dmso%e4%b8%8ecyclobutenones%e7%9a%84%e6%b0%a7%e5%8c%96%e9%87%8d%e6%8e%92%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6.html","title":{"rendered":"Green Chem.\uff1a\u7898\u50ac\u5316DMSO\u4e0eCyclobutenones\u7684\u6c27\u5316\u91cd\u6392\u53cd\u5e94\u65b9\u6cd5\u5b66"},"content":{"rendered":"<p style=\"text-align: justify;\">\u4f5c\u8005\uff1a\u6749\u6749<\/p>\n<h4 style=\"text-align: justify;\">\u5bfc\u8bfb\uff1a<\/h4>\n<p style=\"text-align: justify;\">\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u7684\u7126\u5b81\u7b49\u8bfe\u9898\u7ec4\u5728<em>Green Chem.<\/em>\u4e2d\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u7898\u50ac\u5316DMSO\u4e0ecyclobutenones\u7684\u6c27\u5316\u91cd\u6392\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u544b\u5583-2(5<em>H<\/em>)-\u916e\u5206\u5b50\u7684\u6784\u5efa\u3002<\/p>\n<blockquote><p>Alternative Method to Baeyer-Villiger Oxidation of Cyclobutenones using I<sub>2<\/sub>\/DMSO Catalytic Systems<\/p>\n<p>Sun, Z. Hu, J. Peng, Q. Qin, N. Jiao, <em>Green Chem.<\/em> <strong>2023<\/strong>, ASAP. doi: <a href=\"https:\/\/doi.org\/10.1039\/D3GC01756G\">10.1039\/D3GC01756G<\/a><u>.<\/u><\/p><\/blockquote>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46810 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image002-2.png\" alt=\"\" width=\"1081\" height=\"204\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image002-2.png 1081w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image002-2-300x57.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image002-2-680x128.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image002-2-768x145.png 768w\" sizes=\"(max-width: 1081px) 100vw, 1081px\" \/><\/p>\n<h4 style=\"text-align: justify;\">\u6b63\u6587\uff1a<\/h4>\n<p style=\"text-align: justify;\"><em>\u03b3<\/em>-\u5185\u916f\u9aa8\u67b6\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5404\u7c7b\u751f\u7269\u6d3b\u6027\u5206\u5b50\u3001\u836f\u7269\u4ee5\u53ca\u5929\u7136\u4ea7\u7269\u4e2d (Scheme 1)\u3002\u5e76\u4e14\uff0c\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u91cc\uff0c\u5df2\u7ecf\u6210\u529f\u8bbe\u8ba1\u51fa\u591a\u79cd\u6784\u5efa\u5185\u916f\u5206\u5b50\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565(Scheme 2a)<sup>[1]<\/sup>\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u65b9\u6cd5\u90fd\u9700\u8981\u4f7f\u7528\u5f3a\u6216\u4e0d\u7a33\u5b9a\u7684\u6c27\u5316\u5242\u3002\u53d7\u5230DMSO\u4f5c\u4e3a\u6c27\u5316\u5242\u53c2\u4e0e\u76f8\u5173\u53cd\u5e94\u65b9\u6cd5\u5b66<sup>[2]<\/sup>\u4ee5\u53ca\u7898\u50ac\u5316DMSO\u4e0e\u73af\u5df1\u916e\u5408\u6210\u90bb\u82ef\u4e8c\u915a\u53cd\u5e94\u65b9\u6cd5\u5b66 (Scheme 2b)<sup>[3]<\/sup>\u76f8\u5173\u7814\u7a76\u62a5\u9053\u7684\u542f\u53d1\uff0c\u8fd9\u91cc\uff0c\u5317\u4eac\u5927\u5b66\u7684\u7126\u5b81\u7b49\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u7898\u50ac\u5316DMSO\u4e0ecyclobutenones\u7684\u6c27\u5316\u91cd\u6392\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u544b\u5583-2(5<em>H<\/em>)-\u916e\u5206\u5b50\u7684\u6784\u5efa (Scheme 2c)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46811 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image003-2.png\" alt=\"\" width=\"1147\" height=\"443\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image003-2.png 1147w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image003-2-300x116.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image003-2-680x263.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image003-2-768x297.png 768w\" sizes=\"(max-width: 1147px) 100vw, 1147px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46812 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image004-1.png\" alt=\"\" width=\"1116\" height=\"1152\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image004-1.png 1116w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image004-1-291x300.png 291w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image004-1-680x702.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image004-1-768x793.png 768w\" sizes=\"(max-width: 1116px) 100vw, 1116px\" \/>\u00a0\u9996\u5148\uff0c\u4f5c\u8005\u91c7\u75282-\u4e01\u57fa-3-\u82ef\u57fa\u73af\u4e01\u57fa-2-\u70ef-1-\u916e<strong>1a<\/strong>\u4e0eDMSO\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528\u7898\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5728MeNO<sub>2<\/sub>\u53cd\u5e94\u6eb6\u5242\u4e2d\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a100<sup>o<\/sup>C\uff0c\u6700\u7ec8\u83b7\u5f9784%\u6536\u7387\u7684\u4ea7\u7269<strong>2a<\/strong>\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46813 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image005-2.png\" alt=\"\" width=\"1200\" height=\"1336\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image005-2.png 1200w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image005-2-269x300.png 269w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image005-2-680x757.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image005-2-768x855.png 768w\" sizes=\"(max-width: 1200px) 100vw, 1200px\" \/><\/p>\n<p style=\"text-align: justify;\">\u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u4e00\u7cfb\u5217cyclobutenones\u5e95\u7269 (Table 2)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46814 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image006-1.png\" alt=\"\" width=\"1200\" height=\"1972\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image006-1.png 1200w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image006-1-183x300.png 183w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image006-1-623x1024.png 623w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image006-1-768x1262.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image006-1-935x1536.png 935w\" sizes=\"(max-width: 1200px) 100vw, 1200px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46817 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/a96b2cc9b854a89e8ecc512a016ce897.png\" alt=\"\" width=\"632\" height=\"285\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/a96b2cc9b854a89e8ecc512a016ce897.png 632w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/a96b2cc9b854a89e8ecc512a016ce897-300x135.png 300w\" sizes=\"(max-width: 632px) 100vw, 632px\" \/><\/p>\n<p style=\"text-align: justify;\">\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5bf9\u4e0a\u8ff0\u6c27\u5316\u91cd\u6392\u8fc7\u7a0b\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76 \u00a0(Scheme 3)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46815 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image008-1.png\" alt=\"\" width=\"1200\" height=\"872\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image008-1.png 1200w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image008-1-300x218.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image008-1-680x494.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image008-1-768x558.png 768w\" sizes=\"(max-width: 1200px) 100vw, 1200px\" \/><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46818 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/fd0ccdafd989525d206e0c4d1a2aa708.png\" alt=\"\" width=\"554\" height=\"178\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/fd0ccdafd989525d206e0c4d1a2aa708.png 554w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/fd0ccdafd989525d206e0c4d1a2aa708-300x96.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/fd0ccdafd989525d206e0c4d1a2aa708-550x178.png 550w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p style=\"text-align: justify;\">\u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\u4ee5\u53ca\u524d\u671f\u76f8\u5173\u7684\u6587\u732e\u62a5\u9053<sup>[4]<\/sup>\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 4)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-46816 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image010.png\" alt=\"\" width=\"824\" height=\"1002\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image010.png 824w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image010-247x300.png 247w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image010-680x827.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image010-768x934.png 768w\" sizes=\"(max-width: 824px) 100vw, 824px\" \/><\/p>\n<p style=\"text-align: justify;\">\u603b\u7ed3\uff1a\u5317\u4eac\u5927\u5b66\u7684\u7126\u5b81\u7b49\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u7898\u50ac\u5316DMSO\u4e0ecyclobutenones\u7684\u6c27\u5316\u91cd\u6392\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u544b\u5583-2(5<em>H<\/em>)-\u916e\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565\u5177\u6709\u53cd\u5e94\u6761\u4ef6\u7b80\u5355\u3001\u5b89\u5168\u6027\u9ad8\u4ee5\u53ca\u64cd\u4f5c\u7b80\u5355\u7b49\u4f18\u52bf\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/h4>\n<ul style=\"text-align: justify;\">\n<li>[1] G. Hughes, M. Kimura, S. L. Buchwald, <em>J. Am. Chem. Soc.<\/em> <strong>2003<\/strong>, <em>125<\/em>, 11253. doi: <a href=\"https:\/\/doi.org\/10.1021\/ja0351692\">10.1021\/ja0351692<\/a>.<\/li>\n<li>[2] J. Sun, W. Weng, P. Li, B. Zhang, <em>Green Chem.<\/em> <strong>2017<\/strong>, <em>19<\/em>, 1128. doi: <a href=\"https:\/\/doi.org\/10.1039\/C6GC03115C\">10.1039\/C6GC03115C<\/a>.<\/li>\n<li>[3] Y. Liang, X. Li, X. Wang, M. Zou, C. Tang, Y. Liang, S. Song, N. Jiao, <em>J. Am. Chem. Soc.<\/em> <strong>2016<\/strong>, <em>138<\/em>, 12271. doi: <a href=\"https:\/\/doi.org\/10.1021\/jacs.6b07269\">10.1021\/jacs.6b07269<\/a>.<\/li>\n<li>[4] Y. Liang, K. Wu, S. Song, X. Li, X. Huang, N. Jiao, <em>Org. Lett.<\/em> <strong>2015<\/strong>, <em>17<\/em>, 876. doi: <a href=\"https:\/\/doi.org\/10.1021\/ol5037387\">10.1021\/ol5037387<\/a>.<\/li>\n<\/ul>\n<p style=\"text-align: justify;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d.<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u6749\u6749 \u5bfc\u8bfb\uff1a \u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u7684\u7126\u5b81\u7b49\u8bfe\u9898\u7ec4\u5728Green Chem.\u4e2d\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u7898\u50ac\u5316DMSO\u4e0ecyclobutenones\u7684\u6c27\u5316\u91cd\u6392\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u544b\u5583-2(5H)-\u916e\u5206\u5b50\u7684\u6784\u5efa\u3002 Alternative Method to Baeyer-Villiger Oxidation of Cyclobutenones using I2\/DMSO Catalytic Systems Sun, Z. Hu, J. Peng, Q. Qin, N. Jiao, Green Chem. 2023, ASAP. doi: 10.1039\/D3GC01756G. \u6b63\u6587\uff1a \u03b3-\u5185\u916f\u9aa8\u67b6\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5404\u7c7b\u751f\u7269\u6d3b\u6027\u5206\u5b50\u3001\u836f\u7269\u4ee5\u53ca\u5929\u7136\u4ea7\u7269\u4e2d (Scheme 1)\u3002\u5e76\u4e14\uff0c\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u91cc\uff0c\u5df2\u7ecf\u6210\u529f\u8bbe\u8ba1\u51fa\u591a\u79cd\u6784\u5efa\u5185\u916f\u5206\u5b50\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565(Scheme 2a)[1]\u3002\u7136\u800c\uff0c\u5927\u591a\u6570\u65b9\u6cd5\u90fd\u9700\u8981\u4f7f\u7528\u5f3a\u6216\u4e0d\u7a33\u5b9a\u7684\u6c27\u5316\u5242\u3002\u53d7\u5230DMSO\u4f5c\u4e3a\u6c27\u5316\u5242\u53c2\u4e0e\u76f8\u5173\u53cd\u5e94\u65b9\u6cd5\u5b66[2]\u4ee5\u53ca\u7898\u50ac\u5316DMSO\u4e0e\u73af\u5df1\u916e\u5408\u6210\u90bb\u82ef\u4e8c\u915a\u53cd\u5e94\u65b9\u6cd5\u5b66 (Scheme 2b)[3]\u76f8\u5173\u7814\u7a76\u62a5\u9053\u7684\u542f\u53d1\uff0c\u8fd9\u91cc\uff0c\u5317\u4eac\u5927\u5b66\u7684\u7126\u5b81\u7b49\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u7898\u50ac\u5316DMSO\u4e0ecyclobutenones\u7684\u6c27\u5316\u91cd\u6392\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u544b\u5583-2(5H)-\u916e\u5206\u5b50\u7684\u6784\u5efa (Scheme 2c)\u3002 \u00a0\u9996\u5148\uff0c\u4f5c\u8005\u91c7\u75282-\u4e01\u57fa-3-\u82ef\u57fa\u73af\u4e01\u57fa-2-\u70ef-1-\u916e1a\u4e0eDMSO\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528\u7898\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u5728MeNO2\u53cd\u5e94\u6eb6\u5242\u4e2d\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a100oC\uff0c\u6700\u7ec8\u83b7\u5f9784%\u6536\u7387\u7684\u4ea7\u72692a\u3002 \u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5bf9\u4e00\u7cfb\u5217cyclobutenones\u5e95\u7269 (Table 2)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002 \u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5bf9\u4e0a\u8ff0\u6c27\u5316\u91cd\u6392\u8fc7\u7a0b\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76 \u00a0(Scheme 3)\u3002 \u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\u4ee5\u53ca\u524d\u671f\u76f8\u5173\u7684\u6587\u732e\u62a5\u9053[4]\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 4)\u3002 \u603b\u7ed3\uff1a\u5317\u4eac\u5927\u5b66\u7684\u7126\u5b81\u7b49\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u7898\u50ac\u5316DMSO\u4e0ecyclobutenones\u7684\u6c27\u5316\u91cd\u6392\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u544b\u5583-2(5H)-\u916e\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565\u5177\u6709\u53cd\u5e94\u6761\u4ef6\u7b80\u5355\u3001\u5b89\u5168\u6027\u9ad8\u4ee5\u53ca\u64cd\u4f5c\u7b80\u5355\u7b49\u4f18\u52bf\u3002 \u53c2\u8003\u6587\u732e\uff1a [1] G. Hughes, M. Kimura, S. L. Buchwald, J. Am. Chem. Soc. 2003, 125, 11253. doi: 10.1021\/ja0351692. [2] J. Sun, W. Weng, P. Li, B. Zhang, Green Chem. 2017, 19, 1128. doi: 10.1039\/C6GC03115C. [3] Y. Liang, X. Li, X. Wang, M. Zou, C. Tang, Y. Liang, S. Song, N. Jiao, J. Am. Chem. Soc. 2016, 138, 12271. [&hellip;]","protected":false},"author":26,"featured_media":46809,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1271],"tags":[4247,61,3278,2548],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/09\/image001-3.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-caX","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/46807"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=46807"}],"version-history":[{"count":1,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/46807\/revisions"}],"predecessor-version":[{"id":46819,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/46807\/revisions\/46819"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/46809"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=46807"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=46807"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=46807"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}