{"id":47154,"date":"2023-10-31T09:01:31","date_gmt":"2023-10-31T01:01:31","guid":{"rendered":"\/\/www.gsbet888.com\/?p=47154"},"modified":"2023-10-30T16:26:57","modified_gmt":"2023-10-30T08:26:57","slug":"frank-glorius%e7%bb%84jacs%ef%bc%9a%e5%85%89%e8%af%b1%e5%af%bcc-s%e9%94%ae%e8%a3%82%e8%a7%a3%e5%ae%9e%e7%8e%b0%e5%8f%8c%e7%8e%af%e4%b8%81%e7%83%b7%e7%9a%84%e9%a1%ba%e5%bc%8f%e5%ae%98%e8%83%bd%e5%9b%a2","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/%e7%83%ad%e7%82%b9%e7%a0%94%e7%a9%b6\/2023\/10\/frank-glorius%e7%bb%84jacs%ef%bc%9a%e5%85%89%e8%af%b1%e5%af%bcc-s%e9%94%ae%e8%a3%82%e8%a7%a3%e5%ae%9e%e7%8e%b0%e5%8f%8c%e7%8e%af%e4%b8%81%e7%83%b7%e7%9a%84%e9%a1%ba%e5%bc%8f%e5%ae%98%e8%83%bd%e5%9b%a2.html","title":{"rendered":"Frank Glorius\u7ec4JACS\uff1a\u5149\u8bf1\u5bfcC-S\u952e\u88c2\u89e3\u5b9e\u73b0\u53cc\u73af\u4e01\u70f7\u7684\u987a\u5f0f\u5b98\u80fd\u56e2\u5316"},"content":{"rendered":"<p style=\"text-align: justify;\">\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a<\/p>\n<h4 style=\"text-align: justify;\"><strong>\u5bfc\u8bfb<\/strong>\uff1a<\/h4>\n<p style=\"text-align: justify;\">\u8fd1\u65e5\uff0c\u5fb7\u56fd\u660e\u65af\u7279\u5927\u5b66\u7684Frank Glorius\u6559\u6388\u8bfe\u9898\u7ec4\u4ee5\u7cfb\u5217\u786b\u919a\u4f5c\u4e3a\u53cc\u529f\u80fd\u8bd5\u5242\uff0c\u5b9e\u73b0\u4e86BCB\u7684\u786b-\u7094\u57fa\u5316\u3001\u786b-\u70ef\u57fa\u5316\u4ee5\u53ca\u786b-\u70ef\u4e19\u57fa\u5316\u53cd\u5e94\uff0c\u5927\u90e8\u5206\u4f8b\u5b50\u90fd\u663e\u793a\u51fa\u4e86\u4f18\u5f02\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\uff08&gt;95:5\uff09\u3002\u540c\u65f6\uff0c\u786b-\u70ef\u57fa\u5316\u8fd8\u5c55\u793a\u4e86\u4f18\u5f02\u7684E\u5f0f\u9009\u62e9\u6027\u3002\u8be5\u7814\u7a76\u5177\u6709\u539f\u5b50\u5229\u7528\u7387\u9ad8\u3001\u53cd\u5e94\u6761\u4ef6\u7b80\u5355\u6e29\u548c\u4ee5\u53ca\u4f18\u5f02\u9009\u62e9\u6027\u7b49\u4f18\u52bf\u3002\u8be5\u7814\u7a76\u4e3aBCB\u73af\u5b9e\u73b0\u987a\u5f0f\u53cc\u529f\u80fd\u5316\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u548c\u7a7a\u95f4<\/p>\n<blockquote><p><em>syn<\/em>-Selective Difunctionalization of Bicyclobutanes Enabled by Photoredox-Mediated C\u2013S \u03c3-Bond Scission<\/p>\n<p>Huamin Wang, Johannes E. Erchinger, Madina Lenz, Subhabrata Dutta, Constantin G. Daniliuc, and Frank Glorius*<\/p>\n<p><em>J. Am. Chem. Soc.<\/em> <strong>2023<\/strong>, ASAP. doi:<a href=\"https:\/\/www.nature.com\/articles\/s41929-023-01037-9\"> 10.1021\/jacs.3c08512.<\/a><\/p><\/blockquote>\n<h4 style=\"text-align: justify;\"><strong>\u6b63\u6587<\/strong>\uff1a<\/h4>\n<p style=\"text-align: justify;\">\u73af\u4e01\u57fa\u7ed3\u6784\u5728\u836f\u7269\u5206\u5b50\u4e2d\u5e7f\u6cdb\u5b58\u5728\uff0c\u56e0\u6b64\uff0c\u6784\u7b51\u8be5\u7c7b\u578b\u7684\u5206\u5b50\u9aa8\u67b6\u5177\u6709\u91cd\u8981\u7684\u7814\u7a76\u610f\u4e49\u3002\u53cc\u73af[1.1.0]\u4e01\u70f7\uff08BCB\uff09\u8fd1\u5e74\u6765\u901a\u8fc7strain-release\u7684\u65b9\u5f0f\u6210\u4e3a\u4e86\u6784\u7b51\u542b\u73af\u4e01\u57fa\u7684\u5316\u5408\u7269\u7684\u91cd\u8981\u524d\u4f53\u3002\u4f46\u662f\uff0c\u8be5\u9886\u57df\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\u4f9d\u7136\u9762\u4e34\u7740\u5f88\u5927\u7684\u6311\u6218\uff0c\u5c24\u5176\u5408\u6210\u591a\u53d6\u4ee3\u73af\u4e01\u70f7\u884d\u751f\u7269\u7684\u9009\u62e9\u6027\u96be\u4ee5\u63a7\u5236\u3002\u6700\u8fd1\uff0cFrank Glorius\u8bfe\u9898\u7ec4\u901a\u8fc7\u5149\u6c27\u5316\u8bf1\u5bfc\u4e24\u7ec4\u5206\u53cc\u5b98\u80fd\u56e2\u5316\u53cd\u5e94\uff0c\u4ee5strain-release\u65b9\u5f0f\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u987a\u5f0f\u786b-\u7094\u57fa\u53d6\u4ee3\u3001\u786b-\u70ef\u57fa\u53d6\u4ee3\u4ee5\u53ca\u786b-\u70ef\u4e19\u57fa\u53d6\u4ee3\u7684\u73af\u4e01\u70f7\u4ea7\u7269\uff0c\u53cd\u5e94\u663e\u793a\u51fa\u4e86\u4f18\u5f02\u7684\u533a\u57df\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027\uff08\u5982\u56fe1\u6240\u793a\uff09\u3002<\/p>\n<p style=\"text-align: justify;\">\n<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47381 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/22.jpg\" alt=\"\" width=\"793\" height=\"411\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/22.jpg 793w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/22-300x155.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/22-680x352.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/22-768x398.jpg 768w\" sizes=\"(max-width: 793px) 100vw, 793px\" \/><\/p>\n<p style=\"text-align: center;\">\u56fe1. 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