{"id":47259,"date":"2023-10-26T08:00:19","date_gmt":"2023-10-26T00:00:19","guid":{"rendered":"\/\/www.gsbet888.com\/?p=47259"},"modified":"2023-10-24T22:44:38","modified_gmt":"2023-10-24T14:44:38","slug":"green-chem-%ef%bc%9a%e5%8f%af%e8%a7%81%e5%85%89%e8%af%b1%e5%af%bc%e9%93%81%e5%82%ac%e5%8c%96s-n%e4%ba%a4%e5%8f%89%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2023\/10\/green-chem-%ef%bc%9a%e5%8f%af%e8%a7%81%e5%85%89%e8%af%b1%e5%af%bc%e9%93%81%e5%82%ac%e5%8c%96s-n%e4%ba%a4%e5%8f%89%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6.html","title":{"rendered":"Green Chem.\uff1a\u53ef\u89c1\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66"},"content":{"rendered":"<p style=\"text-align: justify;\">\u4f5c\u8005\uff1a\u6749\u6749<\/p>\n<h4 style=\"text-align: justify;\">\u5bfc\u8bfb\uff1a<\/h4>\n<p style=\"text-align: justify;\">\u8fd1\u65e5\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u4e8e\u6653\u5f3a\u8bfe\u9898\u7ec4\u5728<em>Green Chem.<\/em>\u4e2d\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u53ef\u89c1\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217<em>N<\/em>-acylsulfenamides\u5206\u5b50\u7684\u6784\u5efa\u3002<\/p>\n<blockquote><p>Visible-light-induced Iron-catalyzed S-N Cross-coupling of Thiols with Dioxazolones<\/p>\n<p>J. Tang, N. Yan, Y. Zhang, Y. Wang, M. Bao, X. Yu, <em>Green Chem.<\/em> <strong>2023<\/strong>, ASAP. doi: <a href=\"https:\/\/doi.org\/10.1039\/D3GC02479B\">10.1039\/D3GC02479B<\/a><u>.<\/u><\/p><\/blockquote>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47261 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image002-9.png\" alt=\"\" width=\"1133\" height=\"299\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image002-9.png 1133w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image002-9-300x79.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image002-9-680x179.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image002-9-768x203.png 768w\" sizes=\"(max-width: 1133px) 100vw, 1133px\" \/><\/p>\n<h4 style=\"text-align: justify;\">\u6b63\u6587\uff1a<\/h4>\n<p style=\"text-align: justify;\"><em>N<\/em>-acylsulfenamides\u9aa8\u67b6\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5404\u7c7b\u519c\u7528\u5316\u5b66\u54c1\u4ee5\u53ca\u805a\u5408\u7269\u5206\u5b50\u4e2d (Scheme 1)\u3002\u5e76\u4e14\uff0c\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u91cc\uff0c\u5df2\u7ecf\u6210\u529f\u8bbe\u8ba1\u51fa\u591a\u79cd\u6784\u5efa<em>N<\/em>-acylsulfenamides\u5206\u5b50\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565 (Scheme 2a) <sup>[1]<\/sup>\u3002\u7136\u800c\uff0c\u6b64\u7c7b\u53cd\u5e94\u5e38\u5b58\u5728\u5e95\u7269\u8303\u56f4\u7a84\u3001\u4f7f\u7528\u8fc7\u91cf\u7684\u6dfb\u52a0\u5242\u3001\u4f7f\u7528\u5267\u6bd2\u8bd5\u5242\u5408\u6210\u9884\u6539\u6027\u786b\u8bd5\u5242\u7b49\u5f0a\u7aef\u3002\u53d7\u5230\u4e8c\u5641\u5511\u916e\u4f5c\u4e3a\u6c2e\u5bbe\u524d\u4f53\u53c2\u4e0e\u76f8\u5173\u53cd\u5e94\u65b9\u6cd5\u5b66<sup>[2]<\/sup>\u3001\u94dc\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66 (Scheme 2b)<sup> [3]<\/sup>\u4ee5\u53ca\u53ef\u89c1\u5149\u4fc3\u8fdb\u94c1\u50ac\u5316\u4e8c\u5641\u5511\u916e\u7684\u6c2e\u5bbe\u8f6c\u79fb\u53cd\u5e94\u65b9\u6cd5\u5b66<sup>[4]<\/sup>\u76f8\u5173\u7814\u7a76\u62a5\u9053\u7684\u542f\u53d1\uff0c\u8fd9\u91cc\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u4e8e\u6653\u5f3a\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u53ef\u89c1\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217<em>N<\/em>-acylsulfenamides\u5206\u5b50\u7684\u6784\u5efa (Scheme 2c)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47262 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image003-5.png\" alt=\"\" width=\"872\" height=\"566\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image003-5.png 872w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image003-5-300x195.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image003-5-680x441.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image003-5-768x498.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image003-5-260x170.png 260w\" sizes=\"(max-width: 872px) 100vw, 872px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47263 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image004-7.png\" alt=\"\" width=\"833\" height=\"816\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image004-7.png 833w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image004-7-300x294.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image004-7-680x666.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image004-7-768x752.png 768w\" sizes=\"(max-width: 833px) 100vw, 833px\" \/><\/p>\n<p style=\"text-align: justify;\">\u9996\u5148\uff0c\u4f5c\u8005\u91c7\u75283-\u82ef\u57fa-1,4,2-\u4e8c\u5641\u5511-5-\u916e<strong>1a<\/strong>\u4e0e4-\u7532\u82ef\u786b\u915a<strong>2a<\/strong>\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528FeBr<sub>3<\/sub>\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c10 W 450 nm blue light\u4f5c\u4e3a\u5149\u6e90\uff0c\u5728MeCN\u53cd\u5e94\u6eb6\u5242\u4e2d\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a40 <sup>o<\/sup>C\uff0c\u6700\u7ec8\u83b7\u5f9783%\u6536\u7387\u7684\u4ea7\u7269<strong>3aa<\/strong>\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47264 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image005-8.png\" alt=\"\" width=\"904\" height=\"1448\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image005-8.png 904w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image005-8-187x300.png 187w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image005-8-639x1024.png 639w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image005-8-768x1230.png 768w\" sizes=\"(max-width: 904px) 100vw, 904px\" \/><\/p>\n<p style=\"text-align: justify;\">\u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5206\u522b\u5bf9\u4e00\u7cfb\u5217\u786b\u9187\u5e95\u7269\u4ee5\u53ca\u4e8c\u5641\u5511\u916e\u5e95\u7269 (Scheme 3)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47265 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image006-8.png\" alt=\"\" width=\"1269\" height=\"1206\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image006-8.png 1269w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image006-8-300x285.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image006-8-680x646.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image006-8-768x730.png 768w\" sizes=\"(max-width: 1269px) 100vw, 1269px\" \/><\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47268 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image017.png\" alt=\"\" width=\"1102\" height=\"979\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image017.png 1102w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image017-300x267.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image017-680x604.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image017-768x682.png 768w\" sizes=\"(max-width: 1102px) 100vw, 1102px\" \/><\/p>\n<p style=\"text-align: justify;\">\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5bf9\u4e0a\u8ff0S-N\u4ea4\u53c9\u5076\u8054\u8fc7\u7a0b\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76 \u00a0(Scheme 4)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47266 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image008-5.png\" alt=\"\" width=\"882\" height=\"753\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image008-5.png 882w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image008-5-300x256.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image008-5-680x581.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image008-5-768x656.png 768w\" sizes=\"(max-width: 882px) 100vw, 882px\" \/><\/p>\n<p style=\"text-align: justify;\">\u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\u4ee5\u53ca\u524d\u671f\u76f8\u5173\u7684\u6587\u732e\u62a5\u9053<sup>[4]<\/sup>\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 5)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-47267 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image010-1.png\" alt=\"\" width=\"900\" height=\"948\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image010-1.png 900w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image010-1-285x300.png 285w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image010-1-680x716.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image010-1-768x809.png 768w\" sizes=\"(max-width: 900px) 100vw, 900px\" \/><\/p>\n<p style=\"text-align: justify;\">\u603b\u7ed3\uff1a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u4e8e\u6653\u5f3a\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u53ef\u89c1\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217<em>N<\/em>-acylsulfenamides\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565\u5177\u6709\u5e95\u7269\u8303\u56f4\u5e7f\u6cdb\u3001\u4f18\u826f\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u4ee5\u53ca\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u7b49\u4f18\u52bf\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/h4>\n<ul style=\"text-align: justify;\">\n<li>[1] J. H. Billman, J. Garrison, R. Anderson, B. Wolnak, <em>J. Am. Chem. Soc<\/em>. <strong>1941<\/strong>, <em>63<\/em>, 1920. doi:<a href=\"https:\/\/doi.org\/10.1021\/ja01852a033\">10.1021\/ja01852a033<\/a>.<\/li>\n<li>[2] C. M. B. Farr, A. M. Kazerouni, B. Park, C. D. Poff, J. Won, K. R. Sharp, M. H. Baik, S. B. Blakey, <em>J. Am. Chem. Soc<\/em>. <strong>2020<\/strong>, <em>142<\/em>, 13996. doi:<a href=\"https:\/\/doi.org\/10.1021\/jacs.0c07305\">10.1021\/jacs.0c07305<\/a>.<\/li>\n<li>[3] Z. Bai, S. Zhu, Y. Hu, P. Yang, X. Chu, G. He, H. Wang, G. Chen, <em>Nat. Commun<\/em>. <strong>2022<\/strong>, <em>13<\/em>, 6445. doi:<a href=\"https:\/\/doi.org\/10.1038\/s41467-022-34223-7\">10.1038\/s41467-022-34223-7<\/a>.<\/li>\n<li>[4] J. Tang, X. Yu, Y. Wang, Y. Yamamoto, M. Bao, <em>Angew. Chem. Int. Ed<\/em>. <strong>2021<\/strong>, <em>60<\/em>, 16426. doi:<a href=\"https:\/\/doi.org\/10.1002\/anie.202016234\">10.1002\/anie.202016234<\/a>.<\/li>\n<\/ul>\n<p style=\"text-align: justify;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d.<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u6749\u6749 \u5bfc\u8bfb\uff1a \u8fd1\u65e5\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u4e8e\u6653\u5f3a\u8bfe\u9898\u7ec4\u5728Green Chem.\u4e2d\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u53ef\u89c1\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217N-acylsulfenamides\u5206\u5b50\u7684\u6784\u5efa\u3002 Visible-light-induced Iron-catalyzed S-N Cross-coupling of Thiols with Dioxazolones J. Tang, N. Yan, Y. Zhang, Y. Wang, M. Bao, X. Yu, Green Chem. 2023, ASAP. doi: 10.1039\/D3GC02479B. \u6b63\u6587\uff1a N-acylsulfenamides\u9aa8\u67b6\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5404\u7c7b\u519c\u7528\u5316\u5b66\u54c1\u4ee5\u53ca\u805a\u5408\u7269\u5206\u5b50\u4e2d (Scheme 1)\u3002\u5e76\u4e14\uff0c\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u91cc\uff0c\u5df2\u7ecf\u6210\u529f\u8bbe\u8ba1\u51fa\u591a\u79cd\u6784\u5efaN-acylsulfenamides\u5206\u5b50\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565 (Scheme 2a) [1]\u3002\u7136\u800c\uff0c\u6b64\u7c7b\u53cd\u5e94\u5e38\u5b58\u5728\u5e95\u7269\u8303\u56f4\u7a84\u3001\u4f7f\u7528\u8fc7\u91cf\u7684\u6dfb\u52a0\u5242\u3001\u4f7f\u7528\u5267\u6bd2\u8bd5\u5242\u5408\u6210\u9884\u6539\u6027\u786b\u8bd5\u5242\u7b49\u5f0a\u7aef\u3002\u53d7\u5230\u4e8c\u5641\u5511\u916e\u4f5c\u4e3a\u6c2e\u5bbe\u524d\u4f53\u53c2\u4e0e\u76f8\u5173\u53cd\u5e94\u65b9\u6cd5\u5b66[2]\u3001\u94dc\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66 (Scheme 2b) [3]\u4ee5\u53ca\u53ef\u89c1\u5149\u4fc3\u8fdb\u94c1\u50ac\u5316\u4e8c\u5641\u5511\u916e\u7684\u6c2e\u5bbe\u8f6c\u79fb\u53cd\u5e94\u65b9\u6cd5\u5b66[4]\u76f8\u5173\u7814\u7a76\u62a5\u9053\u7684\u542f\u53d1\uff0c\u8fd9\u91cc\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u4e8e\u6653\u5f3a\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u53ef\u89c1\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217N-acylsulfenamides\u5206\u5b50\u7684\u6784\u5efa (Scheme 2c)\u3002 \u9996\u5148\uff0c\u4f5c\u8005\u91c7\u75283-\u82ef\u57fa-1,4,2-\u4e8c\u5641\u5511-5-\u916e1a\u4e0e4-\u7532\u82ef\u786b\u915a2a\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528FeBr3\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c10 W 450 nm blue light\u4f5c\u4e3a\u5149\u6e90\uff0c\u5728MeCN\u53cd\u5e94\u6eb6\u5242\u4e2d\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a40 oC\uff0c\u6700\u7ec8\u83b7\u5f9783%\u6536\u7387\u7684\u4ea7\u72693aa\u3002 \u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5206\u522b\u5bf9\u4e00\u7cfb\u5217\u786b\u9187\u5e95\u7269\u4ee5\u53ca\u4e8c\u5641\u5511\u916e\u5e95\u7269 (Scheme 3)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002 \u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5bf9\u4e0a\u8ff0S-N\u4ea4\u53c9\u5076\u8054\u8fc7\u7a0b\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76 \u00a0(Scheme 4)\u3002 \u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\u4ee5\u53ca\u524d\u671f\u76f8\u5173\u7684\u6587\u732e\u62a5\u9053[4]\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 5)\u3002 \u603b\u7ed3\uff1a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u4e8e\u6653\u5f3a\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u53ef\u89c1\u5149\u8bf1\u5bfc\u94c1\u50ac\u5316\u786b\u9187\u4e0e\u4e8c\u5641\u5511\u916e\u7684S-N\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217N-acylsulfenamides\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565\u5177\u6709\u5e95\u7269\u8303\u56f4\u5e7f\u6cdb\u3001\u4f18\u826f\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u4ee5\u53ca\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u7b49\u4f18\u52bf\u3002 \u53c2\u8003\u6587\u732e\uff1a [1] J. H. Billman, J. Garrison, R. Anderson, B. Wolnak, J. Am. Chem. Soc. 1941, 63, 1920. doi:10.1021\/ja01852a033. [2] C. M. B. Farr, A. M. Kazerouni, B. Park, C. D. Poff, J. Won, K. R. Sharp, M. H. Baik, S. B. Blakey, J. Am. Chem. Soc. 2020, 142, [&hellip;]","protected":false},"author":26,"featured_media":47260,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1271],"tags":[4299],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2023\/10\/image001-9.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-cif","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/47259"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=47259"}],"version-history":[{"count":1,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/47259\/revisions"}],"predecessor-version":[{"id":47269,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/47259\/revisions\/47269"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/47260"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=47259"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=47259"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=47259"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}