{"id":4820,"date":"2015-05-07T08:29:44","date_gmt":"2015-05-07T00:29:44","guid":{"rendered":"\/\/www.gsbet888.com\/?p=4820"},"modified":"2019-08-02T18:55:34","modified_gmt":"2019-08-02T10:55:34","slug":"crabbe%e8%81%94%e7%83%af%e5%90%88%e6%88%90crabbe-allene-synthesis","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2015\/05\/crabbe%e8%81%94%e7%83%af%e5%90%88%e6%88%90crabbe-allene-synthesis.html","title":{"rendered":"Crabbe\u8054\u70ef\u5408\u6210(Crabbe Allene Synthesis)"},"content":{"rendered":"<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>\u5728\u94dc\u91d1\u5c5e\u50ac\u5316\u5242\u3001\u591a\u805a\u7532\u919b\u3001\u9ad8\u4f4d\u963b2\u7ea7\u80fa(\u4e8c\u73af\u5df1\u80fa\u3001\u4e8c\u5f02\u4e19\u80fa\u7b49)\u5b58\u5728\u4e0b\uff0c\u628a\u672b\u7aef\u7094\u70c3\u8f6c\u6362\u6210\u8054\u70ef\u7684\u624b\u6cd5\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4><strong>\u57fa\u672c\u6587\u732e<\/strong><\/h4>\n<ul>\n<li>Crabb\u00e9, P.; Fillion, H.; Andr\u00e9, D.; Luche, J.-L. <em>J. Chem. Soc. Chem. Commun.<\/em> <strong>1979<\/strong>, 859. DOI:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1039\/C39790000859\">10.1039\/C39790000859<\/a><\/li>\n<li>Kuang, J.; Ma, S. <em>J. Org. Chem.<\/em> <strong>2009<\/strong>, <em>74<\/em>, 1763. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1021\/jo802391x\">10.1021\/jo802391x<\/a><\/li>\n<li>Kitagaki, S.; Komizu, M.; Mukai, C. <em>Synlett<\/em> <strong>2011<\/strong>, 1129. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1055\/s-0030-1259936\">10.1055\/s-0030-1259936<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4><strong>\u53cd\u5e94\u673a\u7406<\/strong><\/h4>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/2014-10-26_18-29-01.png\"><br \/>\n<\/a> <a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/Crabbe_allene_3.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-4822 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/Crabbe_allene_3.gif\" alt=\"Crabbe_allene_3\" width=\"341\" height=\"259\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<h4><strong>\u53cd\u5e94\u5b9e\u4f8b<\/strong><\/h4>\n<p>1,3-\u4e8c\u53d6\u4ee3\u8054\u70ef\u7684\u5408\u6210[1a]\u3002\u518d\u5229\u7528\u916e-\u624b\u6027\u78f7\u50ac\u5316\u5242\u4e5f\u53ef\u4ee5\u8fdb\u4e00\u6b65\u8fdb\u884c\u4e0d\u5bf9\u79f0\u5408\u6210[1b]\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/Crabbe_allene_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-4823 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/Crabbe_allene_2.gif\" alt=\"Crabbe_allene_2\" width=\"377\" height=\"81\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4><strong>\u5b9e\u9a8c\u6b65\u9aa4<\/strong><\/h4>\n<p>&nbsp;<\/p>\n<h4><strong>\u5b9e\u9a8c\u6280\u5de7<\/strong><\/h4>\n<p>&nbsp;<\/p>\n<h4><strong>\u53c2\u8003\u6587\u732e<\/strong><\/h4>\n<ol>\n<li>(a) Kuang, J.; Ma, S. <em>J. Am. Chem. Soc.<\/em> <strong>2010<\/strong>, <em>132<\/em>, 1786. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1021\/ja910503k\">10.1021\/ja910503k<\/a> (b) Ye, J.; Li, S.; Chen, B.; Fan, W.; Kuang, J.; Liu, J.; Liu, Y.; Miao, B.; Wan, B.; Wang, Y.; Xie, X.; Yu, Q.; Yuan, W.; Ma, S. <em>Org. Lett.<\/em> <strong>2012<\/strong>,<em>14<\/em>, 1346. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1021\/ol300296k\">10.1021\/ol300296k<\/a><\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u5728\u94dc\u91d1\u5c5e\u50ac\u5316\u5242\u3001\u591a\u805a\u7532\u919b\u3001\u9ad8\u4f4d\u963b2\u7ea7\u80fa(\u4e8c\u73af\u5df1\u80fa\u3001\u4e8c\u5f02\u4e19\u80fa\u7b49)\u5b58\u5728\u4e0b\uff0c\u628a\u672b\u7aef\u7094\u70c3\u8f6c\u6362\u6210\u8054\u70ef\u7684\u624b\u6cd5\u3002 &nbsp; \u57fa\u672c\u6587\u732e Crabb\u00e9, P.; Fillion, H.; Andr\u00e9, D.; Luche, J.-L. J. Chem. Soc. Chem. Commun. 1979, 859. DOI:10.1039\/C39790000859 Kuang, J.; Ma, S. J. Org. Chem. 2009, 74, 1763. DOI: 10.1021\/jo802391x Kitagaki, S.; Komizu, M.; Mukai, C. Synlett 2011, 1129. DOI: 10.1055\/s-0030-1259936 &nbsp; \u53cd\u5e94\u673a\u7406 &nbsp; &nbsp; \u53cd\u5e94\u5b9e\u4f8b 1,3-\u4e8c\u53d6\u4ee3\u8054\u70ef\u7684\u5408\u6210[1a]\u3002\u518d\u5229\u7528\u916e-\u624b\u6027\u78f7\u50ac\u5316\u5242\u4e5f\u53ef\u4ee5\u8fdb\u4e00\u6b65\u8fdb\u884c\u4e0d\u5bf9\u79f0\u5408\u6210[1b]\u3002 &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e (a) Kuang, J.; Ma, S. J. Am. Chem. Soc. 2010, 132, 1786. DOI: 10.1021\/ja910503k (b) Ye, J.; Li, S.; Chen, B.; Fan, W.; Kuang, J.; Liu, J.; Liu, Y.; Miao, B.; Wan, B.; Wang, Y.; Xie, X.; Yu, Q.; Yuan, W.; Ma, S. Org. Lett. 2012,14, 1346. DOI: 10.1021\/ol300296k &nbsp; \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01","protected":false},"author":5,"featured_media":4821,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[831,832,829,830],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/2014-10-26_18-29-01.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-1fK","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/4820"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=4820"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/4820\/revisions"}],"predecessor-version":[{"id":27930,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/4820\/revisions\/27930"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/4821"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=4820"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=4820"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=4820"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}