{"id":48643,"date":"2024-01-31T08:00:42","date_gmt":"2024-01-31T00:00:42","guid":{"rendered":"\/\/www.gsbet888.com\/?p=48643"},"modified":"2024-01-29T21:24:12","modified_gmt":"2024-01-29T13:24:12","slug":"%e5%8d%8e%e4%b8%ad%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%e5%94%90%e4%bb%8e%e8%be%89%e8%af%be%e9%a2%98%e7%bb%84jacs-%e5%8f%af%e6%8c%81%e7%bb%ad%e5%a4%9a%e7%9b%b8%e9%93%81%e5%82%ac%e5%8c%96%e7%83%af","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2024\/01\/%e5%8d%8e%e4%b8%ad%e7%a7%91%e6%8a%80%e5%a4%a7%e5%ad%a6%e5%94%90%e4%bb%8e%e8%be%89%e8%af%be%e9%a2%98%e7%bb%84jacs-%e5%8f%af%e6%8c%81%e7%bb%ad%e5%a4%9a%e7%9b%b8%e9%93%81%e5%82%ac%e5%8c%96%e7%83%af.html","title":{"rendered":"\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4JACS: \u53ef\u6301\u7eed\u591a\u76f8\u94c1\u50ac\u5316\u70ef\u4e19\u4f4d\u78b3\u6c22\u952e\u6c27\u5316"},"content":{"rendered":"

\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a<\/strong><\/p>\n

\u5bfc \u8bfb<\/strong><\/h4>\n

\u8fd1\u65e5\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u5510\u4ece\u8f89\u7814\u7a76\u5458\u8bfe\u9898\u7ec4\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\u201cSustainable Aerobic Allylic C-H Bond Oxidation with Heterogeneous Iron Catalyst\u201d\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a\u300a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\u300b\uff08J. Am. Chem. Soc<\/em>.\uff09\u4e0a\u520a\u53d1\u3002\u672c\u5de5\u4f5c\u4e2d\uff0c\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u7a33\u5b9a\u3001\u53ef\u5faa\u73af\u7684\u591a\u76f8\u94c1\u50ac\u5316\u5242\u7528\u4e8e\u70ef\u4e19\u4f4d\u6c27\u5316\u5236\u70ef\u916e\uff0c\u4f7f\u7528\u7a7a\u6c14\u6216\u6c27\u6c14\u4f5c\u4e3a\u6c27\u6e90\uff0c\u5e76\u4e14\u5bf9\u50ac\u5316\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u7814\u7a76\u3002<\/p>\n

Sustainable Aerobic Allylic C-H Bond Oxidation with Heterogeneous Iron Catalyst<\/p>\n

Yijie Jiang, Sanxia Chen, Yuangu Chen, Ailing Gu, and Conghui Tang*<\/strong><\/p>\n

J. Am. Chem. Soc. <\/em>2024<\/strong>, 146,<\/em> doi: 10.1021\/jacs.3c12688<\/a>.<\/p><\/blockquote>\n

\u6b63\u6587\uff1a<\/strong><\/h4>\n

\u78b3\u6c22\u952e\u6c27\u5316\u662f\u4e00\u7c7b\u5e7f\u6cdb\u5b58\u5728\u4e8e\u6709\u673a\u8f6c\u5316\u548c\u751f\u7269\u4f53\u7cfb\u4e2d\u7684\u57fa\u672c\u53cd\u5e94\uff0c\u5176\u4e2d\u70ef\u4e19\u4f4d\u78b3\u6c22\u952e\u6c27\u5316\u751f\u6210\u70ef\u916e\u7684\u53cd\u5e94\u7531\u4e8e\u70ef\u70c3\u539f\u6599\u6613\u5f97\u4e14\u70ef\u916e\u4ea7\u7269\u5177\u6709\u91cd\u8981\u4ef7\u503c\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f20\u7edf\u7684\u70ef\u4e19\u4f4d\u78b3\u6c22\u952e\u6c27\u5316\u5236\u5907\u70ef\u916e\u9700\u4f7f\u7528\u9ad8\u4ef7Cr\u3001\u4e8c\u6c27\u5316\u7852\u7b49\u5f53\u91cf\u7684\u73af\u5883\u4e0d\u53cb\u597d\u578b\u6c27\u5316\u5242\uff0c\u968f\u540e\u4e5f\u9646\u7eed\u53d1\u5c55\u4e86\u57fa\u4e8e\u50ac\u5316\u91cf\u91d1\u5c5e\uff08Cr, Rh, Ru, Pd\uff09\u642d\u914d\u8fc7\u6c27\u53d4\u4e01\u9187\u4f5c\u4e3a\u6c27\u5316\u5242\u7684\u4f53\u7cfb\uff0c\u4ee5\u53ca\u7535\u50ac\u5316\u548c\u5149\u50ac\u5316\u4f53\u7cfb\u3002\u4ece\u7eff\u8272\u53ef\u6301\u7eed\u7684\u89d2\u5ea6\u800c\u8a00\uff0c\u53d1\u5c55\u6e29\u548c\u6761\u4ef6\u4e0b\u7a7a\u6c14\u4f5c\u4e3a\u6c27\u5316\u5242\u3001\u50ac\u5316\u5242\u53ef\u5faa\u73af\u5229\u7528\u7684\u70ef\u4e19\u4f4d\u6c27\u5316\u53cd\u5e94\u662f\u975e\u5e38\u503c\u5f97\u671f\u5f85\u7684\u3002\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u81f4\u529b\u4e8e\u57fa\u4e8e\u5ec9\u4ef7\u91d1\u5c5e\u50ac\u5316\u7684\u5747\u76f8\u3001\u591a\u76f8\u53ca\u5355\u539f\u5b50\u50ac\u5316\u4f53\u7cfb\u5f00\u53d1\uff08J. Am. Chem. Soc.<\/em> 2024<\/strong>, 146<\/em>, 10.1021\/jacs.3c12688<\/a>; J. Am. Chem. Soc.<\/em> 2023<\/strong>, 145<\/em>, 4142\u20134149<\/a>; Angew. Chem. Int. Ed.<\/em> 2024<\/strong>, 63<\/em>, e202314708<\/a>; Angew. Chem. Int. Ed.<\/em> 2023<\/strong>, 62<\/em>, e202314364<\/a>; Angew. Chem. Int. Ed.<\/em> 2023<\/strong>, 62<\/em>, e202303433<\/a>; J. Catal.<\/em> 2022<\/strong>, 416<\/em>, 170\u2013175<\/a>; Org. Chem. Front.<\/em> 2022<\/strong>, 9<\/em>, 4554\u20134560<\/a>\uff09\u3002\u672c\u5de5\u4f5c\u4e2d\uff0c\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u7a33\u5b9a\u3001\u53ef\u5faa\u73af\u7684\u591a\u76f8\u94c1\u50ac\u5316\u5242\u7528\u4e8e\u70ef\u4e19\u4f4d\u6c27\u5316\u5236\u70ef\u916e\uff0c\u4f7f\u7528\u7a7a\u6c14\u6216\u6c27\u6c14\u4f5c\u4e3a\u6c27\u6e90\uff0c\u5e76\u4e14\u5bf9\u50ac\u5316\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u7814\u7a76\u3002<\/p>\n

\"\"<\/p>\n

\u56fe\u7247\u6765\u6e90\uff1aJ. Am. Chem. Soc.<\/em><\/p>\n

\u672c\u7814\u7a76\u6240\u7528\u5230\u7684\u94c1\u50ac\u5316\u5242\u91c7\u7528\u918b\u9178\u4e9a\u94c1\u548c1\uff0c10-\u83f2\u5570\u5549\u4ee5Al2<\/sub>O3<\/sub>\u4e3a\u8f7d\u4f53\u5728700\u6444\u6c0f\u5ea6\u6761\u4ef6\u4e0b\u5236\u5907\u800c\u6210\uff0c\u5176\u4e2d\u4e3b\u8981\u5305\u542bFeNx<\/sub>\u7269\u79cd\u548cFex<\/sub>Oy<\/sub>\u7269\u79cd\u3002\u786e\u5b9a\u4e86\u4f18\u9009\u7684\u50ac\u5316\u5242Fe(1)-phen(2)@\u03b1-Al2<\/sub>O3<\/sub>-700\u540e\u4f5c\u8005\u7ee7\u7eed\u8fdb\u884c\u4e86\u53cd\u5e94\u6761\u4ef6\u4f18\u5316\uff0c\u9488\u5bf9\u4e0d\u540c\u7ed3\u6784\u7684\u5e95\u7269\u5206\u522b\u4f18\u5316\u5f97\u5230\u9002\u7528\u7684\u53cd\u5e94\u6761\u4ef6\u3002\u8be5\u53cd\u5e94\u4f53\u7cfb\u9488\u5bf9\u8bb8\u591a\u7c7b\u578b\u7684\u5929\u7136\u4ea7\u7269\u5206\u5b50\uff08\u753e\u4f53\u3001\u5355\u841c\u3001\u500d\u534a\u841c\u3001\u4e09\u841c\u7b49\uff09\u4ee5\u53ca\u7b80\u5355\u7684\u70ef\u70c3\u5206\u5b50\u90fd\u53ef\u9002\u7528\uff0c\u5e76\u4e14\u4f53\u73b0\u51fa\u6bd4\u4f20\u7edf\u6c27\u5316\u65b9\u6cd5\u66f4\u9ad8\u7684\u6548\u7387\u548c\u53ef\u6301\u7eed\u6027\u3002\u6b64\u5916\uff0c\u5bf9\u4e8e\u542b\u6709\u836f\u7269\u5206\u5b50\u7ed3\u6784\u7684\u70ef\u4e19\u4f4d\u78b3\u6c22\u952e\u4e5f\u53ef\u4ee5\u987a\u5229\u8fdb\u884c\u8be5\u53cd\u5e94\u3002\u5728\u50ac\u5316\u5242\u5faa\u73af\u56de\u65369\u6b21\u4ee5\u540e\u53cd\u5e94\u6548\u7387\u90fd\u6ca1\u6709\u53d1\u751f\u660e\u663e\u7684\u4e0b\u964d\uff0c\u8bc1\u660e\u4e86\u8be5\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\uff0c\u540c\u65f6\u53cd\u5e94\u91cf\u7ea7\u53ef\u4ee5\u653e\u5927\u81f3\u5341\u514b\u7ea7\u5b9e\u9a8c\u3002\u4e3a\u4e86\u5370\u8bc1\u8be5\u4f53\u7cfb\u7684\u7eff\u8272\u53ef\u6301\u7eed\u6027\uff0c\u4f5c\u8005\u4ee5\u672c\u6587\u5de5\u4f5c\u548c\u6587\u732e\u4e2d\u03b1-\u848e\u70ef\u7684\u6c27\u5316\u53cd\u5e94\u4f5c\u4e3a\u8003\u5bdf\u5bf9\u8c61\uff0c\u9488\u5bf9\u53cd\u5e94\u4ea7\u7387\u3001\u53cd\u5e94\u8d28\u91cf\u6548\u7387\u3001\u78b3\u7ecf\u6d4e\u6027\u3001\u539f\u5b50\u7ecf\u6d4e\u6027\u3001\u548cE-Factor\u8fdb\u884c\u4e86\u5bf9\u6bd4\uff0c\u672c\u6587\u5de5\u4f5c\u5728\u8fd9\u4e9b\u6307\u6807\u4e2d\u90fd\u8868\u73b0\u4f18\u5f02\u3002\u4e3a\u4e86\u4e86\u89e3\u50ac\u5316\u673a\u7406\uff0c\u4f5c\u8005\u5f00\u5c55\u4e86\u9178\u8680\u5b9e\u9a8c\u548cKSCN\u4e2d\u6bd2\u5b9e\u9a8c\u7b49\u673a\u7406\u5b9e\u9a8c\uff0c\u8bc1\u660e\u4e86FeNx<\/sub>\u7269\u79cd\u548cFex<\/sub>Oy<\/sub>\u7269\u79cd\u5bf9\u50ac\u5316\u6d3b\u6027\u90fd\u6709\u8d21\u732e\uff0c\u4f46\u524d\u8005\u5360\u4e3b\u5bfc\u5730\u4f4d\u3002\u53e6\u5916\uff0c\u901a\u8fc7\u81ea\u7531\u57fa\u6355\u83b7\u5b9e\u9a8c\u9a8c\u8bc1\u4e86\u53cd\u5e94\u7ecf\u5386\u81ea\u7531\u57fa\u8fc7\u7a0b\uff0c\u6c27\u540c\u4f4d\u7d20\u6807\u8bb0\u5b9e\u9a8c\u8bc1\u660e\u4ea7\u7269\u4e2d\u7684\u6c27\u539f\u5b50\u6765\u6e90\u4e8e\u7a7a\u6c14\u4e2d\u7684\u6c27\u6c14\u3002<\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u4f4e\u6210\u672c\u7684\u7eb3\u7c73\u94c1\u50ac\u5316\u5242\u7528\u4e8e\u91cd\u8981\u7684\u70ef\u4e19\u4f4dC-H\u6c27\u5316\u53cd\u5e94\uff0c\u5e76\u5728\u6548\u7387\u3001\u53ef\u6301\u7eed\u6027\u548c\u9009\u62e9\u6027\u65b9\u9762\u6bd4\u73b0\u6709\u7684\u8bb8\u591a\u65b9\u6cd5\u6709\u663e\u8457\u7684\u4f18\u52bf\u3002\u8be5\u65b9\u6cd5\u5e95\u7269\u8303\u56f4\u5e7f\uff0c\u9002\u7528\u4e8e\u8bb8\u591a\u5929\u7136\u4ea7\u7269\u7ed3\u6784\u5206\u5b50\uff0c\u6df1\u5165\u7684\u673a\u7406\u7814\u7a76\u4e5f\u786e\u5b9a\u4e86\u50ac\u5316\u6d3b\u6027\u7269\u79cd\u53ca\u673a\u7406\u8def\u7ebf\u3002<\/p>\n

\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5510\u4ece\u8f89\u7814\u7a76\u5458\u4e3a\u901a\u8baf\u4f5c\u8005\uff0c\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u7855\u58eb\u7814\u7a76\u751f\u59dc\u6bc5\u6770\u4e3a\u7b2c\u4e00\u4f5c\u8005\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff0822001086\u300122371083\uff09\u3001\u4e2d\u592e\u9ad8\u6821\u57fa\u672c\u79d1\u7814\u4e1a\u52a1\u8d39\uff08HUST 2020kfyXJJS094\uff09\u3001\u5317\u4eac\u5927\u5b66\u5929\u7136\u836f\u7269\u53ca\u4eff\u751f\u836f\u7269\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\uff08K202011\uff09\u7684\u8d44\u52a9\u3002\u611f\u8c22\u5317\u4eac\u5927\u5b66\u7126\u5b81\u6559\u6388\u5bf9\u6c27\u540c\u4f4d\u7d20\u6807\u8bb0\u5b9e\u9a8c\u7684\u5e2e\u52a9\uff0c\u4ee5\u53ca\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u674e\u660e\u6d69\u6559\u6388\u5bf9\u4e8e\u7eff\u8272\u5316\u5b66\u6307\u6807\u8ba1\u7b97\u7684\u6307\u5bfc\u3002<\/p>\n

\u3010\u8bfe\u9898\u7ec4\u4ecb\u7ecd\u3011<\/strong><\/h4>\n

\"\"<\/p>\n

\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u5510\u4ece\u8f89\u7814\u7a76\u5458<\/strong>\uff0c2011\u5e74\u672c\u79d1\u6bd5\u4e1a\u4e8e\u534e\u4e2d\u79d1\u6280\u5927\u5b66\uff0c2011-2016\u5e74\u5728\u5317\u4eac\u5927\u5b66\u76f4\u63a5\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\uff08\u5bfc\u5e08\uff1a\u7126\u5b81\u6559\u6388<\/strong>\uff09\uff0c\u968f\u540e\u5728\u5fb7\u56fd\u548c\u7f8e\u56fd\u7684\u77e5\u540d\u9ad8\u6821\u3001\u7814\u7a76\u6240\u8fdb\u884c\u535a\u58eb\u540e\u7814\u7a76(\u5bfc\u5e08\uff1aMatthias Beller, David Sarlah, Liming Zhang)\uff0c2020\u5e74\u56de\u56fd\u4f5c\u4e3a\u8bfe\u9898\u7ec4\u957f\u5f00\u5c55\u72ec\u7acb\u7814\u7a76\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u4e3b\u8981\u4ece\u4e8b\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u3001\u5747\u76f8\u548c\u591a\u76f8\u50ac\u5316\u3001\u7eff\u8272\u53ca\u4eff\u751f\u6709\u673a\u5408\u6210\u7814\u7a76\u3002\u76ee\u524d\u5df2\u53d1\u8868\u9ad8\u6c34\u5e73SCI\u671f\u520a\u8bba\u658735\u7bc7\uff0c\u603b\u8ba1\u4ed6\u4eba\u5f15\u7528\u6b21\u65704300\u4f59\u6b21\u3002\u4ee5\u901a\u8baf\u4f5c\u8005\u3001\u7b2c\u4e00\u4f5c\u8005\u53d1\u8868\u7684\u9876\u7ea7\u671f\u520a\u8bba\u6587\u5305\u62ecChem. Rev.<\/em>\uff081\u7bc7\uff09\uff0cChem. Soc. Rev.<\/em>\uff081\u7bc7\uff09,\u00a0J. Am. Chem. Soc.<\/em>\uff083\u7bc7\uff09\uff0cAngew. Chem. Int. Ed.<\/em>\uff087\u7bc7\uff09\u7b49\u3002\u76f8\u5173\u6210\u679c\u88abAngew. Chem. Int. Ed.<\/em>\uff0cSynfact<\/em>,\u00a0Synform\u00a0<\/em>\u7b49\u6742\u5fd7\u62a5\u9053\u6216\u4eae\u70b9\u8bc4\u8ff0\u3002\u62c5\u4efbJ. Am. Chem. Soc.<\/em>, Chem. Sci.<\/em>, Chem. Commun.<\/em>,\u00a0Org. Lett.\u00a0<\/em>\u7b49\u56fd\u9645\u77e5\u540d\u671f\u520a\u7684\u5ba1\u7a3f\u4eba\u3002\u7533\u8bf7\u4e2d\u56fd\u53d1\u660e\u4e13\u52293\u9879\u3001\u5df2\u6388\u67431\u9879\u3002\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\u3001\u9752\u5e74\u9879\u76ee\uff0c\u53c2\u4e0e\u91cd\u70b9\u9879\u76ee\uff1b\u4f5c\u4e3a\u9879\u76ee\u9aa8\u5e72\u53c2\u4e0e\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u8bfe\u9898\u3002\u83b7\u8bc4\u534e\u4e2d\u5b66\u8005\u3001\u6e56\u5317\u7701\u767e\u4eba\u8ba1\u5212\u3001\u6b66\u6c49\u82f1\u624d\u3001\u5317\u4eac\u5e02\u81ea\u7136\u79d1\u5b66\u5956\u4e00\u7b49\u5956\uff085\/8\uff09,Reaxys PhD Prize\u7b49\u8363\u8a89\u3002\u66f4\u591a\u8be6\u60c5\u8bf7\u89c1\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1ahttps:\/\/www.thetanglab.com\/<\/a><\/p>\n

\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d.<\/p>\n

\n

\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a \u5bfc \u8bfb \u8fd1\u65e5\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u5510\u4ece\u8f89\u7814\u7a76\u5458\u8bfe\u9898\u7ec4\u7684\u6700\u65b0\u7814\u7a76\u6210\u679c\u201cSustainable Aerobic Allylic C-H Bond Oxidation with Heterogeneous Iron Catalyst\u201d\u5728\u56fd\u9645\u9876\u7ea7\u671f\u520a\u300a\u7f8e\u56fd\u5316\u5b66\u4f1a\u5fd7\u300b\uff08J. Am. Chem. Soc.\uff09\u4e0a\u520a\u53d1\u3002\u672c\u5de5\u4f5c\u4e2d\uff0c\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u7a33\u5b9a\u3001\u53ef\u5faa\u73af\u7684\u591a\u76f8\u94c1\u50ac\u5316\u5242\u7528\u4e8e\u70ef\u4e19\u4f4d\u6c27\u5316\u5236\u70ef\u916e\uff0c\u4f7f\u7528\u7a7a\u6c14\u6216\u6c27\u6c14\u4f5c\u4e3a\u6c27\u6e90\uff0c\u5e76\u4e14\u5bf9\u50ac\u5316\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u7814\u7a76\u3002 Sustainable Aerobic Allylic C-H Bond Oxidation with Heterogeneous Iron Catalyst Yijie Jiang, Sanxia Chen, Yuangu Chen, Ailing Gu, and Conghui Tang* J. Am. Chem. Soc. 2024, 146, doi: 10.1021\/jacs.3c12688. \u6b63\u6587\uff1a \u78b3\u6c22\u952e\u6c27\u5316\u662f\u4e00\u7c7b\u5e7f\u6cdb\u5b58\u5728\u4e8e\u6709\u673a\u8f6c\u5316\u548c\u751f\u7269\u4f53\u7cfb\u4e2d\u7684\u57fa\u672c\u53cd\u5e94\uff0c\u5176\u4e2d\u70ef\u4e19\u4f4d\u78b3\u6c22\u952e\u6c27\u5316\u751f\u6210\u70ef\u916e\u7684\u53cd\u5e94\u7531\u4e8e\u70ef\u70c3\u539f\u6599\u6613\u5f97\u4e14\u70ef\u916e\u4ea7\u7269\u5177\u6709\u91cd\u8981\u4ef7\u503c\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4f20\u7edf\u7684\u70ef\u4e19\u4f4d\u78b3\u6c22\u952e\u6c27\u5316\u5236\u5907\u70ef\u916e\u9700\u4f7f\u7528\u9ad8\u4ef7Cr\u3001\u4e8c\u6c27\u5316\u7852\u7b49\u5f53\u91cf\u7684\u73af\u5883\u4e0d\u53cb\u597d\u578b\u6c27\u5316\u5242\uff0c\u968f\u540e\u4e5f\u9646\u7eed\u53d1\u5c55\u4e86\u57fa\u4e8e\u50ac\u5316\u91cf\u91d1\u5c5e\uff08Cr, Rh, Ru, Pd\uff09\u642d\u914d\u8fc7\u6c27\u53d4\u4e01\u9187\u4f5c\u4e3a\u6c27\u5316\u5242\u7684\u4f53\u7cfb\uff0c\u4ee5\u53ca\u7535\u50ac\u5316\u548c\u5149\u50ac\u5316\u4f53\u7cfb\u3002\u4ece\u7eff\u8272\u53ef\u6301\u7eed\u7684\u89d2\u5ea6\u800c\u8a00\uff0c\u53d1\u5c55\u6e29\u548c\u6761\u4ef6\u4e0b\u7a7a\u6c14\u4f5c\u4e3a\u6c27\u5316\u5242\u3001\u50ac\u5316\u5242\u53ef\u5faa\u73af\u5229\u7528\u7684\u70ef\u4e19\u4f4d\u6c27\u5316\u53cd\u5e94\u662f\u975e\u5e38\u503c\u5f97\u671f\u5f85\u7684\u3002\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u81f4\u529b\u4e8e\u57fa\u4e8e\u5ec9\u4ef7\u91d1\u5c5e\u50ac\u5316\u7684\u5747\u76f8\u3001\u591a\u76f8\u53ca\u5355\u539f\u5b50\u50ac\u5316\u4f53\u7cfb\u5f00\u53d1\uff08J. Am. Chem. Soc. 2024, 146, 10.1021\/jacs.3c12688; J. Am. Chem. Soc. 2023, 145, 4142\u20134149; Angew. Chem. Int. Ed. 2024, 63, e202314708; Angew. Chem. Int. Ed. 2023, 62, e202314364; Angew. Chem. Int. Ed. 2023, 62, e202303433; J. Catal. 2022, 416, 170\u2013175; Org. Chem. Front. 2022, 9, 4554\u20134560\uff09\u3002\u672c\u5de5\u4f5c\u4e2d\uff0c\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u7a33\u5b9a\u3001\u53ef\u5faa\u73af\u7684\u591a\u76f8\u94c1\u50ac\u5316\u5242\u7528\u4e8e\u70ef\u4e19\u4f4d\u6c27\u5316\u5236\u70ef\u916e\uff0c\u4f7f\u7528\u7a7a\u6c14\u6216\u6c27\u6c14\u4f5c\u4e3a\u6c27\u6e90\uff0c\u5e76\u4e14\u5bf9\u50ac\u5316\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u7814\u7a76\u3002 \u56fe\u7247\u6765\u6e90\uff1aJ. Am. Chem. Soc. \u672c\u7814\u7a76\u6240\u7528\u5230\u7684\u94c1\u50ac\u5316\u5242\u91c7\u7528\u918b\u9178\u4e9a\u94c1\u548c1\uff0c10-\u83f2\u5570\u5549\u4ee5Al2O3\u4e3a\u8f7d\u4f53\u5728700\u6444\u6c0f\u5ea6\u6761\u4ef6\u4e0b\u5236\u5907\u800c\u6210\uff0c\u5176\u4e2d\u4e3b\u8981\u5305\u542bFeNx\u7269\u79cd\u548cFexOy\u7269\u79cd\u3002\u786e\u5b9a\u4e86\u4f18\u9009\u7684\u50ac\u5316\u5242Fe(1)-phen(2)@\u03b1-Al2O3-700\u540e\u4f5c\u8005\u7ee7\u7eed\u8fdb\u884c\u4e86\u53cd\u5e94\u6761\u4ef6\u4f18\u5316\uff0c\u9488\u5bf9\u4e0d\u540c\u7ed3\u6784\u7684\u5e95\u7269\u5206\u522b\u4f18\u5316\u5f97\u5230\u9002\u7528\u7684\u53cd\u5e94\u6761\u4ef6\u3002\u8be5\u53cd\u5e94\u4f53\u7cfb\u9488\u5bf9\u8bb8\u591a\u7c7b\u578b\u7684\u5929\u7136\u4ea7\u7269\u5206\u5b50\uff08\u753e\u4f53\u3001\u5355\u841c\u3001\u500d\u534a\u841c\u3001\u4e09\u841c\u7b49\uff09\u4ee5\u53ca\u7b80\u5355\u7684\u70ef\u70c3\u5206\u5b50\u90fd\u53ef\u9002\u7528\uff0c\u5e76\u4e14\u4f53\u73b0\u51fa\u6bd4\u4f20\u7edf\u6c27\u5316\u65b9\u6cd5\u66f4\u9ad8\u7684\u6548\u7387\u548c\u53ef\u6301\u7eed\u6027\u3002\u6b64\u5916\uff0c\u5bf9\u4e8e\u542b\u6709\u836f\u7269\u5206\u5b50\u7ed3\u6784\u7684\u70ef\u4e19\u4f4d\u78b3\u6c22\u952e\u4e5f\u53ef\u4ee5\u987a\u5229\u8fdb\u884c\u8be5\u53cd\u5e94\u3002\u5728\u50ac\u5316\u5242\u5faa\u73af\u56de\u65369\u6b21\u4ee5\u540e\u53cd\u5e94\u6548\u7387\u90fd\u6ca1\u6709\u53d1\u751f\u660e\u663e\u7684\u4e0b\u964d\uff0c\u8bc1\u660e\u4e86\u8be5\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\uff0c\u540c\u65f6\u53cd\u5e94\u91cf\u7ea7\u53ef\u4ee5\u653e\u5927\u81f3\u5341\u514b\u7ea7\u5b9e\u9a8c\u3002\u4e3a\u4e86\u5370\u8bc1\u8be5\u4f53\u7cfb\u7684\u7eff\u8272\u53ef\u6301\u7eed\u6027\uff0c\u4f5c\u8005\u4ee5\u672c\u6587\u5de5\u4f5c\u548c\u6587\u732e\u4e2d\u03b1-\u848e\u70ef\u7684\u6c27\u5316\u53cd\u5e94\u4f5c\u4e3a\u8003\u5bdf\u5bf9\u8c61\uff0c\u9488\u5bf9\u53cd\u5e94\u4ea7\u7387\u3001\u53cd\u5e94\u8d28\u91cf\u6548\u7387\u3001\u78b3\u7ecf\u6d4e\u6027\u3001\u539f\u5b50\u7ecf\u6d4e\u6027\u3001\u548cE-Factor\u8fdb\u884c\u4e86\u5bf9\u6bd4\uff0c\u672c\u6587\u5de5\u4f5c\u5728\u8fd9\u4e9b\u6307\u6807\u4e2d\u90fd\u8868\u73b0\u4f18\u5f02\u3002\u4e3a\u4e86\u4e86\u89e3\u50ac\u5316\u673a\u7406\uff0c\u4f5c\u8005\u5f00\u5c55\u4e86\u9178\u8680\u5b9e\u9a8c\u548cKSCN\u4e2d\u6bd2\u5b9e\u9a8c\u7b49\u673a\u7406\u5b9e\u9a8c\uff0c\u8bc1\u660e\u4e86FeNx\u7269\u79cd\u548cFexOy\u7269\u79cd\u5bf9\u50ac\u5316\u6d3b\u6027\u90fd\u6709\u8d21\u732e\uff0c\u4f46\u524d\u8005\u5360\u4e3b\u5bfc\u5730\u4f4d\u3002\u53e6\u5916\uff0c\u901a\u8fc7\u81ea\u7531\u57fa\u6355\u83b7\u5b9e\u9a8c\u9a8c\u8bc1\u4e86\u53cd\u5e94\u7ecf\u5386\u81ea\u7531\u57fa\u8fc7\u7a0b\uff0c\u6c27\u540c\u4f4d\u7d20\u6807\u8bb0\u5b9e\u9a8c\u8bc1\u660e\u4ea7\u7269\u4e2d\u7684\u6c27\u539f\u5b50\u6765\u6e90\u4e8e\u7a7a\u6c14\u4e2d\u7684\u6c27\u6c14\u3002 \u7efc\u4e0a\u6240\u8ff0\uff0c\u672c\u6587\u5f00\u53d1\u4e86\u4e00\u79cd\u4f4e\u6210\u672c\u7684\u7eb3\u7c73\u94c1\u50ac\u5316\u5242\u7528\u4e8e\u91cd\u8981\u7684\u70ef\u4e19\u4f4dC-H\u6c27\u5316\u53cd\u5e94\uff0c\u5e76\u5728\u6548\u7387\u3001\u53ef\u6301\u7eed\u6027\u548c\u9009\u62e9\u6027\u65b9\u9762\u6bd4\u73b0\u6709\u7684\u8bb8\u591a\u65b9\u6cd5\u6709\u663e\u8457\u7684\u4f18\u52bf\u3002\u8be5\u65b9\u6cd5\u5e95\u7269\u8303\u56f4\u5e7f\uff0c\u9002\u7528\u4e8e\u8bb8\u591a\u5929\u7136\u4ea7\u7269\u7ed3\u6784\u5206\u5b50\uff0c\u6df1\u5165\u7684\u673a\u7406\u7814\u7a76\u4e5f\u786e\u5b9a\u4e86\u50ac\u5316\u6d3b\u6027\u7269\u79cd\u53ca\u673a\u7406\u8def\u7ebf\u3002 \u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5510\u4ece\u8f89\u7814\u7a76\u5458\u4e3a\u901a\u8baf\u4f5c\u8005\uff0c\u5510\u4ece\u8f89\u8bfe\u9898\u7ec4\u7855\u58eb\u7814\u7a76\u751f\u59dc\u6bc5\u6770\u4e3a\u7b2c\u4e00\u4f5c\u8005\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff0822001086\u300122371083\uff09\u3001\u4e2d\u592e\u9ad8\u6821\u57fa\u672c\u79d1\u7814\u4e1a\u52a1\u8d39\uff08HUST 2020kfyXJJS094\uff09\u3001\u5317\u4eac\u5927\u5b66\u5929\u7136\u836f\u7269\u53ca\u4eff\u751f\u836f\u7269\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\uff08K202011\uff09\u7684\u8d44\u52a9\u3002\u611f\u8c22\u5317\u4eac\u5927\u5b66\u7126\u5b81\u6559\u6388\u5bf9\u6c27\u540c\u4f4d\u7d20\u6807\u8bb0\u5b9e\u9a8c\u7684\u5e2e\u52a9\uff0c\u4ee5\u53ca\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u674e\u660e\u6d69\u6559\u6388\u5bf9\u4e8e\u7eff\u8272\u5316\u5b66\u6307\u6807\u8ba1\u7b97\u7684\u6307\u5bfc\u3002 \u3010\u8bfe\u9898\u7ec4\u4ecb\u7ecd\u3011 \u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u5510\u4ece\u8f89\u7814\u7a76\u5458\uff0c2011\u5e74\u672c\u79d1\u6bd5\u4e1a\u4e8e\u534e\u4e2d\u79d1\u6280\u5927\u5b66\uff0c2011-2016\u5e74\u5728\u5317\u4eac\u5927\u5b66\u76f4\u63a5\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\uff08\u5bfc\u5e08\uff1a\u7126\u5b81\u6559\u6388\uff09\uff0c\u968f\u540e\u5728\u5fb7\u56fd\u548c\u7f8e\u56fd\u7684\u77e5\u540d\u9ad8\u6821\u3001\u7814\u7a76\u6240\u8fdb\u884c\u535a\u58eb\u540e\u7814\u7a76(\u5bfc\u5e08\uff1aMatthias Beller, David Sarlah, Liming Zhang)\uff0c2020\u5e74\u56de\u56fd\u4f5c\u4e3a\u8bfe\u9898\u7ec4\u957f\u5f00\u5c55\u72ec\u7acb\u7814\u7a76\u3002 […]","protected":false},"author":26,"featured_media":48646,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1271],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/01\/7f88dbbcaa77a1d28f1e88164d4f6dcd-2.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-cEz","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/48643"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=48643"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/48643\/revisions"}],"predecessor-version":[{"id":48648,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/48643\/revisions\/48648"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/48646"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=48643"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=48643"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=48643"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}