{"id":49425,"date":"2024-04-08T09:08:12","date_gmt":"2024-04-08T01:08:12","guid":{"rendered":"\/\/www.gsbet888.com\/?p=49425"},"modified":"2024-04-08T09:10:14","modified_gmt":"2024-04-08T01:10:14","slug":"org-lett-%ef%bc%9anhc-%e5%82%ac%e5%8c%96%e7%83%af%e7%83%83%e7%9a%84acylphosphorylation%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2024\/04\/org-lett-%ef%bc%9anhc-%e5%82%ac%e5%8c%96%e7%83%af%e7%83%83%e7%9a%84acylphosphorylation%e5%8f%8d%e5%ba%94%e6%96%b9%e6%b3%95%e5%ad%a6.html","title":{"rendered":"Org. Lett. \uff1aNHC-\u50ac\u5316\u70ef\u70c3\u7684Acylphosphorylation\u53cd\u5e94\u65b9\u6cd5\u5b66"},"content":{"rendered":"<p style=\"text-align: justify;\">\u4f5c\u8005\uff1a\u6749\u6749<\/p>\n<h4 style=\"text-align: justify;\">\u5bfc\u8bfb\uff1a<\/h4>\n<p style=\"text-align: justify;\">\u8fd1\u65e5\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u8d75\u5251\u6960\u8bfe\u9898\u7ec4\u5728<em>Org. Lett.<\/em><em>\u00a0<\/em>\u4e2d\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684NHC (<em>N<\/em>-Heterocyclic carbene)-\u50ac\u5316\u70ef\u70c3\u3001\u919b\u4e0e\u809f\u81a6\u9178\u916f\u7684acylphosphorylation\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217<em>\u03b3<\/em>-oxo-\u81a6\u9178\u916f\u5206\u5b50\u7684\u6784\u5efa\u3002<\/p>\n<blockquote><p>Synthesis of <em>\u03b3<\/em>-Oxo-phosphonates via <em>N<\/em>-Heterocyclic Carbene-Catalyzed Acylphosphorylation of Alkenes<\/p>\n<p>J. Mo, S. Sun, H. Xu, H. Shu, J. Zhao, <em>Org. Lett.<\/em><strong>2024<\/strong>, <em>26<\/em>, 2197. doi: <a href=\"https:\/\/doi.org\/10.1021\/acs.orglett.4c00234\">10.1021\/acs.orglett.4c00234<\/a><u>.<\/u><\/p><\/blockquote>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49427 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image002-1.jpg\" alt=\"\" width=\"554\" height=\"268\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image002-1.jpg 554w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image002-1-300x145.jpg 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<h4 style=\"text-align: justify;\">\u6b63\u6587\uff1a<\/h4>\n<p style=\"text-align: justify;\">\u6709\u673a\u81a6\u5316\u5408\u7269\u5728\u519c\u4e1a\u3001\u6750\u6599\u79d1\u5b66\u3001\u6709\u673a\u5408\u6210\u4e0e\u836f\u7269\u53d1\u73b0\u7b49\u9886\u57df\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5e76\u4e14\uff0c\u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u91cc\uff0c\u8bf8\u591a\u7814\u7a76\u56e2\u961f\u5df2\u7ecf\u6210\u529f\u8bbe\u8ba1\u51fa\u591a\u79cd\u5229\u7528\u5149\u6c27\u5316\u8fd8\u539f\u751f\u6210\u542b\u78f7\u81ea\u7531\u57fa\u6784\u5efaC\u2212P\u952e\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565 (Scheme 1A)<sup>[1]<\/sup>\u3002\u7136\u800c\uff0c\u901a\u8fc7\u6709\u673a\u50ac\u5316\u5355\u7535\u5b50\u8f6c\u79fb\u751f\u6210\u78f7\u4e2d\u5fc3\u81ea\u7531\u57fa\u7684\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u76ee\u524d\u5374\u8f83\u5c11\u6709\u76f8\u5173\u7684\u7814\u7a76\u62a5\u9053<sup>[2]<\/sup>\u3002\u53d7\u5230\u8fd1\u5e74\u6765\u5229\u7528NHC\u6709\u673a\u50ac\u5316\u751f\u6210ketyl\u81ea\u7531\u57fa<strong>B<\/strong>\u53c2\u4e0e\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66(Scheme 1B)<sup>[3]<\/sup> \u76f8\u5173\u7814\u7a76\u62a5\u9053\u7684\u542f\u53d1\uff0c\u8fd9\u91cc\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u8d75\u5251\u6960\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684NHC-\u50ac\u5316\u70ef\u70c3\u3001\u919b\u4e0e\u809f\u81a6\u9178\u916f\u7684acylphosphorylation\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217<em>\u03b3<\/em>-oxo-\u81a6\u9178\u916f\u5206\u5b50\u7684\u6784\u5efa (Scheme 1C)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49428 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image003-3.jpg\" alt=\"\" width=\"554\" height=\"613\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image003-3.jpg 554w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image003-3-271x300.jpg 271w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p style=\"text-align: justify;\">\u9996\u5148\uff0c\u4f5c\u8005\u91c7\u7528\u82ef\u7532\u919b<strong>1a<\/strong>\u3001\u82ef\u4e59\u70ef<strong>2a<\/strong>\u4e0e\u809f\u81a6\u9178\u916f\u884d\u751f\u7269<strong>3<\/strong>\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528\u809f\u81a6\u9178\u916f\u884d\u751f\u7269<strong>3c<\/strong>\u4f5c\u4e3a\u5e95\u7269\uff0c<strong>N3<\/strong>\u4f5c\u4e3a\u9884\u50ac\u5316\u5242\uff0cK<sub>2<\/sub>CO<sub>3<\/sub>\u4f5c\u4e3a\u78b1\uff0c\u5728CH<sub>3<\/sub>CN\u53cd\u5e94\u6eb6\u5242\u4e2d\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a60<sup>o<\/sup>C\uff0c\u6700\u7ec8\u83b7\u5f9783%\u6536\u7387\u7684\u4ea7\u7269<strong>4aa<\/strong>\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49429 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image004-1.jpg\" alt=\"\" width=\"554\" height=\"766\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image004-1.jpg 554w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image004-1-217x300.jpg 217w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/p>\n<p style=\"text-align: justify;\">\u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5206\u522b\u5bf9\u4e00\u7cfb\u5217\u919b\u5e95\u7269 (Scheme 2)\u70ef\u70c3\u4ee5\u53ca\u81a6\u9178\u916f\u5e95\u7269 (Scheme 3)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49430 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image005-1.jpg\" alt=\"\" width=\"554\" height=\"862\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image005-1.jpg 554w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image005-1-193x300.jpg 193w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49431 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image006.png\" alt=\"\" width=\"548\" height=\"269\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image006.png 548w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image006-300x147.png 300w\" sizes=\"(max-width: 548px) 100vw, 548px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49432 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image007-1.jpg\" alt=\"\" width=\"554\" height=\"922\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image007-1.jpg 554w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image007-1-180x300.jpg 180w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49433 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image008.png\" alt=\"\" width=\"509\" height=\"206\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image008.png 509w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image008-300x121.png 300w\" sizes=\"(max-width: 509px) 100vw, 509px\" \/><\/p>\n<p style=\"text-align: justify;\">\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5bf9\u4e0a\u8ff0acylphosphorylation\u8fc7\u7a0b\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76 (Scheme 4A)\u3002\u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\u4ee5\u53ca\u524d\u671f\u76f8\u5173\u7684\u6587\u732e\u62a5\u9053<sup>[3]<\/sup>\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 4B)\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49434 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image009-1.jpg\" alt=\"\" width=\"554\" height=\"588\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image009-1.jpg 554w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image009-1-283x300.jpg 283w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49435 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image010.png\" alt=\"\" width=\"488\" height=\"81\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image010.png 488w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/04\/image010-300x50.png 300w\" sizes=\"(max-width: 488px) 100vw, 488px\" \/><\/p>\n<p style=\"text-align: justify;\">\u603b\u7ed3\uff1a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u8d75\u5251\u6960\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684NHC-\u50ac\u5316\u70ef\u70c3\u3001\u919b\u4e0e\u809f\u81a6\u9178\u916f\u7684acylphosphorylation\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217<em>\u03b3<\/em>-oxo-\u81a6\u9178\u916f\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565\u5177\u6709\u5e95\u7269\u8303\u56f4\u5e7f\u6cdb\u4ee5\u53ca\u4f18\u826f\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u7b49\u4f18\u52bf\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/h4>\n<ul style=\"text-align: justify;\">\n<li>[1] I. Kim, G. Kang, K. Lee, B. Park, D. Kang, H. Jung, Y. T. He, M. H. Baik, S. Hong, <em>J. Am. Chem. Soc. <\/em><strong>2019<\/strong>, <em>141<\/em>, 9239. doi:<a href=\"https:\/\/doi.org\/10.1021\/jacs.9b02013\">10.1021\/jacs.9b02013<\/a>.<\/li>\n<li>[2] T. Ishii, K. Nagao, H. Ohmiya, <em>Chem. Sci. <\/em><strong>2020<\/strong>, <em>11<\/em>, 5630. doi:<a href=\"https:\/\/doi.org\/10.1039\/D0SC01538E\">10.1039\/D0SC01538E<\/a>.<\/li>\n<li>[3] W. Liu, W. Lee, H. Shu, C. Xiao, H. Xu, X. Chen, K. N. Houk, J. Zhao, <em>J. Am. Chem. Soc. <\/em><strong>2022<\/strong>, <em>144<\/em>, 22767. doi:<a href=\"https:\/\/doi.org\/10.1021\/jacs.2c11209\">10.1021\/jacs.2c11209<\/a>.<\/li>\n<\/ul>\n<p style=\"text-align: justify;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d.<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u6749\u6749 \u5bfc\u8bfb\uff1a \u8fd1\u65e5\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u8d75\u5251\u6960\u8bfe\u9898\u7ec4\u5728Org. Lett.\u00a0\u4e2d\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684NHC (N-Heterocyclic carbene)-\u50ac\u5316\u70ef\u70c3\u3001\u919b\u4e0e\u809f\u81a6\u9178\u916f\u7684acylphosphorylation\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u03b3-oxo-\u81a6\u9178\u916f\u5206\u5b50\u7684\u6784\u5efa\u3002 Synthesis of \u03b3-Oxo-phosphonates via N-Heterocyclic Carbene-Catalyzed Acylphosphorylation of Alkenes J. Mo, S. Sun, H. Xu, H. Shu, J. Zhao, Org. Lett.2024, 26, 2197. doi: 10.1021\/acs.orglett.4c00234. \u6b63\u6587\uff1a \u6709\u673a\u81a6\u5316\u5408\u7269\u5728\u519c\u4e1a\u3001\u6750\u6599\u79d1\u5b66\u3001\u6709\u673a\u5408\u6210\u4e0e\u836f\u7269\u53d1\u73b0\u7b49\u9886\u57df\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u5e76\u4e14\uff0c\u5728\u8fc7\u53bb\u7684\u51e0\u5e74\u91cc\uff0c\u8bf8\u591a\u7814\u7a76\u56e2\u961f\u5df2\u7ecf\u6210\u529f\u8bbe\u8ba1\u51fa\u591a\u79cd\u5229\u7528\u5149\u6c27\u5316\u8fd8\u539f\u751f\u6210\u542b\u78f7\u81ea\u7531\u57fa\u6784\u5efaC\u2212P\u952e\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565 (Scheme 1A)[1]\u3002\u7136\u800c\uff0c\u901a\u8fc7\u6709\u673a\u50ac\u5316\u5355\u7535\u5b50\u8f6c\u79fb\u751f\u6210\u78f7\u4e2d\u5fc3\u81ea\u7531\u57fa\u7684\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u76ee\u524d\u5374\u8f83\u5c11\u6709\u76f8\u5173\u7684\u7814\u7a76\u62a5\u9053[2]\u3002\u53d7\u5230\u8fd1\u5e74\u6765\u5229\u7528NHC\u6709\u673a\u50ac\u5316\u751f\u6210ketyl\u81ea\u7531\u57faB\u53c2\u4e0e\u5076\u8054\u53cd\u5e94\u65b9\u6cd5\u5b66(Scheme 1B)[3] \u76f8\u5173\u7814\u7a76\u62a5\u9053\u7684\u542f\u53d1\uff0c\u8fd9\u91cc\uff0c\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u8d75\u5251\u6960\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684NHC-\u50ac\u5316\u70ef\u70c3\u3001\u919b\u4e0e\u809f\u81a6\u9178\u916f\u7684acylphosphorylation\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u03b3-oxo-\u81a6\u9178\u916f\u5206\u5b50\u7684\u6784\u5efa (Scheme 1C)\u3002 \u9996\u5148\uff0c\u4f5c\u8005\u91c7\u7528\u82ef\u7532\u919b1a\u3001\u82ef\u4e59\u70ef2a\u4e0e\u809f\u81a6\u9178\u916f\u884d\u751f\u72693\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u7528\u809f\u81a6\u9178\u916f\u884d\u751f\u72693c\u4f5c\u4e3a\u5e95\u7269\uff0cN3\u4f5c\u4e3a\u9884\u50ac\u5316\u5242\uff0cK2CO3\u4f5c\u4e3a\u78b1\uff0c\u5728CH3CN\u53cd\u5e94\u6eb6\u5242\u4e2d\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a60oC\uff0c\u6700\u7ec8\u83b7\u5f9783%\u6536\u7387\u7684\u4ea7\u72694aa\u3002 \u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5206\u522b\u5bf9\u4e00\u7cfb\u5217\u919b\u5e95\u7269 (Scheme 2)\u70ef\u70c3\u4ee5\u53ca\u81a6\u9178\u916f\u5e95\u7269 (Scheme 3)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002 \u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5bf9\u4e0a\u8ff0acylphosphorylation\u8fc7\u7a0b\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76 (Scheme 4A)\u3002\u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\u4ee5\u53ca\u524d\u671f\u76f8\u5173\u7684\u6587\u732e\u62a5\u9053[3]\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 4B)\u3002 \u603b\u7ed3\uff1a\u5927\u8fde\u7406\u5de5\u5927\u5b66\u7684\u8d75\u5251\u6960\u8bfe\u9898\u7ec4\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684NHC-\u50ac\u5316\u70ef\u70c3\u3001\u919b\u4e0e\u809f\u81a6\u9178\u916f\u7684acylphosphorylation\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u03b3-oxo-\u81a6\u9178\u916f\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u5408\u6210\u8f6c\u5316\u7b56\u7565\u5177\u6709\u5e95\u7269\u8303\u56f4\u5e7f\u6cdb\u4ee5\u53ca\u4f18\u826f\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u7b49\u4f18\u52bf\u3002 \u53c2\u8003\u6587\u732e\uff1a [1] I. Kim, G. Kang, K. Lee, B. Park, D. Kang, H. Jung, Y. T. He, M. H. Baik, S. Hong, J. Am. Chem. Soc. 2019, 141, 9239. doi:10.1021\/jacs.9b02013. [2] T. Ishii, K. Nagao, H. Ohmiya, Chem. Sci. 2020, 11, 5630. doi:10.1039\/D0SC01538E. [3] W. Liu, W. Lee, H. Shu, C. Xiao, H. Xu, X. Chen, K. 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