{"id":49735,"date":"2024-05-09T08:00:30","date_gmt":"2024-05-09T00:00:30","guid":{"rendered":"\/\/www.gsbet888.com\/?p=49735"},"modified":"2024-05-08T21:57:08","modified_gmt":"2024-05-08T13:57:08","slug":"%e3%80%8cspotlight-research%e3%80%8d%e5%8f%af%e8%a7%81%e5%85%89%e4%bb%8b%e5%af%bc%e7%9a%84%e5%8f%8c%e6%a0%b8%e9%87%91%e5%82%ac%e5%8c%96%e5%81%95%e4%ba%8c%e6%b0%af%e7%83%b7%e7%83%83%e7%9a%84%e5%8f%91","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2024\/05\/%e3%80%8cspotlight-research%e3%80%8d%e5%8f%af%e8%a7%81%e5%85%89%e4%bb%8b%e5%af%bc%e7%9a%84%e5%8f%8c%e6%a0%b8%e9%87%91%e5%82%ac%e5%8c%96%e5%81%95%e4%ba%8c%e6%b0%af%e7%83%b7%e7%83%83%e7%9a%84%e5%8f%91.html","title":{"rendered":"\u300cSpotlight Research\u300d\u53ef\u89c1\u5149\u4ecb\u5bfc\u7684\u53cc\u6838\u91d1\u50ac\u5316\u5055\u4e8c\u6c2f\u70f7\u70c3\u7684\u53d1\u6563\u6027\u53bb\u6c2f\u787c\u5316\u53cd\u5e94"},"content":{"rendered":"<p style=\"text-align: justify;\"><strong>\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a<\/strong><\/p>\n<p style=\"text-align: justify;\">\u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u6765\u81ea\u5357\u4eac\u5927\u5b66\u7684\u535a\u58eb\u751f\u5d47\u6210\u9f99\u4e3a\u6211\u4eec\u5206\u4eab\u3002<\/p>\n<p style=\"text-align: justify;\">2024\u5e745\u67082\u65e5\uff0c<em>Nat. Commun. <\/em>\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea<strong>\u5357\u4eac\u5927\u5b66\u8c22\u52b2\u6559\u6388<\/strong>\u56e2\u961f\u9898\u4e3a\u300cDinuclear gold-catalyzed divergent dechlorinative radical borylation of <em>gem<\/em>-dichloroalkanes\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u6587\u4e2d\uff0c\u4ed6\u4eec\u5229\u7528\u53ef\u89c1\u5149\u4ecb\u5bfc\u7684\u53cc\u6838\u91d1\u50ac\u5316\u7b56\u7565\uff0c\u5b9e\u73b0\u4e86\u5055\u4e8c\u6c2f\u70f7\u70c3\u7684\u53d1\u6563\u6027\u53bb\u6c2f\u787c\u5316\u53cd\u5e94\uff0c\u5408\u6210\u4e86\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u70f7\u57fa\u787c\u9178\u916f\u3001a-\u6c2f\u4ee3\u787c\u9178\u916f\u548c\u5055\u4e8c\u787c\u9178\u916f\u884d\u751f\u7269,\u6269\u5c55\u4e86\u5055\u4e8c\u6c2f\u4ee3\u70f7\u70c3\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u6a21\u5f0f\u3002<\/p>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49739 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/025fbbb20c0c18652719f8f0c6fd86b6.png\" alt=\"\" width=\"962\" height=\"247\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/025fbbb20c0c18652719f8f0c6fd86b6.png 962w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/025fbbb20c0c18652719f8f0c6fd86b6-300x77.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/025fbbb20c0c18652719f8f0c6fd86b6-680x175.png 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/025fbbb20c0c18652719f8f0c6fd86b6-768x197.png 768w\" sizes=\"(max-width: 962px) 100vw, 962px\" \/><\/p>\n<blockquote>\n<p style=\"text-align: justify;\">\u201cDinuclear gold-catalyzed divergent dechlorinative radical borylation of <em>gem<\/em>-dichloroalkanes Cheng-Long Ji, Hongliang Chen, Qi Gao, Jie Han, Weipeng Li, Jin Xie* <em>Nat. Commun. <\/em><strong>2023<\/strong><em>, <\/em>15<em>, <\/em>3721<em>.<\/em>\u201d<\/p>\n<\/blockquote>\n<h4 style=\"text-align: justify;\"><strong>Q1. <\/strong><strong>\u8bf7\u5bf9\u201c<\/strong><strong>Dinuclear gold-catalyzed divergent dechlorinative radical borylation of <em>gem<\/em>-dichloroalkanes<\/strong><strong>\u201d<\/strong><strong>\u4f5c<\/strong><strong>\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002<\/strong><\/h4>\n<p style=\"text-align: justify;\">\u8fd1\u5e74\u6765\uff0c\u6709\u673a\u787c\u5316\u5408\u7269\u56e0\u5176\u72ec\u7279\u7684\u7406\u5316\u6027\u80fd\u800c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6709\u673a\u5408\u6210\u3001\u836f\u7269\u53d1\u73b0\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u3002\u76ee\u524d\uff0c\u5408\u6210\u70f7\u57fa\u787c\u9178\u916f\u7684\u65b9\u6cd5\u4e3b\u8981\u5305\u62ec\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5364\u4ee3\u70c3\u7684\u53bb\u5364\u787c\u5316\u3001\u4e0d\u9971\u548cC=C\u952e\u7684\u52a0\u6c22\u787c\u5316\u8fc7\u7a0b\u4ee5\u53caC\u2212H\u952e\u7684\u6c27\u5316\u787c\u5316\u7b49\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u901a\u5e38\u5b58\u5728\u5b98\u80fd\u56e2\u8010\u53d7\u6027\u3001\u53cd\u5e94\u6761\u4ef6\u82db\u523b\u4ee5\u53ca\u70ef\u70c3\u7684\u533a\u57df\u9009\u62e9\u6027\u7b49\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u7c7b\u7b80\u5355\u3001\u6e29\u548c\u3001\u9ad8\u6548\u7684\u65b9\u6cd5\u5408\u6210\u6709\u673a\u787c\u5316\u5408\u7269\u4e00\u76f4\u662f\u8be5\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u5728\u524d\u671f\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u6211\u4eec\u5b9e\u73b0\u4e86\u53ef\u89c1\u5149\u8bf1\u5bfc\u4e0b\u53cc\u6838\u91d1\u50ac\u5316\u5055\u4e8c\u6c2f\u4ee3\u70f7\u70c3\u53c2\u4e0e\u7684\u53d1\u6563\u6027\u81ea\u7531\u57fa\u53bb\u6c2f\u787c\u5316\u53cd\u5e94\uff0c\u5408\u6210\u4e86\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u70f7\u57fa\u787c\u9178\u916f\u3001a-\u6c2f\u4ee3\u787c\u9178\u916f\u548c\u5055\u4e8c\u787c\u9178\u916f\u884d\u751f\u7269\u3002\u8be5\u65b9\u6cd5\u4e5f\u9002\u7528\u4e8e\u590d\u6742\u5929\u7136\u4ea7\u7269\u548c\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u4fee\u9970\uff0c\u5c55\u73b0\u4e86\u53cc\u6838\u91d1\u50ac\u5316\u4f53\u7cfb\u826f\u597d\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u53cc\u6838\u91d1\u50ac\u5316\u5242\u548c\u6eb6\u5242\u7edc\u5408\u7684B<sub>2<\/sub>cat<sub>2<\/sub>\u4e4b\u95f4\u7684\u5f31\u914d\u4f4d\u4f5c\u7528\u5728\u60f0\u6027C\u2212Cl\u952e\u6d3b\u5316\u4ee5\u53ca\u540e\u7eed\u53bb\u6c2f\u787c\u5316\u8fc7\u7a0b\u4e2d\u53d1\u6325\u7740\u5173\u952e\u4f5c\u7528\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>Q2. <\/strong><strong>\u6709\u5173\u672c\u6b21\u7814\u7a76\u7684\u65f6\u5019\u9047\u5230\u8fc7\u600e\u6837\u7684\u56f0\u96be\u5462\uff1f\u53c8\u662f\u600e\u6837\u514b\u670d\u7684\u5462<\/strong><\/h4>\n<p style=\"text-align: justify;\">\u5728\u8fdb\u884c\u672c\u6b21\u7814\u7a76\u8fc7\u7a0b\u4e2d\uff0c\u6700\u5927\u7684\u6311\u6218\u662f\u5bf9\u5316\u5408\u7269\u7684\u5206\u79bb\u63d0\u7eaf\u5de5\u4f5c\u3002\u7531\u4e8e\u4e00\u4e9b\u8102\u80aa\u5316\u5408\u7269\u8367\u5149\u7279\u6027\u8f83\u5f31\uff0c\u6240\u4ee5\u5f00\u59cb\u65f6\u5728\u5206\u79bb\u63d0\u7eaf\u4e0a\u82b1\u8d39\u4e86\u4e00\u4e9b\u7cbe\u529b\u3002\u4f46\u968f\u7740\u5bf9\u53cd\u5e94\u7684\u7406\u89e3\u4e0d\u65ad\u6df1\u5165\uff0c\u7ecf\u8fc7\u5c1d\u8bd5\u4e0d\u540c\u7684\u63d0\u7eaf\u65b9\u6cd5\uff0c\u5305\u62ec\u663e\u8272\u5242\u7684\u8fd0\u7528\u4ee5\u53ca\u4e0d\u540c\u5206\u79bb\u624b\u6bb5\u6210\u529f\u7684\u89e3\u51b3\u4e86\u8fd9\u4e2a\u95ee\u9898\u3002\u505a\u5b9e\u9a8c\u5c31\u662f\u8fd9\u6837\uff0c\u8981\u575a\u6301\uff0c\u591a\u52a8\u624b\uff0c\u591a\u603b\u7ed3\uff0c\u603b\u80fd\u627e\u5230\u89e3\u51b3\u7684\u529e\u6cd5\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>Q3. <\/strong><strong>\u672c\u6b21\u7814\u7a76\u4e3b\u4f53\uff0c\u6709\u6ca1\u6709\u4ec0\u4e48\u8ba9\u60a8\u611f\u89c9\u7279\u522b\u8f9b\u82e6\u548c\u70e7\u8111\u5462\uff1f<\/strong><\/h4>\n<p style=\"text-align: justify;\">\u7279\u522b\u8f9b\u82e6\u7684\u95ee\u9898\u662f\u5728\u4e8e\u73b0\u6709\u7684\u53cd\u5e94\u673a\u5236\u7684\u7814\u7a76\u3002\u7531\u4e8e\u53cd\u5e94\u7684\u4e2d\u95f4\u4f53\u6781\u4e0d\u7a33\u5b9a\uff0c\u6211\u4eec\u82b1\u8d39\u4e86\u5927\u91cf\u65f6\u95f4\u4ee5\u53ca\u5c1d\u8bd5\u4e86\u4e0d\u540c\u7684\u65b9\u6cd5\u6765\u5408\u6210\u8be5\u4e2d\u95f4\u4f53\u3002\u6700\u540e\uff0c\u901a\u8fc7\u63a7\u5236\u5b9e\u9a8c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u6211\u4eec\u7684\u731c\u60f3\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>Q4. <\/strong><strong>\u5c06\u6765\u60f3\u7ee7\u7eed\u7814\u7a76\u5316\u5b66\u7684\u54ea\u4e2a\u65b9\u5411\u5462\uff1f<\/strong><\/h4>\n<p style=\"text-align: justify;\">\u53ef\u80fd\u8fd8\u662f\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\uff0c\u7ee7\u7eed\u6df1\u5165\u7814\u7a76\u53cc\u6838\u91d1\u5c5e\u5316\u5b66\u7684\u72ec\u7279\u50ac\u5316\u673a\u5236\u4ee5\u53ca\u63a2\u7d22\u5176\u53c2\u4e0e\u65b0\u578b\u53cd\u5e94\u6a21\u5f0f\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>Q5. <\/strong><strong>\u6700\u540e\uff0c\u6709\u4ec0\u4e48\u60f3\u5bf9\u5404\u4f4d\u8bfb\u8005\u8bf4\u7684\u5417\uff1f<\/strong><\/h4>\n<p style=\"text-align: justify;\">\u80fd\u8bfb\u5230\u8fd9\u4e2a\u6587\u7ae0\u548c\u63a8\u9001\u7684\u57fa\u672c\u90fd\u662f\u540c\u884c\u7684\u8001\u5e08\u548c\u540c\u5b66\uff0c\u7b80\u5355\u5206\u4eab\u4e00\u4e0b\u505a\u8bfe\u9898\u7684\u5fc3\u5f97\u4f53\u4f1a\uff1a\u5728\u79d1\u7814\u7684\u6f2b\u957f\u5f81\u9014\u4e2d\uff0c\u56f0\u96be\u548c\u632b\u6298\u5982\u540c\u9669\u5cfb\u7684\u5c71\u5cf0\uff0c\u65f6\u5e38\u6a2a\u4e98\u5728\u6211\u4eec\u524d\u884c\u7684\u9053\u8def\u4e0a\u3002\u7136\u800c\uff0c\u9762\u5bf9\u8fd9\u4e9b\u6311\u6218\uff0c\u6211\u4eec\u5fc5\u987b\u5b66\u4f1a\u51b7\u9759\u5730\u5ba1\u89c6\u95ee\u9898\uff0c\u4ee5\u5ba2\u89c2\u7684\u6001\u5ea6\u5206\u6790\u6bcf\u4e00\u4e2a\u7ec6\u8282\uff0c\u5bfb\u627e\u7a81\u7834\u7684\u53ef\u80fd\u3002<\/p>\n<p style=\"text-align: justify;\">\u5728\u6b64\u6211\u8981\u7279\u522b\u611f\u8c22\u8c22\u52b2\u8001\u5e08\u5728\u6574\u4e2a\u8bfe\u9898\u7814\u7a76\u4e2d\u63d0\u4f9b\u7684\u6089\u5fc3\u6307\u5bfc\u3002\u8c22\u8001\u5e08\u5bf9\u4e8e\u79d1\u7814\u63a2\u7d22\u4e00\u4e1d\u4e0d\u82df\u7684\u6001\u5ea6\u548c\u6562\u4e8e\u62fc\u640f\u7684\u7cbe\u795e\uff0c\u90fd\u662f\u503c\u5f97\u6211\u4eec\u7ec8\u751f\u5b66\u4e60\u7684\u3002\u4ed6\u5e38\u5e38\u6559\u5bfc\u6211\u4eec\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u672c\u6765\u5c31\u662f\u5145\u6ee1\u56f0\u96be\u4e0e\u6311\u6218\u7684\uff0c\u4f46\u662f\u529e\u6cd5\u603b\u6bd4\u56f0\u96be\u591a\u3002\u53ea\u8981\u591a\u601d\u8003\uff0c\u591a\u52aa\u529b\uff0c\u6700\u540e\u90fd\u80fd\u8fce\u5203\u800c\u89e3\u3002\u6b64\u5916\uff0c\u6211\u4e5f\u8981\u611f\u6069\u6c42\u5b66\u8def\u4e0a\u9047\u89c1\u7684\u6bcf\u4e00\u4e2a\u4eba\uff0c\u6211\u7684\u4eba\u751f\u56e0\u4f60\u4eec\u7684\u5b58\u5728\u800c\u66f4\u52a0\u7cbe\u5f69\u3002<\/p>\n<h4 style=\"text-align: justify;\"><strong>\u8c22\u52b2\u8bfe\u9898\u7ec4\u7b80\u4ecb<\/strong><\/h4>\n<p style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-49738 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/image005.jpg\" alt=\"\" width=\"799\" height=\"291\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/image005.jpg 799w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/image005-300x109.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/image005-680x248.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/05\/image005-768x280.jpg 768w\" sizes=\"(max-width: 799px) 100vw, 799px\" \/><\/p>\n<p style=\"text-align: justify;\">\u8c22\u52b2\u6559\u6388\u4e8e2017\u5e747\u6708\u52a0\u5165\u5357\u4eac\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u548c\u914d\u4f4d\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5f00\u5c55\u72ec\u7acb\u79d1\u7814\u5de5\u4f5c\u3002\u7814\u7a76\u65b9\u5411\u4e3a\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u3001\u81ea\u7531\u57fa\u5316\u5b66\u4e0e\u6218\u7565\u6709\u673a\u65b0\u6750\u6599\uff0c\u901a\u8fc7\u5206\u5b50\u6784\u7b51\u65b0\u6982\u5ff5\u548c\u65b0\u7b56\u7565\u7684\u53d1\u5c55\u4e0e\u521b\u65b0\uff0c\u8de8\u5b66\u79d1\u89e3\u51b3\u79d1\u5b66\u9886\u57df\u4e2d\u5b58\u5728\u7684\u91cd\u5927\u6311\u6218\u3002\u76ee\u524d\u5df2\u5728<em>Chem. Rev.<\/em>, <em>Chem. Soc. Rev., Acc. Chem. Res., Nat. Chem., Nat. Catal., Nat. Synth., Chem<\/em>, <em>J. Am. Chem. Soc., Angew. Chem. Int. Ed.<\/em>, <em>Nat. Commun<\/em><em>.<\/em>\u7b49\u56fd\u9645\u8457\u540d\u5b66\u672f\u671f\u520a\u53d1\u8868\u8bba\u658780\u4f59\u7bc7\uff0c\u88ab\u5f155500\u4f59\u6b21\uff1b\u7533\u8bf7\u4e13\u522920\u9879\uff0c\u6388\u6743\u56fd\u9645\u4e13\u52291\u9879\uff0c\u4e2d\u56fd\u4e13\u522912\u9879\u3002\u7814\u7a76\u6210\u679c\u591a\u6b21\u88ab<em>Nat. Catal., Synform, Synfacts<\/em>\u7b49\u4eae\u70b9\u4ecb\u7ecd\uff0c<em>Angew. Chem.<\/em>\u5728\u201cAuthor Profile\u201d\u4e13\u680f\u8fdb\u884c\u4e86\u4eba\u7269\u4e13\u8bbf\u4ecb\u7ecd\u3002\u73b0\u53d7\u9080\u62c5\u4efb\u56fd\u9645\u5b66\u672f\u671f\u520a<em>Gold Bulletin<\/em>\u548c<em>Frontiers in Chemistry<\/em>\u7684\u526f\u4e3b\u7f16;<em> Science China Chemistry<\/em><em>\u3001<\/em><em>Chinese Journal of Chemistry<\/em><em>\u3001<\/em><em>Heteroatom Chemistry<\/em>\u3001\u300a\u5408\u6210\u5316\u5b66\u300b\u3001\u300a\u6709\u673a\u5316\u5b66\u300b\u548c<em>Chemical Synthesis<\/em>\u7b49\u671f\u520a\uff08\u9752\u5e74\uff09\u7f16\u59d4\u3002<\/p>\n<p style=\"text-align: justify;\">\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d.<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a \u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u6765\u81ea\u5357\u4eac\u5927\u5b66\u7684\u535a\u58eb\u751f\u5d47\u6210\u9f99\u4e3a\u6211\u4eec\u5206\u4eab\u3002 2024\u5e745\u67082\u65e5\uff0cNat. Commun. \u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u5357\u4eac\u5927\u5b66\u8c22\u52b2\u6559\u6388\u56e2\u961f\u9898\u4e3a\u300cDinuclear gold-catalyzed divergent dechlorinative radical borylation of gem-dichloroalkanes\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u6587\u4e2d\uff0c\u4ed6\u4eec\u5229\u7528\u53ef\u89c1\u5149\u4ecb\u5bfc\u7684\u53cc\u6838\u91d1\u50ac\u5316\u7b56\u7565\uff0c\u5b9e\u73b0\u4e86\u5055\u4e8c\u6c2f\u70f7\u70c3\u7684\u53d1\u6563\u6027\u53bb\u6c2f\u787c\u5316\u53cd\u5e94\uff0c\u5408\u6210\u4e86\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u70f7\u57fa\u787c\u9178\u916f\u3001a-\u6c2f\u4ee3\u787c\u9178\u916f\u548c\u5055\u4e8c\u787c\u9178\u916f\u884d\u751f\u7269,\u6269\u5c55\u4e86\u5055\u4e8c\u6c2f\u4ee3\u70f7\u70c3\u5728\u6709\u673a\u5408\u6210\u4e2d\u7684\u5e94\u7528\u6a21\u5f0f\u3002 \u201cDinuclear gold-catalyzed divergent dechlorinative radical borylation of gem-dichloroalkanes Cheng-Long Ji, Hongliang Chen, Qi Gao, Jie Han, Weipeng Li, Jin Xie* Nat. Commun. 2023, 15, 3721.\u201d Q1. \u8bf7\u5bf9\u201cDinuclear gold-catalyzed divergent dechlorinative radical borylation of gem-dichloroalkanes\u201d\u4f5c\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002 \u8fd1\u5e74\u6765\uff0c\u6709\u673a\u787c\u5316\u5408\u7269\u56e0\u5176\u72ec\u7279\u7684\u7406\u5316\u6027\u80fd\u800c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6709\u673a\u5408\u6210\u3001\u836f\u7269\u53d1\u73b0\u3001\u6750\u6599\u79d1\u5b66\u7b49\u9886\u57df\u3002\u76ee\u524d\uff0c\u5408\u6210\u70f7\u57fa\u787c\u9178\u916f\u7684\u65b9\u6cd5\u4e3b\u8981\u5305\u62ec\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5364\u4ee3\u70c3\u7684\u53bb\u5364\u787c\u5316\u3001\u4e0d\u9971\u548cC=C\u952e\u7684\u52a0\u6c22\u787c\u5316\u8fc7\u7a0b\u4ee5\u53caC\u2212H\u952e\u7684\u6c27\u5316\u787c\u5316\u7b49\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u65b9\u6cd5\u901a\u5e38\u5b58\u5728\u5b98\u80fd\u56e2\u8010\u53d7\u6027\u3001\u53cd\u5e94\u6761\u4ef6\u82db\u523b\u4ee5\u53ca\u70ef\u70c3\u7684\u533a\u57df\u9009\u62e9\u6027\u7b49\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u7c7b\u7b80\u5355\u3001\u6e29\u548c\u3001\u9ad8\u6548\u7684\u65b9\u6cd5\u5408\u6210\u6709\u673a\u787c\u5316\u5408\u7269\u4e00\u76f4\u662f\u8be5\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u5728\u524d\u671f\u7814\u7a76\u7684\u57fa\u7840\u4e0a\uff0c\u6211\u4eec\u5b9e\u73b0\u4e86\u53ef\u89c1\u5149\u8bf1\u5bfc\u4e0b\u53cc\u6838\u91d1\u50ac\u5316\u5055\u4e8c\u6c2f\u4ee3\u70f7\u70c3\u53c2\u4e0e\u7684\u53d1\u6563\u6027\u81ea\u7531\u57fa\u53bb\u6c2f\u787c\u5316\u53cd\u5e94\uff0c\u5408\u6210\u4e86\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u70f7\u57fa\u787c\u9178\u916f\u3001a-\u6c2f\u4ee3\u787c\u9178\u916f\u548c\u5055\u4e8c\u787c\u9178\u916f\u884d\u751f\u7269\u3002\u8be5\u65b9\u6cd5\u4e5f\u9002\u7528\u4e8e\u590d\u6742\u5929\u7136\u4ea7\u7269\u548c\u836f\u7269\u5206\u5b50\u7684\u540e\u671f\u4fee\u9970\uff0c\u5c55\u73b0\u4e86\u53cc\u6838\u91d1\u50ac\u5316\u4f53\u7cfb\u826f\u597d\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u53cc\u6838\u91d1\u50ac\u5316\u5242\u548c\u6eb6\u5242\u7edc\u5408\u7684B2cat2\u4e4b\u95f4\u7684\u5f31\u914d\u4f4d\u4f5c\u7528\u5728\u60f0\u6027C\u2212Cl\u952e\u6d3b\u5316\u4ee5\u53ca\u540e\u7eed\u53bb\u6c2f\u787c\u5316\u8fc7\u7a0b\u4e2d\u53d1\u6325\u7740\u5173\u952e\u4f5c\u7528\u3002 Q2. \u6709\u5173\u672c\u6b21\u7814\u7a76\u7684\u65f6\u5019\u9047\u5230\u8fc7\u600e\u6837\u7684\u56f0\u96be\u5462\uff1f\u53c8\u662f\u600e\u6837\u514b\u670d\u7684\u5462 \u5728\u8fdb\u884c\u672c\u6b21\u7814\u7a76\u8fc7\u7a0b\u4e2d\uff0c\u6700\u5927\u7684\u6311\u6218\u662f\u5bf9\u5316\u5408\u7269\u7684\u5206\u79bb\u63d0\u7eaf\u5de5\u4f5c\u3002\u7531\u4e8e\u4e00\u4e9b\u8102\u80aa\u5316\u5408\u7269\u8367\u5149\u7279\u6027\u8f83\u5f31\uff0c\u6240\u4ee5\u5f00\u59cb\u65f6\u5728\u5206\u79bb\u63d0\u7eaf\u4e0a\u82b1\u8d39\u4e86\u4e00\u4e9b\u7cbe\u529b\u3002\u4f46\u968f\u7740\u5bf9\u53cd\u5e94\u7684\u7406\u89e3\u4e0d\u65ad\u6df1\u5165\uff0c\u7ecf\u8fc7\u5c1d\u8bd5\u4e0d\u540c\u7684\u63d0\u7eaf\u65b9\u6cd5\uff0c\u5305\u62ec\u663e\u8272\u5242\u7684\u8fd0\u7528\u4ee5\u53ca\u4e0d\u540c\u5206\u79bb\u624b\u6bb5\u6210\u529f\u7684\u89e3\u51b3\u4e86\u8fd9\u4e2a\u95ee\u9898\u3002\u505a\u5b9e\u9a8c\u5c31\u662f\u8fd9\u6837\uff0c\u8981\u575a\u6301\uff0c\u591a\u52a8\u624b\uff0c\u591a\u603b\u7ed3\uff0c\u603b\u80fd\u627e\u5230\u89e3\u51b3\u7684\u529e\u6cd5\u3002 Q3. \u672c\u6b21\u7814\u7a76\u4e3b\u4f53\uff0c\u6709\u6ca1\u6709\u4ec0\u4e48\u8ba9\u60a8\u611f\u89c9\u7279\u522b\u8f9b\u82e6\u548c\u70e7\u8111\u5462\uff1f \u7279\u522b\u8f9b\u82e6\u7684\u95ee\u9898\u662f\u5728\u4e8e\u73b0\u6709\u7684\u53cd\u5e94\u673a\u5236\u7684\u7814\u7a76\u3002\u7531\u4e8e\u53cd\u5e94\u7684\u4e2d\u95f4\u4f53\u6781\u4e0d\u7a33\u5b9a\uff0c\u6211\u4eec\u82b1\u8d39\u4e86\u5927\u91cf\u65f6\u95f4\u4ee5\u53ca\u5c1d\u8bd5\u4e86\u4e0d\u540c\u7684\u65b9\u6cd5\u6765\u5408\u6210\u8be5\u4e2d\u95f4\u4f53\u3002\u6700\u540e\uff0c\u901a\u8fc7\u63a7\u5236\u5b9e\u9a8c\u8fdb\u4e00\u6b65\u9a8c\u8bc1\u6211\u4eec\u7684\u731c\u60f3\u3002 Q4. \u5c06\u6765\u60f3\u7ee7\u7eed\u7814\u7a76\u5316\u5b66\u7684\u54ea\u4e2a\u65b9\u5411\u5462\uff1f \u53ef\u80fd\u8fd8\u662f\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\uff0c\u7ee7\u7eed\u6df1\u5165\u7814\u7a76\u53cc\u6838\u91d1\u5c5e\u5316\u5b66\u7684\u72ec\u7279\u50ac\u5316\u673a\u5236\u4ee5\u53ca\u63a2\u7d22\u5176\u53c2\u4e0e\u65b0\u578b\u53cd\u5e94\u6a21\u5f0f\u3002 Q5. \u6700\u540e\uff0c\u6709\u4ec0\u4e48\u60f3\u5bf9\u5404\u4f4d\u8bfb\u8005\u8bf4\u7684\u5417\uff1f \u80fd\u8bfb\u5230\u8fd9\u4e2a\u6587\u7ae0\u548c\u63a8\u9001\u7684\u57fa\u672c\u90fd\u662f\u540c\u884c\u7684\u8001\u5e08\u548c\u540c\u5b66\uff0c\u7b80\u5355\u5206\u4eab\u4e00\u4e0b\u505a\u8bfe\u9898\u7684\u5fc3\u5f97\u4f53\u4f1a\uff1a\u5728\u79d1\u7814\u7684\u6f2b\u957f\u5f81\u9014\u4e2d\uff0c\u56f0\u96be\u548c\u632b\u6298\u5982\u540c\u9669\u5cfb\u7684\u5c71\u5cf0\uff0c\u65f6\u5e38\u6a2a\u4e98\u5728\u6211\u4eec\u524d\u884c\u7684\u9053\u8def\u4e0a\u3002\u7136\u800c\uff0c\u9762\u5bf9\u8fd9\u4e9b\u6311\u6218\uff0c\u6211\u4eec\u5fc5\u987b\u5b66\u4f1a\u51b7\u9759\u5730\u5ba1\u89c6\u95ee\u9898\uff0c\u4ee5\u5ba2\u89c2\u7684\u6001\u5ea6\u5206\u6790\u6bcf\u4e00\u4e2a\u7ec6\u8282\uff0c\u5bfb\u627e\u7a81\u7834\u7684\u53ef\u80fd\u3002 \u5728\u6b64\u6211\u8981\u7279\u522b\u611f\u8c22\u8c22\u52b2\u8001\u5e08\u5728\u6574\u4e2a\u8bfe\u9898\u7814\u7a76\u4e2d\u63d0\u4f9b\u7684\u6089\u5fc3\u6307\u5bfc\u3002\u8c22\u8001\u5e08\u5bf9\u4e8e\u79d1\u7814\u63a2\u7d22\u4e00\u4e1d\u4e0d\u82df\u7684\u6001\u5ea6\u548c\u6562\u4e8e\u62fc\u640f\u7684\u7cbe\u795e\uff0c\u90fd\u662f\u503c\u5f97\u6211\u4eec\u7ec8\u751f\u5b66\u4e60\u7684\u3002\u4ed6\u5e38\u5e38\u6559\u5bfc\u6211\u4eec\u5b9e\u9a8c\u8fc7\u7a0b\u4e2d\u672c\u6765\u5c31\u662f\u5145\u6ee1\u56f0\u96be\u4e0e\u6311\u6218\u7684\uff0c\u4f46\u662f\u529e\u6cd5\u603b\u6bd4\u56f0\u96be\u591a\u3002\u53ea\u8981\u591a\u601d\u8003\uff0c\u591a\u52aa\u529b\uff0c\u6700\u540e\u90fd\u80fd\u8fce\u5203\u800c\u89e3\u3002\u6b64\u5916\uff0c\u6211\u4e5f\u8981\u611f\u6069\u6c42\u5b66\u8def\u4e0a\u9047\u89c1\u7684\u6bcf\u4e00\u4e2a\u4eba\uff0c\u6211\u7684\u4eba\u751f\u56e0\u4f60\u4eec\u7684\u5b58\u5728\u800c\u66f4\u52a0\u7cbe\u5f69\u3002 \u8c22\u52b2\u8bfe\u9898\u7ec4\u7b80\u4ecb \u8c22\u52b2\u6559\u6388\u4e8e2017\u5e747\u6708\u52a0\u5165\u5357\u4eac\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u548c\u914d\u4f4d\u5316\u5b66\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u5f00\u5c55\u72ec\u7acb\u79d1\u7814\u5de5\u4f5c\u3002\u7814\u7a76\u65b9\u5411\u4e3a\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u3001\u81ea\u7531\u57fa\u5316\u5b66\u4e0e\u6218\u7565\u6709\u673a\u65b0\u6750\u6599\uff0c\u901a\u8fc7\u5206\u5b50\u6784\u7b51\u65b0\u6982\u5ff5\u548c\u65b0\u7b56\u7565\u7684\u53d1\u5c55\u4e0e\u521b\u65b0\uff0c\u8de8\u5b66\u79d1\u89e3\u51b3\u79d1\u5b66\u9886\u57df\u4e2d\u5b58\u5728\u7684\u91cd\u5927\u6311\u6218\u3002\u76ee\u524d\u5df2\u5728Chem. Rev., Chem. Soc. Rev., Acc. Chem. Res., Nat. Chem., Nat. Catal., Nat. Synth., Chem, J. Am. Chem. Soc., Angew. Chem. Int. Ed., Nat. Commun.\u7b49\u56fd\u9645\u8457\u540d\u5b66\u672f\u671f\u520a\u53d1\u8868\u8bba\u658780\u4f59\u7bc7\uff0c\u88ab\u5f155500\u4f59\u6b21\uff1b\u7533\u8bf7\u4e13\u522920\u9879\uff0c\u6388\u6743\u56fd\u9645\u4e13\u52291\u9879\uff0c\u4e2d\u56fd\u4e13\u522912\u9879\u3002\u7814\u7a76\u6210\u679c\u591a\u6b21\u88abNat. Catal., Synform, Synfacts\u7b49\u4eae\u70b9\u4ecb\u7ecd\uff0cAngew. 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