{"id":49894,"date":"2024-05-24T08:01:03","date_gmt":"2024-05-24T00:01:03","guid":{"rendered":"\/\/www.gsbet888.com\/?p=49894"},"modified":"2024-05-26T13:48:20","modified_gmt":"2024-05-26T05:48:20","slug":"%e3%80%8cspotlight-research%e3%80%8dpps%e5%82%ac%e5%8c%96%e9%aa%a8%e6%9e%b6%e9%87%8d%e7%bb%84%e6%9e%84%e5%bb%bas-%e4%b8%ad%e5%bf%83%e6%89%8b%e6%80%a7%e4%ba%9a%e7%a0%9c%e8%83%ba","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2024\/05\/%e3%80%8cspotlight-research%e3%80%8dpps%e5%82%ac%e5%8c%96%e9%aa%a8%e6%9e%b6%e9%87%8d%e7%bb%84%e6%9e%84%e5%bb%bas-%e4%b8%ad%e5%bf%83%e6%89%8b%e6%80%a7%e4%ba%9a%e7%a0%9c%e8%83%ba.html","title":{"rendered":"\u300cSpotlight Research\u300dPPS\u50ac\u5316\u9aa8\u67b6\u91cd\u7ec4\u6784\u5efaS-\u4e2d\u5fc3\u624b\u6027\u4e9a\u781c\u80fa"},"content":{"rendered":"

\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a<\/strong><\/p>\n

\u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u6765\u81ea\u56db\u5ddd\u5927\u5b66\u7684\u535a\u58eb\u751f\u5218\u8d5e\u5a07\u4e3a\u6211\u4eec\u5206\u4eab\u3002<\/p>\n

2024\u5e745\u670822\u65e5\uff0cNat. Commun. <\/em>\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u56db\u5ddd\u5927\u5b66\u738b\u5929\u5229\u6559\u6388<\/strong>\u56e2\u961f\u9898\u4e3a\u300cOrganocatalytic skeletal reorganization for enantioselective synthesis of S<\/em>-stereogenic sulfinamides\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u6587\u4e2d\uff0c\u4ed6\u4eec\u5229\u7528\u624b\u6027\u80bd-\u5b63\u93fb\u76d0\uff08PPS\uff09\u50ac\u5316\u5242\u9996\u6b21\u5b9e\u73b0\u4e86\u201cS(VI)\u4e9a\u781c\u4e9a\u80fa\u5230S(IV)\u4e9a\u781c\u80fa\u201d\u7684\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\uff0c\u4e3a\u786b\u4e2d\u5fc3\u624b\u6027\u4e9a\u781c\u80fa\u5316\u5408\u7269\u7684\u9ad8\u6548\u3001\u7cbe\u51c6\u5408\u6210\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\uff0c\u8be5\u7814\u7a76\u5c06\u52a9\u529b\u4e8e\u542b\u786b\u624b\u6027\u4e2d\u5fc3\u5206\u5b50\u53ca\u5176\u7c7b\u4f3c\u7269\u7684\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u521b\u5236\uff0c\u63a8\u52a8\u76f8\u5173\u836f\u7269\u5206\u5b50\u7684\u8bbe\u8ba1\u4e0e\u5f00\u53d1\u3002<\/p>\n

\"\"<\/p>\n

\n

\u201cOrganocatalytic skeletal reorganization for enantioselective synthesis of S<\/em>-stereogenic sulfinamides. Zanjiao Liu, Siqiang Fang, Haoze Li, Chunxiu Xiao, Kai Xiao, Zhishan Su* & Tianli Wang*<\/p>\n

Nat. Commun. <\/em>2024<\/strong>, <\/em>15, <\/em>4348. <\/em>doi\uff1a10.1038\/s41467-024-48727-x<\/a><\/p>\n<\/blockquote>\n

Q1. <\/strong>\u8bf7\u5bf9\u201c<\/strong>Organocatalytic skeletal reorganization for enantioselective synthesis of S<\/em>-stereogenic sulfinamides<\/strong>\u201d<\/strong>\u4f5c<\/strong>\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002<\/strong><\/h4>\n

\u4e9a\u781c\u80fa\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u542b\u786b\u4e2d\u5fc3\u624b\u6027\u5316\u5408\u7269\uff0c\u8fd9\u7c7b\u5316\u5408\u7269\u5e38\u5e38\u5177\u6709\u72ec\u7279\u7684\u7ed3\u6784\u548c\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u836f\u7269\u521b\u5236\u4e0e\u5f00\u53d1\u3001\u914d\u4f53\u53ca\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u7b49\u9886\u57df\u5907\u53d7\u77a9\u76ee\u3002\u7136\u800c\uff0c\u7531\u4e8e\u7f3a\u4e4f\u7406\u6027\u7684\u5e95\u7269\u8bbe\u8ba1\u3001\u5408\u9002\u7684\u53cd\u5e94\u7c7b\u578b\u3001\u4ee5\u53ca\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u4f53\u7cfb\uff0c\u624b\u6027\u4e9a\u781c\u80fa\u5316\u5408\u7269\u7684\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\u4ecd\u9762\u4e34\u7740\u8270\u5de8\u6311\u6218\u3002\u6211\u4eec\u901a\u8fc7\u5bf9\u6709\u673a\u53cd\u5e94\u8fdb\u884c\u7cbe\u5de7\u7684\u8bbe\u8ba1\uff0c\u91c7\u7528\u7ed3\u6784\u67d4\u6027\u4e14\u9ad8\u5ea6\u53ef\u63a7\u53ef\u8c03\u7684\u624b\u6027\u80bd-\u5b63\u93fb\u76d0\uff08PPS\uff09\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u9996\u6b21\u5b9e\u73b0\u4e86\u524d\u624b\u6027\/\u5916\u6d88\u65cb\u4e9a\u781c\u4e9a\u80fa\u5206\u5b50\u7684\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\u53cd\u5e94\uff0c\u4e3a\u542b\u786b\u624b\u6027\u4e2d\u5fc3\u7684\u4e9a\u781c\u80fa\u5206\u5b50\u7684\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\u5f00\u8f9f\u4e86\u524d\u6240\u672a\u6709\u7684\u9014\u5f84\u3002\u8be5\u53cd\u5e94\u901a\u8fc7\u53bb\u5bf9\u79f0\u5316\u6216\u5e73\u884c\u52a8\u529b\u5b66\u62c6\u5206\u65b9\u5f0f\uff0c\u4ee5\u4f18\u5f02\u7684\u5bf9\u6620\u9009\u62e9\u6027\u6784\u7b51\u4e86\u542b\u6709\u591a\u7c7b\u4e0d\u540c\u53d6\u4ee3\u7684\u624b\u6027\u4e9a\u781c\u80fa\u4ea7\u7269\uff0c\u4e3a\u63a2\u7d22\u548c\u8bbe\u8ba1\u7ed3\u6784\u591a\u6837\u7684\u786b\u7acb\u4f53\u4e2d\u5fc3\u751f\u7269\u6d3b\u6027\u5206\u5b50\u5960\u5b9a\u4e86\u91cd\u8981\u57fa\u7840\u3002\u8be6\u7ec6\u7684\u673a\u7406\u5b9e\u9a8c\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u9610\u660e\u4e86\u8be5\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\u53cd\u5e94\u7ecf\u5386\u4e86\u201c\u5148\u5f00\u73af-\u518d\u5173\u73af\u201d\u7684\u5206\u6b65\u5386\u7a0b\uff0c\u5f00\u73af\u6b65\u9aa4\u662f\u8be5\u53cd\u5e94\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\u7684\u5173\u952e\u6b65\u9aa4\u3002\u8be5\u65b9\u6848\u5c06\u9ad8\u6548\u52a9\u529b\u4e8e\u76f8\u5173\u542b\u786b\u624b\u6027\u5206\u5b50\u53ca\u5176\u7c7b\u4f3c\u7269\u7684\u9ad8\u6548\u7cbe\u51c6\u5408\u6210\u4ee5\u53ca\u836f\u7269\u5206\u5b50\u7684\u8bbe\u8ba1\u5f00\u53d1\u3002<\/p>\n

Q2. <\/strong>\u6709\u5173\u672c\u6b21\u7814\u7a76\u7684\u65f6\u5019\u9047\u5230\u8fc7\u600e\u6837\u7684\u56f0\u96be\u5462\uff1f\u53c8\u662f\u600e\u6837\u514b\u670d\u7684\u5462<\/strong><\/h4>\n

\u5728\u8fdb\u884c\u672c\u6b21\u7814\u7a76\u8fc7\u7a0b\u4e2d\uff0c\u6700\u5927\u7684\u6311\u6218\u662f\u5bf9\u53cd\u5e94\u673a\u7406\u7684\u6df1\u5165\u5256\u6790\u3002\u901a\u8fc7\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\u7684\u7b56\u7565\u5b9e\u73b0\u201cS(VI)\u4e9a\u781c\u4e9a\u80fa\u5230S(IV)\u4e9a\u781c\u80fa\u201d\u7684\u8f6c\u5316\uff0c\u5728\u5148\u524d\u7684\u6587\u732e\u80cc\u666f\u4e2d\u662f\u672a\u88ab\u62a5\u9053\u7684\uff0c\u56e0\u6b64\u5176\u53cd\u5e94\u673a\u7406\u662f\u672a\u77e5\u7684\u3002\u5728\u63a2\u7d22\u53cd\u5e94\u5386\u7a0b\u7684\u8fc7\u7a0b\u4e2d\uff0c\u6211\u4eec\u5728-40\u2103\u7684\u4f4e\u6e29\u4e0b\u53d1\u73b0\u4e86\u5173\u952e\u4e8c\u70ef\u4e2d\u95f4\u4f53\u7684\u5b58\u5728\u3002\u4f46\u5728\u5bf9\u4e2d\u95f4\u4f53\u7684\u5206\u79bb\u4e0e\u8868\u5f81\u65f6\uff0c\u5176\u9ad8\u6d3b\u6027\u3001\u6781\u4e0d\u7a33\u5b9a\u6027\u4ee5\u53ca\u4f4e\u542b\u91cf\u5bfc\u81f4\u6211\u4eec\u5f88\u96be\u83b7\u5f97\u8db3\u591f\u7eaf\u7684\u4e8c\u70ef\u4e2d\u95f4\u4f53\u8fdb\u884c\u8fdb\u4e00\u6b65\u673a\u7406\u7684\u7814\u7a76\u3002\u5c3d\u7ba1\u9762\u4e34\u4e0a\u8ff0\u56f0\u96be\uff0c\u4f46\u6211\u4eec\u6700\u7ec8\u901a\u8fc7-78\u2103\u4e0b\u4f4e\u6e29\u67f1\u5c42\u6790\uff0c\u4ee5\u53ca\u591a\u6b21\u5bcc\u96c6\u7684\u65b9\u5f0f\uff0c\u83b7\u5f97\u4e86\u5173\u952e\u4e2d\u95f4\u4f53\u3002\u6b64\u5916\uff0c\u8be6\u7ec6\u7684\u673a\u7406\u5b9e\u9a8c\u540c\u65f6\u7ed3\u5408DFT\u8ba1\u7b97\u4e5f\u4e3a\u8be5\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\u7684\u53cd\u5e94\u673a\u7406\u63d0\u4f9b\u4e86\u66f4\u52a0\u6df1\u523b\u7684\u8ba4\u8bc6\u3002<\/p>\n

Q3. <\/strong>\u672c\u6b21\u7814\u7a76\u4e3b\u4f53\uff0c\u6709\u6ca1\u6709\u4ec0\u4e48\u8ba9\u60a8\u611f\u89c9\u7279\u522b\u8f9b\u82e6\u548c\u70e7\u8111\u5462\uff1f<\/strong><\/h4>\n

\u672c\u6b21\u7814\u7a76\u4e2d\u7279\u522b\u8f9b\u82e6\u7684\u90e8\u5206\u8981\u5c5e\u5e95\u7269\u5408\u6210\u4e0e\u673a\u7406\u63a2\u7a76\u4e24\u90e8\u5206\u3002\u4e9a\u781c\u4e9a\u80fa\u5e95\u7269\u7684\u4f4e\u4ea7\u7387\u4ee5\u53ca\u4e0d\u7a33\u5b9a\u6027\u3001\u673a\u7406\u90e8\u5206\u5173\u952e\u4e2d\u95f4\u4f53\u7684\u9ad8\u6d3b\u6027\u90fd\u4e3a\u5176\u5206\u79bb\u8868\u5f81\u5e26\u6765\u4e86\u56f0\u96be\u3002\u4f46\u662f\u6211\u4eec\u6700\u7ec8\u90fd\u5f88\u597d\u7684\u89e3\u51b3\u4e86\u4e0a\u8ff0\u96be\u9898\uff0c\u5448\u73b0\u51fa\u4e86\u975e\u5e38\u5b8c\u7f8e\u7684\u5b9e\u9a8c\u7ed3\u679c\u3002<\/p>\n

Q4. <\/strong>\u5c06\u6765\u60f3\u7ee7\u7eed\u7814\u7a76\u5316\u5b66\u7684\u54ea\u4e2a\u65b9\u5411\u5462\uff1f<\/strong><\/h4>\n

\u5e0c\u671b\u7ee7\u7eed\u62d3\u5bbd\u624b\u6027\u80bd-\u5b63\u78f7\u76d0\u50ac\u5316\u4f53\u7cfb\u7684\u50ac\u5316\u8fb9\u754c\uff0c\u63a2\u5bfb\u66f4\u52a0\u65b0\u9896\u7684\u53cd\u5e94\u7c7b\u578b\uff0c\u53d1\u5c55\u66f4\u52a0\u590d\u6742\u7684\u624b\u6027\u9aa8\u67b6\uff0c\u6784\u7b51\u66f4\u52a0\u5b9e\u7528\u7684\u624b\u6027\u5206\u5b50\u3002<\/p>\n

Q5. <\/strong>\u6700\u540e\uff0c\u6709\u4ec0\u4e48\u60f3\u5bf9\u5404\u4f4d\u8bfb\u8005\u8bf4\u7684\u5417\uff1f<\/strong><\/h4>\n

\u9996\u5148\uff0c\u5316\u5b66\u662f\u4e00\u95e8\u9700\u8981\u4e0d\u65ad\u63a2\u7d22\u548c\u53d1\u73b0\u7684\u5b66\u79d1\uff0c\u5b83\u7684\u9b45\u529b\u5c31\u5728\u4e8e\u968f\u7740\u7814\u7a76\u7684\u6df1\u5165\uff0c\u4f60\u603b\u4f1a\u4e0d\u65ad\u53d1\u73b0\u4e00\u4e9b\u65b0\u4e8b\u7269\u3002\u7814\u7a76\u8bfe\u9898\u4ea6\u662f\u5982\u6b64\uff0c\u6211\u4eec\u603b\u4f1a\u5728\u4e00\u6b21\u6b21\u7684\u5b9e\u9a8c\u4e2d\u53d1\u73b0\u65b0\u7684\u95ea\u5149\u70b9\uff0c\u4e0d\u65ad\u63d0\u9ad8\u6587\u7ae0\u6c34\u5e73\u3002\u53e6\u5916\uff0c\u5929\u8d4b\u548c\u52aa\u529b\u540c\u6837\u91cd\u8981\uff0c\u5728\u9762\u5bf9\u5316\u5b66\u7814\u7a76\u4e2d\u7684\u56f0\u96be\u65f6\uff0c\u8981\u6709\u601d\u8003\u6709\u8010\u5fc3\u4e0d\u653e\u5f03\u3002\u6700\u540e\u5e0c\u671b\u6bcf\u4e00\u4e2a\u5316\u5b66\u5de5\u4f5c\u8005\u90fd\u80fd\u62e5\u6709\u5f97\u5929\u72ec\u539a\u7684\u8fd0\u6c14\uff0c\u5728\u5316\u5b66\u7814\u7a76\u7684\u8def\u4e0a\u4e00\u5e06\u98ce\u987a\u3002<\/p>\n

\u5728\u6b64\u6211\u8981\u7279\u522b\u611f\u8c22\u738b\u5929\u5229\u8001\u5e08\u5728\u6574\u4e2a\u8bfe\u9898\u7814\u7a76\u4e2d\u63d0\u4f9b\u7684\u6089\u5fc3\u6307\u5bfc\u3002\u738b\u5929\u5229\u8001\u5e08\u6709\u7740\u4e25\u8c28\u7684\u79d1\u7814\u6001\u5ea6\u3001\u7f1c\u5bc6\u7684\u903b\u8f91\u601d\u7ef4\u3001\u4e30\u5bcc\u7684\u79d1\u5b66\u77e5\u8bc6\u4ee5\u53ca\u8d1f\u8d23\u7684\u5de5\u4f5c\u6001\u5ea6\uff0c\u8ba9\u6211\u5728\u79d1\u7814\u548c\u751f\u6d3b\u4e2d\u90fd\u53d7\u76ca\u532a\u6d45\u3002\u7279\u522b\u611f\u8c22\u738b\u8001\u5e08\u5728\u7814\u7a76\u8fc7\u7a0b\u4e2d\u7684\u8f9b\u82e6\u4ed8\u51fa\uff0c\u5728\u8bfe\u9898\u8ff7\u832b\u65f6\u7ed9\u4e88\u7684\u9f13\u52b1\u3002\u53e6\u5916\uff0c\u7279\u522b\u611f\u8c22\u8bfe\u9898\u7ec4\u540c\u5b66\u4eec\u7ed9\u4e88\u7684\u5e2e\u52a9\uff01<\/p>\n

\u738b\u5929\u5229<\/span>\u8bfe\u9898\u7ec4<\/span>\u7b80\u4ecb<\/span><\/h4>\n

\"\"<\/p>\n

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\u4e3b\u8981\u7814\u7a76\u65b9\u5411\uff1a<\/span>\u6709\u673a\u50ac\u5316\u65b9\u6cd5\u5b66<\/span>\u3001<\/span>\u7eff\u8272\u6709\u673a\u5408\u6210\u5316\u5b66<\/span>\u3001<\/span>\u6709\u673a\u53cd\u5e94\u673a\u7406\u7814\u7a76<\/span>\u3001<\/span>\u751f\u7269\u6d3b\u6027\u5316\u5408\u7269\u5408\u6210\u65b0\u65b9\u6cd5\u7814\u7a76<\/span><\/p>\n

\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1a<\/span>https:\/\/www.chem-wang.com\/<\/span><\/a><\/p>\n

\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d.<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a \u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\u6765\u81ea\u56db\u5ddd\u5927\u5b66\u7684\u535a\u58eb\u751f\u5218\u8d5e\u5a07\u4e3a\u6211\u4eec\u5206\u4eab\u3002 2024\u5e745\u670822\u65e5\uff0cNat. Commun. \u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u56db\u5ddd\u5927\u5b66\u738b\u5929\u5229\u6559\u6388\u56e2\u961f\u9898\u4e3a\u300cOrganocatalytic skeletal reorganization for enantioselective synthesis of S-stereogenic sulfinamides\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u6587\u4e2d\uff0c\u4ed6\u4eec\u5229\u7528\u624b\u6027\u80bd-\u5b63\u93fb\u76d0\uff08PPS\uff09\u50ac\u5316\u5242\u9996\u6b21\u5b9e\u73b0\u4e86\u201cS(VI)\u4e9a\u781c\u4e9a\u80fa\u5230S(IV)\u4e9a\u781c\u80fa\u201d\u7684\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\uff0c\u4e3a\u786b\u4e2d\u5fc3\u624b\u6027\u4e9a\u781c\u80fa\u5316\u5408\u7269\u7684\u9ad8\u6548\u3001\u7cbe\u51c6\u5408\u6210\u63d0\u4f9b\u4e86\u65b0\u7684\u9014\u5f84\uff0c\u8be5\u7814\u7a76\u5c06\u52a9\u529b\u4e8e\u542b\u786b\u624b\u6027\u4e2d\u5fc3\u5206\u5b50\u53ca\u5176\u7c7b\u4f3c\u7269\u7684\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u521b\u5236\uff0c\u63a8\u52a8\u76f8\u5173\u836f\u7269\u5206\u5b50\u7684\u8bbe\u8ba1\u4e0e\u5f00\u53d1\u3002 \u201cOrganocatalytic skeletal reorganization for enantioselective synthesis of S-stereogenic sulfinamides. Zanjiao Liu, Siqiang Fang, Haoze Li, Chunxiu Xiao, Kai Xiao, Zhishan Su* & Tianli Wang* Nat. Commun. 2024, 15, 4348. doi\uff1a10.1038\/s41467-024-48727-x Q1. \u8bf7\u5bf9\u201cOrganocatalytic skeletal reorganization for enantioselective synthesis of S-stereogenic sulfinamides\u201d\u4f5c\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002 \u4e9a\u781c\u80fa\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u542b\u786b\u4e2d\u5fc3\u624b\u6027\u5316\u5408\u7269\uff0c\u8fd9\u7c7b\u5316\u5408\u7269\u5e38\u5e38\u5177\u6709\u72ec\u7279\u7684\u7ed3\u6784\u548c\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u836f\u7269\u521b\u5236\u4e0e\u5f00\u53d1\u3001\u914d\u4f53\u53ca\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u7b49\u9886\u57df\u5907\u53d7\u77a9\u76ee\u3002\u7136\u800c\uff0c\u7531\u4e8e\u7f3a\u4e4f\u7406\u6027\u7684\u5e95\u7269\u8bbe\u8ba1\u3001\u5408\u9002\u7684\u53cd\u5e94\u7c7b\u578b\u3001\u4ee5\u53ca\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\u4f53\u7cfb\uff0c\u624b\u6027\u4e9a\u781c\u80fa\u5316\u5408\u7269\u7684\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\u4ecd\u9762\u4e34\u7740\u8270\u5de8\u6311\u6218\u3002\u6211\u4eec\u901a\u8fc7\u5bf9\u6709\u673a\u53cd\u5e94\u8fdb\u884c\u7cbe\u5de7\u7684\u8bbe\u8ba1\uff0c\u91c7\u7528\u7ed3\u6784\u67d4\u6027\u4e14\u9ad8\u5ea6\u53ef\u63a7\u53ef\u8c03\u7684\u624b\u6027\u80bd-\u5b63\u93fb\u76d0\uff08PPS\uff09\u4f5c\u4e3a\u50ac\u5316\u5242\uff0c\u9996\u6b21\u5b9e\u73b0\u4e86\u524d\u624b\u6027\/\u5916\u6d88\u65cb\u4e9a\u781c\u4e9a\u80fa\u5206\u5b50\u7684\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\u53cd\u5e94\uff0c\u4e3a\u542b\u786b\u624b\u6027\u4e2d\u5fc3\u7684\u4e9a\u781c\u80fa\u5206\u5b50\u7684\u50ac\u5316\u4e0d\u5bf9\u79f0\u5408\u6210\u5f00\u8f9f\u4e86\u524d\u6240\u672a\u6709\u7684\u9014\u5f84\u3002\u8be5\u53cd\u5e94\u901a\u8fc7\u53bb\u5bf9\u79f0\u5316\u6216\u5e73\u884c\u52a8\u529b\u5b66\u62c6\u5206\u65b9\u5f0f\uff0c\u4ee5\u4f18\u5f02\u7684\u5bf9\u6620\u9009\u62e9\u6027\u6784\u7b51\u4e86\u542b\u6709\u591a\u7c7b\u4e0d\u540c\u53d6\u4ee3\u7684\u624b\u6027\u4e9a\u781c\u80fa\u4ea7\u7269\uff0c\u4e3a\u63a2\u7d22\u548c\u8bbe\u8ba1\u7ed3\u6784\u591a\u6837\u7684\u786b\u7acb\u4f53\u4e2d\u5fc3\u751f\u7269\u6d3b\u6027\u5206\u5b50\u5960\u5b9a\u4e86\u91cd\u8981\u57fa\u7840\u3002\u8be6\u7ec6\u7684\u673a\u7406\u5b9e\u9a8c\u7ed3\u5408\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\u8ba1\u7b97\u9610\u660e\u4e86\u8be5\u4e0d\u5bf9\u79f0\u9aa8\u67b6\u91cd\u7ec4\u53cd\u5e94\u7ecf\u5386\u4e86\u201c\u5148\u5f00\u73af-\u518d\u5173\u73af\u201d\u7684\u5206\u6b65\u5386\u7a0b\uff0c\u5f00\u73af\u6b65\u9aa4\u662f\u8be5\u53cd\u5e94\u7acb\u4f53\u9009\u62e9\u6027\u63a7\u5236\u7684\u5173\u952e\u6b65\u9aa4\u3002\u8be5\u65b9\u6848\u5c06\u9ad8\u6548\u52a9\u529b\u4e8e\u76f8\u5173\u542b\u786b\u624b\u6027\u5206\u5b50\u53ca\u5176\u7c7b\u4f3c\u7269\u7684\u9ad8\u6548\u7cbe\u51c6\u5408\u6210\u4ee5\u53ca\u836f\u7269\u5206\u5b50\u7684\u8bbe\u8ba1\u5f00\u53d1\u3002 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