{"id":5009,"date":"2015-05-29T07:20:36","date_gmt":"2015-05-28T23:20:36","guid":{"rendered":"\/\/www.gsbet888.com\/?p=5009"},"modified":"2019-08-02T18:55:31","modified_gmt":"2019-08-02T10:55:31","slug":"%e8%84%b1%e7%be%a7%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94-decarboxylative-coupling-2","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2015\/05\/%e8%84%b1%e7%be%a7%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94-decarboxylative-coupling-2.html","title":{"rendered":"\u8131\u7fa7\u5076\u8054\u53cd\u5e94 Decarboxylative Coupling"},"content":{"rendered":"<h4><strong>\u6982\u8981<\/strong><\/h4>\n<p>\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u662f\u6307\u5229\u7528\u91d1\u5c5e\u50ac\u5316\u5242\u5b9e\u73b0\u7fa7\u9178\u7c7b\u5316\u5408\u7269\u8131\u7fa7\u5e76\u5728\u539f\u6765\u7684\u7fa7\u9178\u4f4d\u70b9\u751f\u6210\u65b0\u7684\u78b3-\u78b3\u952e\u7684\u5316\u5b66\u53cd\u5e94\u3002\u5e7f\u4e49\u4e0a\u6765\u8bf4\uff0c\u4e5f\u53ef\u4ee5\u5c06\u91d1\u5c5e\u50ac\u5316\u7fa7\u9178\u8131\u7fa7\u5e76\u751f\u6210\u78b3\u6742\u539f\u5b50\u5316\u5b66\u952e\uff08\u78b3-\u6c27\uff0c\u78b3-\u786b\uff0c\u78b3-\u6c2e\u952e\u7b49\uff09\u7684\u53cd\u5e94\u5f52\u7c7b\u4e3a\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u3002[1, 2, 3]<sup>\u00a0<\/sup>\u4f20\u7edf\u6709\u673a\u5316\u5b66\u4e2d\u7684\u8131\u7fa7\u53cd\u5e94\u4e3b\u8981\u5229\u7528\u4e86\u6c27\u5316\u7fa7\u9178\u751f\u6210\u81ea\u7531\u57fa\u7684\u8fc7\u7a0b\u3002\u82b3\u57fa\u548c\u70ef\u57fa\uff08Csp<sup>2<\/sup>-COOH\uff09 \u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u4e3b\u8981\u5229\u7528\u91d1\u5c5e\u50ac\u5316\u5b9e\u73b0\u6c27\u5316\u8fd8\u539f\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u8131\u7fa7\uff0c\u5e76\u4e14\u751f\u6210\u91d1\u5c5e\u6709\u673a\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u5b9e\u73b0\u4e0e\u4eb2\u7535\u8bd5\u5242\u6216\u8005\u5728\u6c27\u5316\u6027\u6761\u4ef6\u4e0b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u5076\u8054\u6210\u952e\u3002\u867d\u7136\u4e00\u4e9b\u6d3b\u5316\u7684\u70f7\u57fa\u7fa7\u9178\u53ef\u4ee5\u5728\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u4e0b\u901a\u8fc7\u751f\u6210\u91d1\u5c5e\u6709\u673a\u4e2d\u95f4\u4f53\u7684\u5386\u7a0b\u8fdb\u884c\u975e\u81ea\u7531\u57fa\u8131\u7fa7\u5076\u8054\u3002\u4f46\u662f\uff0c\u9488\u5bf9\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u70f7\u57fa\u7fa7\u9178\uff08Csp<sup>3<\/sup>-COOH\uff09\u7684\u8131\u7fa7\u56f0\u96be\u95ee\u9898\uff0c\u4e00\u4e9b\u70f7\u57fa\u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u4ecd\u7136\u9700\u8981\u901a\u8fc7\u81ea\u7531\u57fa\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u3002\u503c\u5f97\u6307\u51fa\u7684\u662f\uff0c\u6700\u8fd1\uff0cMacMillan\u7b49\u4eba\u6210\u529f\u5c06\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u4e0e\u954d\u50ac\u5316\u5242\u7ed3\u5408\uff0c\u901a\u8fc7\u7ed3\u5408\u5149\u50ac\u5316\u4e0e\u91d1\u5c5e\u6709\u673a\u50ac\u5316\u7684\u6df7\u5408\u624b\u6bb5\uff0c\u5b9e\u73b0\u4e86\u6c28\u57fa\u9178\u548c\u975e\u6d3b\u5316\u70f7\u57fa\u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u3002<span style=\"font-size: small\"><span style=\"line-height: 19px\">[4]<\/span><\/span><\/p>\n<p style=\"text-align: center\"><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/0.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-5157 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/0.jpg\" alt=\"0\" width=\"433\" height=\"146\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/0.jpg 433w, https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/0-300x101.jpg 300w\" sizes=\"(max-width: 433px) 100vw, 433px\" \/><\/a><\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ol>\n<li>\u00a0Shang R, Liu, L. <em>Science China-Chemistry<\/em>, <strong>2011<\/strong>, <em>11<\/em>, 54: 1670\u20131687 DOI: <a href=\"http:\/\/dx.doi.org\/10.1007\/s11426-011-4381-0\">10.1007\/s11426-011-4381-0<\/a><\/li>\n<li>Nilsson M. <em>Acta Chem Scand<\/em>, <strong>1966<\/strong>, 20: 423\u2013426. DOI: <a href=\"http:\/\/dx.doi.org\/10.3891\/acta.chem.scand.20-0423\">10.3891\/acta.chem.scand.20-0423<\/a><\/li>\n<li>Rodr\u00edguez N, Goossen L. <em>Chem Soc Rev<\/em>, <strong>2011<\/strong>, 40:5030\u20135048. DOI: <a href=\"http:\/\/dx.doi.org\/10.1039\/C1CS15093F\">10.1039\/C1CS15093F<\/a><\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<ul>\n<li>\u6839\u636e\u5177\u4f53\u7684\u7fa7\u9178\u5e95\u7269\u4ee5\u53ca\u5076\u8054\u8bd5\u5242\uff0c\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u7684\u673a\u7406\u5b58\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u7684\u5dee\u5f02\uff0c\u4e3b\u8981\u7684\u51e0\u79cd\u673a\u7406\u5305\u62ec\u4e86\u53cc\u91d1\u5c5e\u50ac\u5316\u8131\u7fa7\u5076\u8054\u4f53\u7cfb\uff0c\u5355\u91d1\u5c5e\u50ac\u5316\u7684\u8131\u7fa7\u5076\u8054\u4f53\u7cfb\uff0c\u4ee5\u53ca\u590d\u5408\u50ac\u5316\u4f53\u7cfb\uff08\u5149\u50ac\u5316\u63a5\u529b\u91d1\u5c5e\u50ac\u5316\uff09\u7b49\u3002<\/li>\n<li>\u53cc\u91d1\u5c5e\u50ac\u5316\u4f53\u7cfb<\/li>\n<\/ul>\n<p style=\"text-align: center\"><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/05\/mech1-deco2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-5158 size-full\" 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(a) Zuo, Z.; Ahneman, D.; Chu, L.; Terrett, J.; Doyle, A. G.; MacMillan, D. W. C. <em>Science.<\/em> <strong>2014<\/strong>, <em>345<\/em>, 437. \u00a0<span class=\"cit-sep cit-sep-before-article-doi\">DOI:<\/span><a href=\"http:\/\/dx.doi.org\/10.1126\/science.1255525\">10.1126\/science.1255525<\/a><\/p>\n[5] Goossen, L. J.; Deng, G.; Levy, L. M. <em>Science<\/em>. <strong>2006<\/strong>, <em>313<\/em>, 662.\u00a0<span class=\"cit-sep cit-sep-before-article-doi\">DOI:<\/span><a href=\"http:\/\/dx.doi.org\/10.1126\/science.1128684\">10.1126\/science.1128684<\/a><\/p>\n[6] Myers, A. G.; Tanaka, D.; Mannion, M. R. <em>J. Am. <\/em><em>Chem. Soc.<\/em> <strong>2002<\/strong>, <em>124<\/em>, 11250. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja027523m\">10.1021\/ja027523m<\/a><\/p>\n[7] Shang, R.; Fu, Y.; Li, J.-B.; Zhang, S.-L.; Guo, Q.-X.; Liu, L.; <em>J. Am. <\/em><em>Chem. Soc.<\/em> <strong>2009<\/strong>, <em>131<\/em>, 5738. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja900984x\">10.1021\/ja900984x<\/a><\/p>\n[8] Shang, R.; Fu, Y.; Wang, Y.; Xu, Q.; Yu, H.-Z.; Liu, L. <em>Angew. Chem., Int. Ed.<\/em> <strong>2009<\/strong>, <em>48<\/em>, 9350. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.200904916\">10.1002\/anie.200904916<\/a><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u8131\u7fa7\u5076\u8054\u53cd\u5e94\u662f\u6307\u5229\u7528\u91d1\u5c5e\u50ac\u5316\u5242\u5b9e\u73b0\u7fa7\u9178\u7c7b\u5316\u5408\u7269\u8131\u7fa7\u5e76\u5728\u539f\u6765\u7684\u7fa7\u9178\u4f4d\u70b9\u751f\u6210\u65b0\u7684\u78b3-\u78b3\u952e\u7684\u5316\u5b66\u53cd\u5e94\u3002\u5e7f\u4e49\u4e0a\u6765\u8bf4\uff0c\u4e5f\u53ef\u4ee5\u5c06\u91d1\u5c5e\u50ac\u5316\u7fa7\u9178\u8131\u7fa7\u5e76\u751f\u6210\u78b3\u6742\u539f\u5b50\u5316\u5b66\u952e\uff08\u78b3-\u6c27\uff0c\u78b3-\u786b\uff0c\u78b3-\u6c2e\u952e\u7b49\uff09\u7684\u53cd\u5e94\u5f52\u7c7b\u4e3a\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u3002[1, 2, 3]\u00a0\u4f20\u7edf\u6709\u673a\u5316\u5b66\u4e2d\u7684\u8131\u7fa7\u53cd\u5e94\u4e3b\u8981\u5229\u7528\u4e86\u6c27\u5316\u7fa7\u9178\u751f\u6210\u81ea\u7531\u57fa\u7684\u8fc7\u7a0b\u3002\u82b3\u57fa\u548c\u70ef\u57fa\uff08Csp2-COOH\uff09 \u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u4e3b\u8981\u5229\u7528\u91d1\u5c5e\u50ac\u5316\u5b9e\u73b0\u6c27\u5316\u8fd8\u539f\u4e2d\u6027\u6761\u4ef6\u4e0b\u7684\u8131\u7fa7\uff0c\u5e76\u4e14\u751f\u6210\u91d1\u5c5e\u6709\u673a\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u5b9e\u73b0\u4e0e\u4eb2\u7535\u8bd5\u5242\u6216\u8005\u5728\u6c27\u5316\u6027\u6761\u4ef6\u4e0b\u4e0e\u4eb2\u6838\u8bd5\u5242\u7684\u5076\u8054\u6210\u952e\u3002\u867d\u7136\u4e00\u4e9b\u6d3b\u5316\u7684\u70f7\u57fa\u7fa7\u9178\u53ef\u4ee5\u5728\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u4e0b\u901a\u8fc7\u751f\u6210\u91d1\u5c5e\u6709\u673a\u4e2d\u95f4\u4f53\u7684\u5386\u7a0b\u8fdb\u884c\u975e\u81ea\u7531\u57fa\u8131\u7fa7\u5076\u8054\u3002\u4f46\u662f\uff0c\u9488\u5bf9\u91d1\u5c5e\u50ac\u5316\u5242\u50ac\u5316\u70f7\u57fa\u7fa7\u9178\uff08Csp3-COOH\uff09\u7684\u8131\u7fa7\u56f0\u96be\u95ee\u9898\uff0c\u4e00\u4e9b\u70f7\u57fa\u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u4ecd\u7136\u9700\u8981\u901a\u8fc7\u81ea\u7531\u57fa\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u3002\u503c\u5f97\u6307\u51fa\u7684\u662f\uff0c\u6700\u8fd1\uff0cMacMillan\u7b49\u4eba\u6210\u529f\u5c06\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316\u5242\u4e0e\u954d\u50ac\u5316\u5242\u7ed3\u5408\uff0c\u901a\u8fc7\u7ed3\u5408\u5149\u50ac\u5316\u4e0e\u91d1\u5c5e\u6709\u673a\u50ac\u5316\u7684\u6df7\u5408\u624b\u6bb5\uff0c\u5b9e\u73b0\u4e86\u6c28\u57fa\u9178\u548c\u975e\u6d3b\u5316\u70f7\u57fa\u7fa7\u9178\u7684\u8131\u7fa7\u5076\u8054\u3002[4] \u57fa\u672c\u6587\u732e \u00a0Shang R, Liu, L. Science China-Chemistry, 2011, 11, 54: 1670\u20131687 DOI: 10.1007\/s11426-011-4381-0 Nilsson M. Acta Chem Scand, 1966, 20: 423\u2013426. DOI: 10.3891\/acta.chem.scand.20-0423 Rodr\u00edguez N, Goossen L. Chem Soc Rev, 2011, 40:5030\u20135048. DOI: 10.1039\/C1CS15093F &nbsp; \u53cd\u5e94\u673a\u7406 \u6839\u636e\u5177\u4f53\u7684\u7fa7\u9178\u5e95\u7269\u4ee5\u53ca\u5076\u8054\u8bd5\u5242\uff0c\u8131\u7fa7\u5076\u8054\u53cd\u5e94\u7684\u673a\u7406\u5b58\u5728\u4e00\u5b9a\u7a0b\u5ea6\u4e0a\u7684\u5dee\u5f02\uff0c\u4e3b\u8981\u7684\u51e0\u79cd\u673a\u7406\u5305\u62ec\u4e86\u53cc\u91d1\u5c5e\u50ac\u5316\u8131\u7fa7\u5076\u8054\u4f53\u7cfb\uff0c\u5355\u91d1\u5c5e\u50ac\u5316\u7684\u8131\u7fa7\u5076\u8054\u4f53\u7cfb\uff0c\u4ee5\u53ca\u590d\u5408\u50ac\u5316\u4f53\u7cfb\uff08\u5149\u50ac\u5316\u63a5\u529b\u91d1\u5c5e\u50ac\u5316\uff09\u7b49\u3002 \u53cc\u91d1\u5c5e\u50ac\u5316\u4f53\u7cfb \u5355\u91d1\u5c5e\u50ac\u5316\u4f53\u7cfb \u53cd\u5e94\u5b9e\u4f8b \u94dc\u94af\u53cc\u91d1\u5c5e\u50ac\u5316\u7684\u8131\u7fa7\u5076\u8054[5] \u94f6\u94af\u50ac\u5316\u7684\u8131\u7fa7\u5076\u8054[6] \u94af\u50ac\u5316\u7684\u8131\u7fa7\u5076\u8054[7] \u94dc\u50ac\u5316\u7684\u8131\u7fa7\u5076\u8054[8] \u5b9e\u9a8c\u6b65\u9aa4 \u4ee5\u53cd\u5e94\u5b9e\u4f8b\u4e09\u4e3a\u4f8b\u3002\u5c06\u7fa7\u9178\u76d0\u3001\u94af\u50ac\u5316\u5242\u548c\u914d\u4f53\u7f6e\u4e8eSchlenk\u53cd\u5e94\u7ba1\u4e2d\uff0c\u5c06\u53cd\u5e94\u6df7\u5408\u7269\u62bd\u771f\u7a7a\u5e76\u5145\u5165\u6c29\u6c14\uff08\u53cd\u590d\u4e09\u6b21\uff09\u3002\u5c06\u6eb4\u82ef\u548c\u6c2e\u7532\u57fa\u5421\u54af\u70f7\u916e\u6eb6\u5242\u901a\u8fc7\u6ce8\u5c04\u5668\u52a0\u5165\u53cd\u5e94\u7ba1\u4e2d\u3002\u5c06\u53cd\u5e94\u7ba1\u4e0e\u5145\u6ee1\u6c29\u6c14\u7684\u771f\u7a7a\u7ebf\u76f8\u63a5\uff0c\u5e76\u81f3\u4e8e150\u6444\u6c0f\u5ea6\u7684\u6cb9\u6d74\u4e2d\u52a0\u70ed\u3002\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u52a0\u5165\u6c34\u6dec\u706d\u53cd\u5e94\uff0c\u5e76\u7528\u4e59\u9178\u4e59\u916f\u8403\u53d6\uff0c\u5c06\u8403\u53d6\u6db2\u51cf\u538b\u84b8\u53d1\u9664\u53bb\u6eb6\u5242\uff0c\u901a\u8fc7\u67f1\u5c42\u6790\u5206\u79bb\u5f97\u5230\u4ea7\u7269\u3002 &nbsp; \u5b9e\u9a8c\u6280\u5de7 \u6ce8\u610f\u7fa7\u9178\u76d0\u53ef\u80fd\u4f1a\u5438\u6f6e\uff0c\u4f7f\u7528\u5e72\u71e5\u540e\u7684\u7fa7\u9178\u76d0\u6709\u65f6\u5019\u4f1a\u6709\u52a9\u4e8e\u53cd\u5e94\u7684\u8fdb\u884c\u3002 \u4e00\u4e9b\u60c5\u51b5\u4e0b\u7fa7\u9178\u76d0\u5728\u53cd\u5e94\u4f53\u7cfb\u4e2d\u5e76\u4e0d\u6eb6\u89e3\uff0c\u9700\u8981\u5747\u5300\u7684\u6405\u62cc\u4f7f\u5f97\u53cd\u5e94\u80fd\u591f\u5145\u5206\u7684\u8fdb\u884c\u3002 &nbsp; \u53c2\u8003\u6587\u732e [4] (a) Zuo, Z.; Ahneman, D.; Chu, L.; Terrett, J.; Doyle, A. G.; MacMillan, D. W. C. Science. 2014, 345, 437. \u00a0DOI:10.1126\/science.1255525 [5] Goossen, L. J.; Deng, G.; Levy, L. M. Science. 2006, 313, 662.\u00a0DOI:10.1126\/science.1128684 [6] Myers, A. G.; Tanaka, D.; Mannion, M. R. J. Am. Chem. Soc. 2002, 124, 11250. 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