{"id":50179,"date":"2024-07-15T08:00:41","date_gmt":"2024-07-15T00:00:41","guid":{"rendered":"\/\/www.gsbet888.com\/?p=50179"},"modified":"2024-07-15T23:40:27","modified_gmt":"2024-07-15T15:40:27","slug":"%e3%80%8cspotlight-research%e3%80%8dhfip%e8%be%85%e5%8a%a9%e5%8d%95%e7%94%b5%e5%ad%90%e8%bd%ac%e7%a7%bb%e9%80%89%e6%8b%a9%e6%80%a7%e6%9e%84%e5%bb%ba%e6%9d%82%e7%8e%af","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2024\/07\/%e3%80%8cspotlight-research%e3%80%8dhfip%e8%be%85%e5%8a%a9%e5%8d%95%e7%94%b5%e5%ad%90%e8%bd%ac%e7%a7%bb%e9%80%89%e6%8b%a9%e6%80%a7%e6%9e%84%e5%bb%ba%e6%9d%82%e7%8e%af.html","title":{"rendered":"\u300cSpotlight Research\u300dHFIP\u8f85\u52a9\u5355\u7535\u5b50\u8f6c\u79fb\u9009\u62e9\u6027\u6784\u5efa\u6742\u73af"},"content":{"rendered":"

\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a<\/p>\n

\u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u6765\u81ea\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240\u7684\u535a\u58eb\u751f\u8c22\u4f73\u4e50\u4e3a\u6211\u4eec\u5206\u4eab\u3002<\/p>\n

2024\u5e747\u67081\u65e5\uff0cNature Synthesis<\/em>\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240Feliu Maseras & M\u00f3nica H. P\u00e9rez-Temprano\u6559\u6388\u6388\u56e2\u961f\u9898\u4e3a\u300cHexafluoroisopropanol-assisted selective intramolecular synthesis of heterocycles by single-electron transfer\u300d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5728\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u201c\u65e7\u8bd5\u5242\uff0c\u65b0\u6280\u5de7\u201d\u7684\u7b56\u7565\u3002\u901a\u8fc7\u7ed3\u5408\u53cc\uff08\u4e09\u6c1f\u4e59\u6c27\u57fa\uff09\u7898\u82ef\uff08PIFA\uff09\u548c\u516d\u6c1f\u5f02\u4e19\u9187\uff08HFIP\uff09\uff0c\u5c06\u4f20\u7edf\u7684HLF\u53cd\u5e94\u673a\u5236\u8f6c\u53d8\u4e3a\u5355\u7535\u5b50\u8f6c\u79fb\uff08SET\uff09\u673a\u5236\uff0c\u751f\u6210\u81ea\u7531\u57fa\u9633\u79bb\u5b50\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u9ad8\u6548\u5730\u5b9e\u73b0\u4e86\u5206\u5b50\u5185C(sp<\/em>3<\/sup>)\u2013H\u76845\/6\u5143\u73af\u5316\u53cd\u5e94\u3002\u8fd9\u4e00\u8fdb\u5c55\u4e0d\u4ec5\u514b\u670d\u4e86\u4f20\u7edfHLF\u53cd\u5e94\u5728\u6784\u5efa\u516d\u5143\u73af\u548c\u542b\u6c27\u6742\u73af\u65f6\u7684\u5c40\u9650\u6027\uff0c\u4e5f\u4e3a\u836f\u7269\u5206\u5b50\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\u3002<\/p>\n

\u00a0\<\/p>\n

\n

\u201cHexafluoroisopropanol-assisted selective intramolecular synthesis of heterocycles by single-electron transfer<\/p>\n

Jiale Xie, Jiayu Zhang, Sitthichok Kasemthaveechok, Sara L\u00f3pez-Resano, Eric Cots, Feliu Maseras *& M\u00f3nica H. P\u00e9rez-Temprano*<\/p>\n

Nat. Synth.<\/em>2024, <\/strong>ASAP, doi:https:\/\/www.nature.com\/articles\/s44160-024-00566-w<\/a>\u201d<\/p>\n<\/blockquote>\n

Q1. <\/strong>\u8bf7\u5bf9\u201c<\/strong>Hexafluoroisopropanol-assisted selective intramolecular synthesis of heterocycles by single-electron transfer\u201d<\/strong>\u4f5c<\/strong>\u4e00\u4e2a\u7b80\u5355\u4ecb\u7ecd\u3002<\/strong><\/h4>\n

\u9971\u548c\u6742\u73af\u662f\u836f\u7269\u5316\u5b66\u4e2d\u5e38\u89c1\u4e14\u91cd\u8981\u7684\u5206\u5b50\u7247\u6bb5\u3002\u4f20\u7edf\u7684Hofmann\u2013L\u00f6ffler\u2013Freytag\uff08HLF\uff09\u53cd\u5e94\u901a\u8fc7\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u81ea\u7531\u57fa\u673a\u5236\uff0c\u5b9e\u73b0\u4e86\u6742\u73af\u5316\u5408\u7269\u7684\u5408\u6210\u3002\u5728\u8fc7\u53bb\u51e0\u5341\u5e74\u4e2d\uff0c\u91c7\u7528\u9ad8\u4ef7\u7898\u8bd5\u5242\u7684\u5408\u6210\u65b9\u6cd5\u663e\u8457\u63d0\u5347\u4e86\u8fd9\u4e00\u53cd\u5e94\u7684\u5b9e\u7528\u6027\u548c\u53ef\u6301\u7eed\u6027\u3002\u7136\u800c\uff0c\u8fd9\u7c7b\u65b9\u6cd5\u5728\u4e94\u5143\u542b\u6c2e\u6742\u73af\u7684\u5408\u6210\u65b9\u9762\u8868\u73b0\u51fa\u8272\uff0c\u4f46\u5728\u6784\u5efa\u516d\u5143\u73af\u6216\u542b\u6c27\u6742\u73af\u65f6\u9762\u4e34\u91cd\u5927\u6311\u6218\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u6211\u4eec\u63d0\u51fa\u4e86\u201c\u65e7\u8bd5\u5242\uff0c\u65b0\u6280\u5de7\u201d\u7684\u7b56\u7565\u3002\u901a\u8fc7\u7ed3\u5408\u53cc\uff08\u4e09\u6c1f\u4e59\u6c27\u57fa\uff09\u7898\u82ef\uff08PIFA\uff09\u548c\u516d\u6c1f\u5f02\u4e19\u9187\uff08HFIP\uff09\uff0c\u5c06\u4f20\u7edf\u7684HLF\u53cd\u5e94\u673a\u5236\u8f6c\u53d8\u4e3a\u5355\u7535\u5b50\u8f6c\u79fb\uff08SET\uff09\u673a\u5236\uff0c\u751f\u6210\u81ea\u7531\u57fa\u9633\u79bb\u5b50\u4e2d\u95f4\u4f53\uff0c\u4ece\u800c\u9ad8\u6548\u5730\u5b9e\u73b0\u4e86\u5206\u5b50\u5185C(sp<\/em>3<\/sup>)\u2013H\u76845\/6\u5143\u73af\u5316\u53cd\u5e94\u3002\u8fd9\u4e00\u8fdb\u5c55\u4e0d\u4ec5\u514b\u670d\u4e86\u4f20\u7edfHLF\u53cd\u5e94\u5728\u6784\u5efa\u516d\u5143\u73af\u548c\u542b\u6c27\u6742\u73af\u65f6\u7684\u5c40\u9650\u6027\uff0c\u4e5f\u4e3a\u836f\u7269\u5206\u5b50\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u5f00\u8f9f\u4e86\u65b0\u7684\u9014\u5f84\u3002\u901a\u8fc7\u8be6\u7ec6\u7684\u673a\u7406\u5b9e\u9a8c\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\uff0c\u57fa\u4e8e\u5e95\u7269\u7684\u7535\u5b50\u4e91\u5bc6\u5ea6\uff0c\u6211\u4eec\u63d0\u51fa\u4e86\u4e24\u79cd\u4e0d\u540c\u7684\u81ea\u7531\u57fa\u9633\u79bb\u5b50\u751f\u6210\u8def\u5f84\u3002\u5bf9\u4e8e\u5bcc\u7535\u5b50\u5e95\u7269\uff0c\u5176\u4e0ePIFA\u5f62\u6210\u7535\u8377\u8f6c\u79fb\uff08CT\uff09\u590d\u5408\u7269\uff0c\u968f\u540e\u7ecf\u5386SET\u8fc7\u7a0b\uff1b\u800c\u5bf9\u4e8e\u7f3a\u4e4f\u4f9b\u7535\u5b50\u53d6\u4ee3\u57fa\u7684\u5e95\u7269\uff0c\u5219\u9700\u8981\u5728\u84dd\u5149\u6fc0\u6d3b\u4e0b\u4f7fPIFA\u8f6c\u53d8\u4e3a\u66f4\u5f3a\u7684\u6c27\u5316\u5242\u624d\u53ef\u5b9e\u73b0SET\u8fc7\u7a0b\u3002\u6b64\u5916\uff0c\u7814\u7a76\u63ed\u793aHFIP\u5bf9\u8be5\u53cd\u5e94\u6709\u7740\u591a\u91cd\u4fc3\u8fdb\u4f5c\u7528\u3002<\/p>\n

Q2. <\/strong>\u6709\u5173\u672c\u6b21\u7814\u7a76\u7684\u65f6\u5019\u9047\u5230\u8fc7\u600e\u6837\u7684\u56f0\u96be\u5462\uff1f\u53c8\u662f\u600e\u6837\u514b\u670d\u7684\u5462<\/strong><\/h4>\n

\u7531\u4e8e\u8bfe\u9898\u7ec4\u7f3a\u4e4f\u5149\u53cd\u5e94\u7684\u80cc\u666f\u548c\u7ecf\u9a8c\uff0c\u6211\u4eec\u5728\u7406\u89e3\u5149\u53cd\u5e94\u7684\u57fa\u672c\u539f\u7406\u548c\u4f18\u5316\u5b9e\u9a8c\u6761\u4ef6\u65b9\u9762\u9047\u5230\u4e86\u6311\u6218\u3002\u6b64\u5916\uff0c\u627e\u5230\u9002\u5408\u7684\u53cd\u5e94\u88c5\u7f6e\u4e5f\u662f\u4e00\u4e2a\u96be\u70b9\u3002\u4e3a\u4e86\u5e94\u5bf9\u8fd9\u4e9b\u56f0\u96be\uff0c\u6211\u4eec\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7684\u6587\u732e\u8c03\u7814\uff0c\u6df1\u5165\u4e86\u89e3\u5149\u53cd\u5e94\u7684\u57fa\u672c\u7406\u8bba\u548c\u524d\u4eba\u7684\u7814\u7a76\u6210\u679c\u3002\u540c\u65f6\uff0c\u6211\u4eec\u79ef\u6781\u4e0e\u5176\u4ed6\u8bfe\u9898\u7ec4\u8fdb\u884c\u8ba8\u8bba\u548c\u5b66\u4e60\uff0c\u4ece\u4e2d\u83b7\u5f97\u4e86\u5b9d\u8d35\u7684\u5efa\u8bae\u548c\u6307\u5bfc\u3002\u5c24\u5176\u8981\u611f\u8c22\u672c\u7814\u7a76\u4e2d\u7684\u5408\u4f5c\u4f19\u4f34\u5f20\u4f73\u745c\u535a\u58eb\uff0c\u5979\u5728\u6574\u4e2a\u7814\u7a76\u8fc7\u7a0b\u4e2d\u63d0\u4f9b\u4e86\u91cd\u8981\u7684\u5e2e\u52a9\u548c\u652f\u6301\uff0c\u6211\u4eec\u5171\u540c\u514b\u670d\u4e86\u5b9e\u9a8c\u548c\u7406\u8bba\u4e0a\u7684\u5404\u79cd\u96be\u9898\u3002<\/p>\n

Q3. <\/strong>\u672c\u6b21\u7814\u7a76\u4e3b\u4f53\uff0c\u6709\u6ca1\u6709\u4ec0\u4e48\u8ba9\u60a8\u611f\u89c9\u7279\u522b\u8f9b\u82e6\u548c\u70e7\u8111\u5462\uff1f<\/strong><\/h4>\n

\u5728\u672c\u6b21\u7814\u7a76\u4e2d\uff0c\u6700\u5177\u6311\u6218\u7684\u662f\u7406\u89e3\u548c\u63ed\u793a\u53cd\u5e94\u7684\u8be6\u7ec6\u673a\u7406\u3002\u5c3d\u7ba1\u6211\u4eec\u6210\u529f\u5730\u5e94\u7528\u5355\u7535\u5b50\u8f6c\u79fb\u673a\u5236\u5b9e\u73b0\u4e86\u5206\u5b50\u5185C(sp<\/em>3<\/sup>)\u2013H\u76845\/6\u5143\u73af\u5316\u53cd\u5e94\uff0c\u4f46\u662f\u5982\u4f55\u7406\u89e3\u5355\u7535\u5b50\u8f6c\u79fb\u7684\u8fc7\u7a0b\uff0c\u5e76\u4e14\u89e3\u91caHFIP\u5728\u8be5\u53cd\u5e94\u4e2d\u7684\u72ec\u7279\u4f5c\u7528\uff0c\u5e76\u4e0d\u7b80\u5355\u3002\u5e78\u8fd0\u7684\u662f\u7ed3\u5408\u4e00\u7cfb\u5217\u673a\u7406\u5b9e\u9a8c\u548cDFT\u8ba1\u7b97\uff0c\u6700\u7ec8\u63d0\u51fa\u4e86\u8f83\u4e3a\u8be6\u7ec6\u7684\u53cd\u5e94\u673a\u7406\uff0c\u4ee5\u53ca\u8bf4\u660e\u4e86HFIP\u5728\u8be5\u53cd\u5e94\u4e2d\u7684\u591a\u91cd\u89d2\u8272\u3002<\/p>\n

Q4. <\/strong>\u5c06\u6765\u60f3\u7ee7\u7eed\u7814\u7a76\u5316\u5b66\u7684\u54ea\u4e2a\u65b9\u5411\u5462\uff1f<\/strong><\/h4>\n

\u5e94\u8be5\u4f1a\u7740\u624b\u8ba1\u7b97\u5316\u5b66\u8f85\u52a9\u6709\u673a\u53cd\u5e94\u7684\u8bbe\u8ba1\u3001\u4f18\u5316\u3001\u7406\u8bba\u7b49\u7814\u7a76\u3002<\/p>\n

Q5. <\/strong>\u6700\u540e\uff0c\u6709\u4ec0\u4e48\u60f3\u5bf9\u5404\u4f4d\u8bfb\u8005\u8bf4\u7684\u5417\uff1f<\/strong><\/h4>\n

\u79d1\u7814\u8fc7\u7a0b\u5c31\u50cf\u6253\u602a\u5347\u7ea7\uff0c\u5145\u6ee1\u4e86\u6311\u6218\u548c\u672a\u77e5\u3002\u6bcf\u4e00\u6b21\u5b9e\u9a8c\u548c\u7814\u7a76\u90fd\u662f\u4e0d\u65ad\u63a2\u7d22\u548c\u5b66\u4e60\u7684\u8fc7\u7a0b\uff0c\u867d\u7136\u4f1a\u9047\u5230\u5404\u79cd\u56f0\u96be\uff0c\u4f46\u6bcf\u514b\u670d\u4e00\u4e2a\u96be\u5173\uff0c\u90fd\u4f1a\u5e26\u6765\u6210\u5c31\u611f\u548c\u65b0\u7684\u77e5\u8bc6\u3002\u4ee5\u559c\u4e50\u7684\u5fc3\u9762\u5bf9\u73af\u5883\uff0c\u4ee5\u5e73\u5b89\u7684\u5fc3\u5e94\u5bf9\u5904\u5883\uff0c\u4ee5\u76fc\u671b\u7684\u5fc3\u9762\u5bf9\u5931\u671b\uff0c\u4ee5\u79ef\u6781\u7684\u5fc3\u6218\u80dc\u6cae\u4e27\u3002\u795d\u5927\u5bb6\u5728\u79d1\u7814\u9053\u8def\u4e0a\u4e0d\u65ad\u7a81\u7834\uff0c\u53d6\u5f97\u66f4\u52a0\u4e30\u7855\u7684\u6210\u679c\u3002<\/p>\n

\<\/p>\n

\u6559\u80b2\u80cc\u666f\uff1a<\/strong><\/p>\n

2018\u20132021 \u676d\u5dde\u5e08\u8303\u5927\u5b66\uff0c\u7406\u5b66\u7855\u58eb\uff0c\u5bfc\u5e08\uff1a\u5f90\u5229\u6587\u6559\u6388<\/p>\n

2021\u2013\u81f3\u4eca \u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240\uff08ICIQ\uff09\uff0c\u535a\u58eb\u5728\u8bfb\uff0c\u5bfc\u5e08\uff1aProf. Monica H. P\u00e9rez-Temprano & Prof. Feliu Maseras<\/p>\n

\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d.<\/p>\n","protected":false},"excerpt":{"rendered":"\u4f5c\u8005\uff1a\u77f3\u6cb9\u919a \u672c\u671f\u70ed\u70b9\u7814\u7a76\uff0c\u6211\u4eec\u9080\u8bf7\u5230\u4e86\u672c\u6587\u7b2c\u4e00\u4f5c\u8005\uff0c\u6765\u81ea\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240\u7684\u535a\u58eb\u751f\u8c22\u4f73\u4e50\u4e3a\u6211\u4eec\u5206\u4eab\u3002 2024\u5e747\u67081\u65e5\uff0cNature Synthesis\u5728\u7ebf\u53d1\u8868\u4e86\u6765\u81ea\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240Feliu Maseras & M\u00f3nica H. 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