{"id":50490,"date":"2024-08-12T08:25:31","date_gmt":"2024-08-12T00:25:31","guid":{"rendered":"\/\/www.gsbet888.com\/?p=50490"},"modified":"2024-09-02T09:31:52","modified_gmt":"2024-09-02T01:31:52","slug":"green-chem-%ef%bc%9a%e5%85%89%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e5%82%ac%e5%8c%96sulfonylthiazoles%e7%9a%84%e8%83%ba%e7%94%b2%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/recentpaper\/2024\/08\/green-chem-%ef%bc%9a%e5%85%89%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f%e5%82%ac%e5%8c%96sulfonylthiazoles%e7%9a%84%e8%83%ba%e7%94%b2%e5%9f%ba%e5%8c%96%e5%8f%8d%e5%ba%94.html","title":{"rendered":"Green Chem.\uff1a\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316Sulfonylthiazoles\u7684\u80fa\u7532\u57fa\u5316\u53cd\u5e94"},"content":{"rendered":"

\u4f5c\u8005\uff1a\u6749\u6749<\/p>\n

\u5bfc\u8bfb\uff1a<\/h4>\n

\u8fd1\u671f\uff0c\u4e91\u5357\u6c11\u65cf\u5927\u5b66\u7684\u6a0a\u4fdd\u654f\u7b49\u4eba\u5728Green Chem.<\/em>\u4e2d\u53d1\u8868\u8bba\u6587\uff0c\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316sulfonylthiazoles\u4e0e\u4e09\u7ea7\u80fa\u884d\u751f\u7269\u7684\u80fa\u7532\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u70f7\u57fa\u5316\u567b\u5511\u5206\u5b50\u7684\u6784\u5efa\u3002<\/p>\n

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Photoredox Catalytic Aminomethylation of Sulfonylthiazoles<\/p>\n

L. Meng, J. Dong, Y. Tang, H. Yang, L. Sun, J. Chen, B. Fan, Green Chem.<\/em> 2024<\/strong>, ASAP. doi: 10.1039\/D4GC00718B<\/a>.<\/u><\/p>\n<\/blockquote>\n

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\u6b63\u6587\uff1a<\/h4>\n

\u567b\u5511\u9aa8\u67b6\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5404\u7c7b\u836f\u7269\u5206\u5b50\u3001\u5929\u7136\u4ea7\u7269\u4ee5\u53ca\u751f\u7269\u6d3b\u6027\u5206\u5b50\u4e2d (Figure 1a)\u3002\u8fd1\u5e74\u6765\uff0c\u8bf8\u591a\u7814\u7a76\u56e2\u961f\u5df2\u7ecf\u6210\u529f\u8bbe\u8ba1\u51fa\u591a\u79cd\u5149\u5316\u5b66\u50ac\u5316\u8102\u80aa\u65cfC-H\u952e\u7684\u6742\u82b3\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66(Figure 1b) [1]<\/sup>\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u6c28\u57fa\u7532\u57fa\u567b\u5511\u7684\u5408\u6210\u5e38\u5b58\u5728\u53cd\u5e94\u6761\u4ef6\u82db\u523b\u3001\u5e95\u7269\u8303\u56f4\u6709\u9650\u4ee5\u53ca\u4f7f\u7528\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7b49\u5f0a\u7aef\u3002\u8fd9\u91cc\uff0c\u4e91\u5357\u6c11\u65cf\u5927\u5b66\u7684\u6a0a\u4fdd\u654f\u7b49\u4eba\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316sulfonylthiazoles\u4e0e\u4e09\u7ea7\u80fa\u884d\u751f\u7269\u7684\u80fa\u7532\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u70f7\u57fa\u5316\u567b\u5511\u5206\u5b50\u7684\u6784\u5efa (Figure 1c)\u3002<\/p>\n

\"\"<\/p>\n

\u9996\u5148\uff0c\u4f5c\u8005\u91c7\u75282-methylsulfonylbenzothiazole 1a<\/strong>\u4e0eN<\/em>,N<\/em>-\u4e8c\u7532\u57fa\u82ef\u80fa2a<\/strong>\u4f5c\u4e3a\u6a21\u578b\u5e95\u7269\uff0c\u8fdb\u884c\u76f8\u5173\u53cd\u5e94\u6761\u4ef6\u7684\u4f18\u5316\u7b5b\u9009 (Table 1)\u3002\u8fdb\u800c\u786e\u5b9a\u6700\u4f73\u7684\u53cd\u5e94\u6761\u4ef6\u4e3a\uff1a\u91c7\u75284CzIPN\u4f5c\u4e3a\u5149\u50ac\u5316\u5242\uff0cK2<\/sub>CO3<\/sub>\u4f5c\u4e3a\u78b1\uff0c30 W blue LED (450 nm)\u4f5c\u4e3a\u5149\u6e90\uff0c\u5728MeCN\u53cd\u5e94\u6eb6\u5242\u4e2d\uff0c\u53cd\u5e94\u6e29\u5ea6\u4e3a\u5ba4\u6e29\uff0c\u6700\u7ec8\u83b7\u5f9785%\u6536\u7387\u7684\u4ea7\u72693aa<\/strong>\u3002<\/p>\n

\"\"<\/p>\n

\u5728\u4e0a\u8ff0\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0c\u4f5c\u8005\u5206\u522b\u5bf9\u4e00\u7cfb\u5217\u4e09\u7ea7\u80fa\u5e95\u7269 (Scheme 1)\u4ee5\u53casulfonylthiazoles\u5e95\u7269 (Scheme 2)\u7684\u5e94\u7528\u8303\u56f4\u8fdb\u884c\u6df1\u5165\u7814\u7a76\u3002<\/p>\n

\"\"<\/p>\n

\"\"<\/p>\n

\"\"\"\"<\/p>\n

\u4e4b\u540e\uff0c\u8be5\u5c0f\u7ec4\u901a\u8fc7\u5982\u4e0b\u7684\u4e00\u7cfb\u5217\u7814\u7a76\u8fdb\u4e00\u6b65\u8868\u660e\uff0c\u8fd9\u4e00\u5168\u65b0\u7684\u80fa\u7532\u57fa\u5316\u7b56\u7565\u5177\u6709\u6f5c\u5728\u7684\u5408\u6210\u5e94\u7528\u4ef7\u503c (Scheme 3)\u3002<\/p>\n

\"\"<\/p>\n

\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u5bf9\u4e0a\u8ff0\u80fa\u7532\u57fa\u5316\u8fc7\u7a0b\u7684\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u8fdb\u4e00\u6b65\u7814\u7a76 \u00a0(Scheme 4)\u3002<\/p>\n

\"\"\"\"<\/p>\n

\u57fa\u4e8e\u4e0a\u8ff0\u7684\u5b9e\u9a8c\u7814\u7a76\u4ee5\u53ca\u524d\u671f\u76f8\u5173\u7684\u6587\u732e\u62a5\u9053[2]<\/sup>\uff0c\u4f5c\u8005\u63d0\u51fa\u5982\u4e0b\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406 (Scheme 5)\u3002<\/p>\n

\u00a0\"\"<\/p>\n

\u603b\u7ed3\uff1a<\/h4>\n

\u4e91\u5357\u6c11\u65cf\u5927\u5b66\u7684\u6a0a\u4fdd\u654f\u7b49\u4eba\u62a5\u9053\u4e00\u79cd\u5168\u65b0\u7684\u5149\u6c27\u5316\u8fd8\u539f\u50ac\u5316sulfonylthiazoles\u4e0e\u4e09\u7ea7\u80fa\u884d\u751f\u7269\u7684\u80fa\u7532\u57fa\u5316\u53cd\u5e94\u65b9\u6cd5\u5b66\uff0c\u8fdb\u800c\u6210\u529f\u5b8c\u6210\u4e00\u7cfb\u5217\u70f7\u57fa\u5316\u567b\u5511\u5206\u5b50\u7684\u6784\u5efa\u3002\u8fd9\u4e00\u5168\u65b0\u7684\u80fa\u7532\u57fa\u5316\u5408\u6210\u8f6c\u5316\u7b56\u7565\u5177\u6709\u5e95\u7269\u8303\u56f4\u5e7f\u6cdb\u3001\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u4ee5\u53ca\u4f18\u826f\u7684\u5b98\u80fd\u56e2\u517c\u5bb9\u6027\u7b49\u4f18\u52bf\u3002<\/p>\n

\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/h4>\n