{"id":51674,"date":"2024-11-18T07:30:15","date_gmt":"2024-11-17T23:30:15","guid":{"rendered":"\/\/www.gsbet888.com\/?p=51674"},"modified":"2024-11-18T07:53:53","modified_gmt":"2024-11-17T23:53:53","slug":"chem-station-%e6%9c%ba%e7%90%86%e5%9b%9b-%e7%ad%94%e6%a1%88%e5%8f%8a%e8%8e%b7%e5%a5%96%e5%90%8d%e5%8d%95","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/%e5%8c%96%e5%ad%a6%e4%b9%a0%e9%a2%98\/2024\/11\/chem-station-%e6%9c%ba%e7%90%86%e5%9b%9b-%e7%ad%94%e6%a1%88%e5%8f%8a%e8%8e%b7%e5%a5%96%e5%90%8d%e5%8d%95.html","title":{"rendered":"Chem-Station \u673a\u7406(\u56db) \u7b54\u6848\u53ca\u83b7\u5956\u540d\u5355"},"content":{"rendered":"<p><b><i>Chem-Station<\/i> <\/b><b>\u673a\u7406<\/b><b>(<\/b><b>\u56db<\/b><b>)<\/b><\/p>\n<p>\u4e3a\u4e0b\u9762\u7684\u53cd\u5e94\u63d0\u51fa\u4e00\u79cd\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406\u3002<span class=\"Apple-converted-space\">\u00a0<\/span><\/p>\n<p>\u8bf7\u6ce8\u610f\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u6784\u578b\uff0c\u540c\u65f6\u6ce8\u610f\u63d0\u51fa\u7684\u53cd\u5e94\u673a\u7406\u5fc5\u987b\u80fd\u591f\u89e3\u91ca\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-51638 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/ce6e2814f207c9333f10785606c57df3-2.png\" alt=\"\" width=\"549\" height=\"132\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/ce6e2814f207c9333f10785606c57df3-2.png 549w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/ce6e2814f207c9333f10785606c57df3-2-300x72.png 300w\" sizes=\"(max-width: 549px) 100vw, 549px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p><b><i>Chem-Station<\/i> <\/b><b>\u673a\u7406<\/b><b>(<\/b><b>\u56db<\/b><b>)<\/b><b>\u7684\u53c2\u8003\u7b54\u6848<\/b><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-51686 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/WechatIMG17.jpg\" alt=\"\" width=\"832\" height=\"634\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/WechatIMG17.jpg 832w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/WechatIMG17-300x229.jpg 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/WechatIMG17-680x518.jpg 680w, https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/WechatIMG17-768x585.jpg 768w\" sizes=\"(max-width: 832px) 100vw, 832px\" \/><\/p>\n<p><b>\u8bc4\u5206\u6807\u51c6\uff1a<\/b><\/p>\n<p>1. \u53cd\u5e94\u673a\u7406\u5408\u7406\uff0c\u5173\u952e\u4e2d\u95f4\u4f53\u6b63\u786e\uff0c\u7b26\u5408\u6709\u673a\u5316\u5b66\u7684\u76f8\u5173\u673a\u7406\u53ca\u7ed3\u6784\u7406\u8bba\uff0c\u65e0\u660e\u663e\u7684\u7406\u8bba\u77e5\u8bc6\u9519\u8bef\u4ee5\u53ca\u65e0\u4ea7\u7269\u6784\u578b\u6807\u6ce8\u9519\u8bef (75-80\u5206)\u3002<\/p>\n<p>(2) \u53cd\u5e94\u673a\u7406\u7bad\u5934\u6807\u6ce8\u89c4\u8303\u5168\u9762\uff0c\u7535\u5b50\u8f6c\u79fb\u4f4d\u7f6e\u6e05\u6670\u660e\u786e\uff0c\u7535\u5b50\u8f6c\u79fb\u65b9\u5411\u51c6\u786e\u65e0\u8bef (10-15\u5206)\u3002<\/p>\n<p>(3) \u5728\u7b26\u5408\u4e0a\u8ff0\u4e24\u70b9\u7684\u57fa\u7840\u4e0a\uff0c\u56fe\u7247\u7f8e\u89c2\uff0c\u80fd\u591f\u660e\u663e\u5438\u5f15\u8bfb\u8005\u9605\u8bfb (5-10\u5206)\u3002<\/p>\n<p><b>\u53c2\u8003\u6587\u732e\uff1a<\/b><\/p>\n[1] T. Koshikawa, Y. Nagashima, K. Tanaka, <i>ACS Catal.<\/i>\u00a0<b>2021<\/b>, <i>11<\/i>, 1932. doi: <a href=\"https:\/\/doi.org\/10.1021\/acscatal.0c05394\">10.1021\/acscatal.0c05394<\/a>.<\/p>\n[2] Chloro(dimethylsulfide)gold(I):M. E. de Orbe, A. M. Echavarren, <i>Org. Synth.<\/i>\u00a0<b>2016<\/b>,\u00a0<i>93<\/i>, 115. doi: <a href=\"http:\/\/orgsyn.org\/demo.aspx?prep=v93p0115\">10.15227\/orgsyn.093.0115.<\/a><\/p>\n[3] C(sp<sup>3<\/sup>)\u2212H insertion by cationic gold carbene:H. E. Bruggeman, R. Lorson, L. J. Allen, L. G. Jackson, W. Gee, B. E. Haines, <i>Organometallics<\/i><b><i> <\/i>2024<\/b>, <i>43<\/i>, 2147. doi: <a href=\"https:\/\/doi.org\/10.1021\/acs.organomet.4c00359\">10.1021\/acs.organomet.4c00359<\/a>.<\/p>\n<p><b><i>Chem-Station<\/i> <\/b><b>\u673a\u7406<\/b><b>(<\/b><b>\u56db<\/b><b>)<\/b><b>\u7684\u83b7\u5956\u540d\u5355<\/b><\/p>\n<p>\u4e00\u7b49\u5956\uff1a<b>Fernweh<\/b>\uff1b<\/p>\n<p>\u4e8c\u7b49\u5956\uff1a<b>Hyouryu<\/b>\uff1b<span class=\"Apple-converted-space\">\u00a0<\/span><\/p>\n<p>\u4e09\u7b49\u5956\uff1a<b>Efimich<\/b>;<\/p>\n<p>\u672c\u671f\u6295\u7a3f\u7684\u5c0f\u7f16\u8f83\u5c11\uff0c\u672c\u671f\u53c2\u4e0e\u5956\u505c\u53d1\u3002<\/p>\n<p>\u4e00\u5207\u6d3b\u52a8\u89e3\u91ca\u6743\u5f52Chem-Station\u7f16\u8f91\u90e8\u6240\u6709\u3002<\/p>\n<p><b>Chem-Station<\/b><b>\u7f16\u8f91\u90e8\u62db\u52df\u4f18\u79c0\u7684\u5c0f\u7f16\u548c\u5ba1\u6838\u4eba\u5458\uff0c\u671b\u6709\u610f\u8005\u5c06\u8054\u7cfb\u65b9\u5f0f\u53d1\u81f3<\/b><b>chemstationchina@126.com<\/b><b>\u3002<\/b><\/p>\n<p style=\"text-align: right;\">2024\u5e7411\u670818\u65e5<\/p>\n<p style=\"text-align: right;\">Chem-Station\u7f16\u8f91\u90e8<\/p>\n<p>\u5173\u6ce8Chem-Station\u6296\u97f3\u53f7\uff1a79473891841<\/p>\n<h5>\u8bf7\u767b\u9646TCI\u8bd5\u5242\u5b98\u7f51\u67e5\u770b\u66f4\u591a\u5185\u5bb9<\/h5>\n<h5>https:\/\/www.tcichemicals.com\/CN\/zh\/<\/h5>\n","protected":false},"excerpt":{"rendered":"Chem-Station \u673a\u7406(\u56db) \u4e3a\u4e0b\u9762\u7684\u53cd\u5e94\u63d0\u51fa\u4e00\u79cd\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406\u3002\u00a0 \u8bf7\u6ce8\u610f\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u6784\u578b\uff0c\u540c\u65f6\u6ce8\u610f\u63d0\u51fa\u7684\u53cd\u5e94\u673a\u7406\u5fc5\u987b\u80fd\u591f\u89e3\u91ca\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002 &nbsp; Chem-Station \u673a\u7406(\u56db)\u7684\u53c2\u8003\u7b54\u6848 \u8bc4\u5206\u6807\u51c6\uff1a 1. \u53cd\u5e94\u673a\u7406\u5408\u7406\uff0c\u5173\u952e\u4e2d\u95f4\u4f53\u6b63\u786e\uff0c\u7b26\u5408\u6709\u673a\u5316\u5b66\u7684\u76f8\u5173\u673a\u7406\u53ca\u7ed3\u6784\u7406\u8bba\uff0c\u65e0\u660e\u663e\u7684\u7406\u8bba\u77e5\u8bc6\u9519\u8bef\u4ee5\u53ca\u65e0\u4ea7\u7269\u6784\u578b\u6807\u6ce8\u9519\u8bef (75-80\u5206)\u3002 (2) \u53cd\u5e94\u673a\u7406\u7bad\u5934\u6807\u6ce8\u89c4\u8303\u5168\u9762\uff0c\u7535\u5b50\u8f6c\u79fb\u4f4d\u7f6e\u6e05\u6670\u660e\u786e\uff0c\u7535\u5b50\u8f6c\u79fb\u65b9\u5411\u51c6\u786e\u65e0\u8bef (10-15\u5206)\u3002 (3) \u5728\u7b26\u5408\u4e0a\u8ff0\u4e24\u70b9\u7684\u57fa\u7840\u4e0a\uff0c\u56fe\u7247\u7f8e\u89c2\uff0c\u80fd\u591f\u660e\u663e\u5438\u5f15\u8bfb\u8005\u9605\u8bfb (5-10\u5206)\u3002 \u53c2\u8003\u6587\u732e\uff1a [1] T. Koshikawa, Y. Nagashima, K. Tanaka, ACS Catal.\u00a02021, 11, 1932. doi: 10.1021\/acscatal.0c05394. [2] Chloro(dimethylsulfide)gold(I):M. E. de Orbe, A. M. Echavarren, Org. Synth.\u00a02016,\u00a093, 115. doi: 10.15227\/orgsyn.093.0115. [3] C(sp3)\u2212H insertion by cationic gold carbene:H. E. Bruggeman, R. Lorson, L. J. Allen, L. G. Jackson, W. Gee, B. E. Haines, Organometallics 2024, 43, 2147. doi: 10.1021\/acs.organomet.4c00359. Chem-Station \u673a\u7406(\u56db)\u7684\u83b7\u5956\u540d\u5355 \u4e00\u7b49\u5956\uff1aFernweh\uff1b \u4e8c\u7b49\u5956\uff1aHyouryu\uff1b\u00a0 \u4e09\u7b49\u5956\uff1aEfimich; \u672c\u671f\u6295\u7a3f\u7684\u5c0f\u7f16\u8f83\u5c11\uff0c\u672c\u671f\u53c2\u4e0e\u5956\u505c\u53d1\u3002 \u4e00\u5207\u6d3b\u52a8\u89e3\u91ca\u6743\u5f52Chem-Station\u7f16\u8f91\u90e8\u6240\u6709\u3002 Chem-Station\u7f16\u8f91\u90e8\u62db\u52df\u4f18\u79c0\u7684\u5c0f\u7f16\u548c\u5ba1\u6838\u4eba\u5458\uff0c\u671b\u6709\u610f\u8005\u5c06\u8054\u7cfb\u65b9\u5f0f\u53d1\u81f3chemstationchina@126.com\u3002 2024\u5e7411\u670818\u65e5 Chem-Station\u7f16\u8f91\u90e8 \u5173\u6ce8Chem-Station\u6296\u97f3\u53f7\uff1a79473891841 \u8bf7\u767b\u9646TCI\u8bd5\u5242\u5b98\u7f51\u67e5\u770b\u66f4\u591a\u5185\u5bb9 https:\/\/www.tcichemicals.com\/CN\/zh\/","protected":false},"author":26,"featured_media":51676,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1290],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/11\/WechatIMG16.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-drs","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51674"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=51674"}],"version-history":[{"count":5,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51674\/revisions"}],"predecessor-version":[{"id":51687,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51674\/revisions\/51687"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/51676"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=51674"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=51674"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=51674"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}