{"id":51841,"date":"2024-12-09T08:00:17","date_gmt":"2024-12-09T00:00:17","guid":{"rendered":"\/\/www.gsbet888.com\/?p=51841"},"modified":"2024-12-19T18:25:52","modified_gmt":"2024-12-19T10:25:52","slug":"imino%e2%80%90stetter-reaction","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2024\/12\/imino%e2%80%90stetter-reaction.html","title":{"rendered":"imino\u2010Stetter reaction"},"content":{"rendered":"

\u6982\u8981:<\/strong><\/h4>\n

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imino\u2010Stetter\u53cd\u5e94(imino\u2010Stetter reaction)\u662f\u4e00\u79cd\u5229\u7528\u90bb\u6c28\u57fa\u8089\u6842\u9178\u884d\u751f\u7269\u548c\u82b3\u9999\u919b\u83b7\u5f97\u7684\u919b\u4e9a\u80fa\u4e0e\u6c30\u5316\u7269\u53d1\u751f\u6781\u6027\u53cd\u8f6c\uff0c\u7ecf\u5386 5-enolexo-exo-trig like \u73af\u5316\uff0c\u6700\u7ec8\u82b3\u6784\u5316\u5f97\u5230\u4e00\u7cfb\u52172-\u82b3\u57fa\u53d6\u4ee3\u7684\u5432\u54da-3-\u4e59\u9178\u884d\u751f\u7269\uff0c\u6781\u5927\u5730\u62d3\u5bbd\u4e86\u5408\u6210\u5432\u54da\u7c7b\u5316\u5408\u7269\u7684\u65b9\u6cd5\u3002\u8be5\u53cd\u5e94\u7531\u97e9\u56fd\u9ad8\u4e3d\u5927\u5b66(Department of Chemistry, Korea University)\u7684(\u53f3Cheol-Hong Cheon)\u8bfe\u9898\u7ec4\u57282016\u5e74\u9996\u6b21\u62a5\u9053[1<\/sup><\/p>\n

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    \n
  1. J. Lee, H.-A. Seo, C.-H. Cheon, Adv. Synth. Catal. <\/em>2016<\/strong>, 358<\/em>, 1566-1570. doi: 10.1002\/adsc.201600155<\/a><\/li>\n
  2. -A. Seo, C.-H. Cheon, J. Org. Chem. <\/em>2016<\/strong>, 81<\/em>, 7917-7923. doi: 10.1021\/acs.joc.6b01621.<\/a><\/li>\n
  3. J. Kim, C.-H. Cheon, Asian. J. Org. Chem. <\/em>2020<\/strong>, 9<\/em>, 2103-2107. doi: 10.1002\/ajoc.202000554.<\/a><\/li>\n
  4. Park, C.-H. Cheon, Org. Pro. Res. Dev. <\/em>2024<\/strong>. ASAP<\/em>. doi: 10.1021\/acs.oprd.4c00366.<\/a><\/li>\n
  5. Jeon, H. J. Kim, C.-H. Cheon, J. Org. Chem. <\/em>2020<\/strong>, 85<\/em>, 8149-8156. doi: 10.1021\/acs.joc.0c01051.<\/a><\/li>\n
  6. Park, C.-H. Cheon, Adv. Synth. Catal. <\/em>2019<\/strong>, 361<\/em>, 4888-4892. doi:10.1002\/adsc.201900801<\/a><\/li>\n
  7. Lee, K.-H. Kim, C.-H. Cheon, Org. Lett. <\/em>2017<\/strong>, 19<\/em>, 2785-2788. doi:10.1021\/acs.orglett.7b00687<\/a><\/li>\n
  8. E. Lee, S. J. Lee, C.-H. Cheon, Synthesis <\/em>2017<\/strong>, 49<\/em>, 4247-4253. doi: 10.1055\/s-0036-1588749.<\/a><\/li>\n
  9. H. Kwon, H.-A. Seo, C.-H. Cheon, Org. Lett. <\/em>2016<\/strong>, 18<\/em>, 5280-5283. doi: 10.1021\/acs.orglett.6b02597.<\/a><\/li>\n<\/ol>\n
    \u8bf7\u767b\u9646TCI\u8bd5\u5242\u5b98\u7f51\u67e5\u770b\u66f4\u591a\u5185\u5bb9<\/h5>\n
    https:\/\/www.tcichemicals.com\/CN\/zh\/<\/h5>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981: imino\u2010Stetter\u53cd\u5e94(imino\u2010Stetter reaction)\u662f\u4e00\u79cd\u5229\u7528\u90bb\u6c28\u57fa\u8089\u6842\u9178\u884d\u751f\u7269\u548c\u82b3\u9999\u919b\u83b7\u5f97\u7684\u919b\u4e9a\u80fa\u4e0e\u6c30\u5316\u7269\u53d1\u751f\u6781\u6027\u53cd\u8f6c\uff0c\u7ecf\u5386 5-enolexo-exo-trig like \u73af\u5316\uff0c\u6700\u7ec8\u82b3\u6784\u5316\u5f97\u5230\u4e00\u7cfb\u52172-\u82b3\u57fa\u53d6\u4ee3\u7684\u5432\u54da-3-\u4e59\u9178\u884d\u751f\u7269\uff0c\u6781\u5927\u5730\u62d3\u5bbd\u4e86\u5408\u6210\u5432\u54da\u7c7b\u5316\u5408\u7269\u7684\u65b9\u6cd5\u3002\u8be5\u53cd\u5e94\u7531\u97e9\u56fd\u9ad8\u4e3d\u5927\u5b66(Department of Chemistry, Korea University)\u7684(\u53f3Cheol-Hong Cheon)\u8bfe\u9898\u7ec4\u57282016\u5e74\u9996\u6b21\u62a5\u9053[1 \u53cd\u5e94\u673a\u7406\uff1a \u53cd\u5e94\u5b9e\u4f8b\uff1a   2-\u82b3\u57fa\u53d6\u4ee3\u5432\u54da-3-\u4e59\u9178\u7684\u5408\u6210[1] 2-\u4e59\u70ef\u57fa\u5432\u54da-3-\u4e59\u9178\u7684\u5408\u6210[2] 2-\u53d6\u4ee3\u8272\u80fa\u7684\u5408\u6210[3] \u5929\u7136\u4ea7\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528[4-9] \u5b9e\u9a8c\u6b65\u9aa4\uff1a \u53c2\u8003\u6587\u732e\uff1a J. Lee, H.-A. Seo, C.-H. Cheon, Adv. Synth. Catal. 2016, 358, 1566-1570. doi: 10.1002\/adsc.201600155 -A. Seo, C.-H. Cheon, J. Org. Chem. 2016, 81, 7917-7923. doi: 10.1021\/acs.joc.6b01621. J. Kim, C.-H. Cheon, Asian. J. Org. Chem. 2020, 9, 2103-2107. doi: 10.1002\/ajoc.202000554. Park, C.-H. Cheon, Org. Pro. Res. Dev. 2024. ASAP. doi: 10.1021\/acs.oprd.4c00366. Jeon, H. J. Kim, C.-H. Cheon, J. Org. Chem. 2020, 85, 8149-8156. doi: 10.1021\/acs.joc.0c01051. Park, C.-H. Cheon, Adv. Synth. Catal. 2019, 361, 4888-4892. doi:10.1002\/adsc.201900801 Lee, K.-H. Kim, C.-H. Cheon, Org. Lett. 2017, 19, 2785-2788. doi:10.1021\/acs.orglett.7b00687 E. Lee, S. J. Lee, […]","protected":false},"author":26,"featured_media":51844,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[4449],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/12\/image001.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-du9","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51841"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=51841"}],"version-history":[{"count":6,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51841\/revisions"}],"predecessor-version":[{"id":51919,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51841\/revisions\/51919"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/51844"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=51841"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=51841"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=51841"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}