{"id":51893,"date":"2024-12-16T08:00:55","date_gmt":"2024-12-16T00:00:55","guid":{"rendered":"\/\/www.gsbet888.com\/?p=51893"},"modified":"2024-12-16T09:06:56","modified_gmt":"2024-12-16T01:06:56","slug":"chem-station-%e6%9c%ba%e7%90%86%e4%b8%83-%e7%ad%94%e6%a1%88%e5%8f%8a%e8%8e%b7%e5%a5%96%e5%90%8d%e5%8d%95","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/%e5%8c%96%e5%ad%a6%e6%9d%82%e8%ae%b0\/%e5%8c%96%e5%ad%a6%e4%b9%a0%e9%a2%98\/2024\/12\/chem-station-%e6%9c%ba%e7%90%86%e4%b8%83-%e7%ad%94%e6%a1%88%e5%8f%8a%e8%8e%b7%e5%a5%96%e5%90%8d%e5%8d%95.html","title":{"rendered":"Chem-Station \u673a\u7406(\u4e03) \u7b54\u6848\u53ca\u83b7\u5956\u540d\u5355"},"content":{"rendered":"
\n

Chem-Station<\/em><\/strong> \u673a\u7406<\/strong>(<\/strong>\u4e03<\/strong>)<\/strong><\/h4>\n

\u4e3a\u4e0b\u9762\u7684\u53cd\u5e94\u63d0\u51fa\u4e00\u79cd\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406\u3002\"\"<\/p>\n

\u8bf7\u6ce8\u610f\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u6784\u578b\uff0c\u540c\u65f6\u6ce8\u610f\u63d0\u51fa\u7684\u53cd\u5e94\u673a\u7406\u5fc5\u987b\u80fd\u591f\u89e3\u91ca\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n

Chem-Station<\/em><\/strong> \u673a\u7406<\/strong>(<\/strong>\u4e03<\/strong>)<\/strong>\u7684\u53c2\u8003\u7b54\u6848<\/strong><\/h4>\n

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\u8bc4\u5206\u6807\u51c6\uff1a<\/strong><\/h4>\n

(1) \u53cd\u5e94\u673a\u7406\u5408\u7406\uff0c\u5173\u952e\u4e2d\u95f4\u4f53\u6b63\u786e\uff0c\u7b26\u5408\u6709\u673a\u5316\u5b66\u7684\u76f8\u5173\u673a\u7406\u53ca\u7ed3\u6784\u7406\u8bba\uff0c\u65e0\u660e\u663e\u7684\u7406\u8bba\u77e5\u8bc6\u9519\u8bef\u4ee5\u53ca\u65e0\u4ea7\u7269\u6784\u578b\u6807\u6ce8\u9519\u8bef (75-80\u5206)\u3002<\/p>\n

(2) \u53cd\u5e94\u673a\u7406\u7bad\u5934\u6807\u6ce8\u89c4\u8303\u5168\u9762\uff0c\u7535\u5b50\u8f6c\u79fb\u4f4d\u7f6e\u6e05\u6670\u660e\u786e\uff0c\u7535\u5b50\u8f6c\u79fb\u65b9\u5411\u51c6\u786e\u65e0\u8bef (10-15\u5206)\u3002<\/p>\n

(3) \u5728\u7b26\u5408\u4e0a\u8ff0\u4e24\u70b9\u7684\u57fa\u7840\u4e0a\uff0c\u56fe\u7247\u7f8e\u89c2\uff0c\u80fd\u591f\u660e\u663e\u5438\u5f15\u8bfb\u8005\u9605\u8bfb (5-10\u5206)\u3002<\/p>\n<\/div>\n

\u53c2\u8003\u6587\u732e\uff1a<\/strong><\/h4>\n
\n[1] A. Rehpenn, S. Hindelang, K. Truong, A. P\u00f6thig, G. Storch, Angew. Chem. Int. Ed.<\/em> 2024<\/strong>, 63<\/em>, e202318590. doi: 10.1002\/anie.202318590<\/a>.<\/p>\n

4\u03c0-photocyclization:<\/p>\n

(1) C. Guerra, Y. A. Rodr\u00edguez-N\u00fa\u00f1ez, M. E. Taborda-Mart\u00ednez, M. Bacho, R. Miranda-Pastrana, A. E. Ensunchoc, New J. Chem.<\/em><\/strong> 2024, 48<\/em>, <\/strong>17633. doi: 10.1039\/D4NJ03442B<\/a>.<\/p>\n

(2) S. C. Coote, Eur. J. Org. Chem. <\/em>2020, <\/strong>1405. doi: 10.1002\/ejoc.201901230<\/a>.<\/p>\n

(3) A. C. Day, M. A. Ledlie, J. Chem. Soc. D<\/em><\/strong> 1970<\/strong>, 1265b. doi: 10.1039\/C2970001265B<\/a>.<\/p>\n

divinylcyclopropane rearrangement:<\/p>\n

(1) S. Kr\u00fcger, T. Gaich, Beilstein J. Org. Chem.<\/em> 2014<\/strong>, 10<\/em>, 163. doi:\u00a010.3762\/bjoc.10.14<\/a>.<\/p>\n

other flavin acted as a triplet sensitizer:<\/p>\n

(1) H. Li, M.-T. Zhang, J. Photochem. Photobiol. A <\/em>2018<\/strong>, 355<\/em>, 109. doi: 10.1016\/j.jphotochem.2017.09.077.<\/a><\/p>\n

(2) W. Zhang, K. L. Carpenter, S. Lin, Angew. Chem. Int. Ed. <\/em>2020<\/strong>, 59<\/em>, 409. doi: 10.1002\/anie.201910300<\/a>.<\/p>\n

(3) J. B. Metternich, R. Gilmour, J. Am. Chem. Soc. <\/em>2015<\/strong>, 137<\/em>, 11254. doi: 10.1021\/jacs.5b07136<\/a>.<\/p>\n

(4) M. P. Kabir, P. Ghosh, S. Gozem, J. Phys. Chem. B<\/em>\u00a02024<\/strong>, 128<\/em>, 31, 7545. doi: 10.1021\/acs.jpcb.4c03748<\/a>.<\/p>\n

(5) A. Rehpenn, A. Waltera, G. Storch, Chem. Sci.<\/em><\/strong> 2022<\/strong>, 13<\/em><\/strong>,<\/strong> 14151. doi: 10.1039\/D2SC04341F<\/a>.<\/p>\n

(6) C. T. Walsh, T. A. Wencewicz, Nat. Prod. Rep.<\/em><\/strong> 2013<\/strong>, 30<\/em><\/strong>, 175. doi:\u00a010.1039\/C2NP20069D<\/a>.<\/p>\n

(7) A. Walter, W. Eisenreich, and G. Storch, Angew. Chem. Int. Ed.<\/em>\u00a02023, <\/strong>62<\/em>, 42, e202310634. doi:\u00a010.1002\/anie.202310634<\/a>.<\/p>\n

(8) T. Langschwager, G. Storch. Angew. Chem. Int. Ed.<\/em> 2024<\/strong>, 63<\/em>, e20241467. doi: 10.1002\/anie.202414679<\/a>.<\/p>\n

(9) R. Foja, A. Walter, C. Jandl, E. Thyrhaug, J. Hauer, G. Storch. J. Am. Chem. Soc.<\/em>\u00a02022<\/strong>, 144<\/em>, 4721. doi:10.1021\/jacs.1c13285<\/a>.<\/p>\n

(10) J. B. Metternich, R. Gilmour, J. Am. Chem. Soc. <\/em>2016<\/strong>, 138<\/em>, 1040. doi: 10.1021\/jacs.5b12081<\/a>.<\/p>\n

(11) A. Rehpenn, A. Walter, G. Storch, Chem. Sci. <\/em>2022<\/strong>, 13<\/em>, 14151. doi: 10.1039\/D2SC04341F. <\/a><\/p>\n

Chem-Station<\/em><\/strong> \u673a\u7406<\/strong>(<\/strong>\u4e03<\/strong>)<\/strong>\u7684\u83b7\u5956\u540d\u5355<\/strong><\/h4>\n

\u4e00\u7b49\u5956\uff1aNagano
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\n\u4e09\u7b49\u5956\uff1a jack<\/p>\n

\u4e00\u5207\u6d3b\u52a8\u89e3\u91ca\u6743\u5f52Chem-Station\u7f16\u8f91\u90e8\u6240\u6709\u3002<\/p>\n

Chem-Station<\/strong>\u7f16\u8f91\u90e8\u62db\u52df\u4f18\u79c0\u7684\u5c0f\u7f16\u548c\u5ba1\u6838\u4eba\u5458\uff0c\u671b\u6709\u610f\u8005\u5c06\u8054\u7cfb\u65b9\u5f0f\u53d1\u81f3<\/strong>chemstationchina@126.com<\/strong>\u3002<\/strong><\/p>\n

2024\u5e7412\u670816\u65e5<\/p>\n

Chem-Station\u7f16\u8f91\u90e8<\/p>\n

\u5173\u6ce8Chem-Station\u6296\u97f3\u53f7\uff1a79473891841<\/p>\n

\u8bf7\u767b\u9646TCI\u8bd5\u5242\u5b98\u7f51\u67e5\u770b\u66f4\u591a\u5185\u5bb9<\/h5>\n
https:\/\/www.tcichemicals.com\/CN\/zh\/<\/h5>\n<\/div>\n","protected":false},"excerpt":{"rendered":"Chem-Station \u673a\u7406(\u4e03) \u4e3a\u4e0b\u9762\u7684\u53cd\u5e94\u63d0\u51fa\u4e00\u79cd\u5408\u7406\u7684\u53cd\u5e94\u673a\u7406\u3002 \u8bf7\u6ce8\u610f\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u6784\u578b\uff0c\u540c\u65f6\u6ce8\u610f\u63d0\u51fa\u7684\u53cd\u5e94\u673a\u7406\u5fc5\u987b\u80fd\u591f\u89e3\u91ca\u6bcf\u6b65\u4e2d\u4ea7\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002 Chem-Station \u673a\u7406(\u4e03)\u7684\u53c2\u8003\u7b54\u6848   \u8bc4\u5206\u6807\u51c6\uff1a (1) \u53cd\u5e94\u673a\u7406\u5408\u7406\uff0c\u5173\u952e\u4e2d\u95f4\u4f53\u6b63\u786e\uff0c\u7b26\u5408\u6709\u673a\u5316\u5b66\u7684\u76f8\u5173\u673a\u7406\u53ca\u7ed3\u6784\u7406\u8bba\uff0c\u65e0\u660e\u663e\u7684\u7406\u8bba\u77e5\u8bc6\u9519\u8bef\u4ee5\u53ca\u65e0\u4ea7\u7269\u6784\u578b\u6807\u6ce8\u9519\u8bef (75-80\u5206)\u3002 (2) \u53cd\u5e94\u673a\u7406\u7bad\u5934\u6807\u6ce8\u89c4\u8303\u5168\u9762\uff0c\u7535\u5b50\u8f6c\u79fb\u4f4d\u7f6e\u6e05\u6670\u660e\u786e\uff0c\u7535\u5b50\u8f6c\u79fb\u65b9\u5411\u51c6\u786e\u65e0\u8bef (10-15\u5206)\u3002 (3) \u5728\u7b26\u5408\u4e0a\u8ff0\u4e24\u70b9\u7684\u57fa\u7840\u4e0a\uff0c\u56fe\u7247\u7f8e\u89c2\uff0c\u80fd\u591f\u660e\u663e\u5438\u5f15\u8bfb\u8005\u9605\u8bfb (5-10\u5206)\u3002 \u53c2\u8003\u6587\u732e\uff1a [1] A. Rehpenn, S. Hindelang, K. Truong, A. P\u00f6thig, G. Storch, Angew. Chem. Int. Ed. 2024, 63, e202318590. doi: 10.1002\/anie.202318590. 4\u03c0-photocyclization: (1) C. Guerra, Y. A. Rodr\u00edguez-N\u00fa\u00f1ez, M. E. Taborda-Mart\u00ednez, M. Bacho, R. Miranda-Pastrana, A. E. Ensunchoc, New J. Chem. 2024, 48, 17633. doi: 10.1039\/D4NJ03442B. (2) S. C. Coote, Eur. J. Org. Chem. 2020, 1405. doi: 10.1002\/ejoc.201901230. (3) A. C. Day, M. A. Ledlie, J. Chem. Soc. D 1970, 1265b. doi: 10.1039\/C2970001265B. divinylcyclopropane rearrangement: (1) S. Kr\u00fcger, T. Gaich, Beilstein J. Org. Chem. 2014, 10, 163. doi:\u00a010.3762\/bjoc.10.14. other flavin acted as a […]","protected":false},"author":26,"featured_media":51894,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[1290],"tags":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2024\/12\/d15b3f5370e325a1946956299bc457af.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-duZ","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51893"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=51893"}],"version-history":[{"count":5,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51893\/revisions"}],"predecessor-version":[{"id":51911,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/51893\/revisions\/51911"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/51894"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=51893"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=51893"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=51893"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}