{"id":5487,"date":"2015-06-19T15:46:30","date_gmt":"2015-06-19T07:46:30","guid":{"rendered":"\/\/www.gsbet888.com\/?p=5487"},"modified":"2019-08-02T18:55:24","modified_gmt":"2019-08-02T10:55:24","slug":"criegee%e4%b9%99%e4%ba%8c%e9%86%87%e6%b0%a7%e5%8c%96%e5%bc%80%e8%a3%82criegee-glycol-oxidative-cleavage","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2015\/06\/criegee%e4%b9%99%e4%ba%8c%e9%86%87%e6%b0%a7%e5%8c%96%e5%bc%80%e8%a3%82criegee-glycol-oxidative-cleavage.html","title":{"rendered":"Criegee\u4e59\u4e8c\u9187\u6c27\u5316\u5f00\u88c2(Criegee Glycol Oxidative Cleavage)"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>\u56db\u918b\u9178\u94c5\u50ac\u5316\u76841,2-\u4e8c\u9187(\u4e59\u4e8c\u9187)\u7684\u6c27\u5316\u5f00\u88c2\u7684\u624b\u6cd5\u3002\u8ddf\u9ad8\u7898\u9178\u94a0\u7684\u6c27\u5316\u5f00\u88c2\u76f8\u6bd4\uff0c\u8be5\u53cd\u5e94\u4e0d\u9700\u8981\u6c34\u7cfb\u6eb6\u5242\uff0c\u800c\u4e14\u53cd\u5e94\u6027\u4e5f\u66f4\u9ad8\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Criegee, R. <em>Ber.<\/em> <strong>1933<\/strong>, <em>64<\/em>, 260.<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p><a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/www.chem-station.com\/odos\/2009\/08\/criegee-criegee-glycol-oxidati.html\">Malaprade\u88c2\u89e3(\u9ad8\u7898\u9178\u94a0\u6cd5)<\/a>\u3001\u76f8\u5bf9\u4e8e\u5e95\u7269\u6765\u8bf4\uff0c\u5fc5\u987b\u662fcis\u914d\u7f6e\u7684\u4e8c\u9187\u624d\u53ef\u4ee5\u5f15\u53d1\u88c2\u89e3\u53cd\u5e94\uff0c\u800cCriegee\u6cd5\u5219\u6ca1\u6709\u8fd9\u79cd\u9650\u5236\u3002\u6839\u636e\u8fd9\u4e2a\u7279\u70b9\uff0c\u4e00\u822c\u8ba4\u4e3a\u8be5\u53cd\u5e94\u4e0d\u4f1a\u5f62\u6210\u73af\u72b6\u4e2d\u95f4\u4f53\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/06\/criegee_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-5489 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/06\/criegee_2.gif\" alt=\"criegee_2\" width=\"485\" height=\"91\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>Merrilactone A\u7684\u5408\u6210[1]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/06\/criegee_3.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-5490 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/06\/criegee_3.gif\" alt=\"criegee_3\" width=\"559\" height=\"101\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6280\u5de7<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n[1] (a) Inoue, M.; Sato, T.; Hirama, M. <em>J. Am. Chem. Soc.\u00a0<\/em><strong>2003<\/strong>, <em>125<\/em>, 10772. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1021\/ja036587%2B\">10.1021\/ja036587+<\/a>\u00a0(b) Inoue, M.; Sato, T.; Hirama, M. <em>Angew. Chem. Int. Ed.\u00a0<\/em><strong>2006<\/strong>, <em>45<\/em>, 4843. doi:<a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.200601358\">10.1002\/anie.200601358<\/a><br \/>\n(c) Inoue, M.; Lee, N.; Kasuya, S.; Sato, T.; Hirama, M.; Moriyama,\u00a0M.; Fukuyama, Y. <em>J. Org. Chem.<\/em> <strong>2007<\/strong>,<em>72<\/em>,\u00a03065. DOI: <a class=\"ext-link ext-icon-2\" title=\"\" href=\"http:\/\/dx.doi.org\/10.1021\/jo0700474\">10.1021\/jo0700474<\/a><\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u56db\u918b\u9178\u94c5\u50ac\u5316\u76841,2-\u4e8c\u9187(\u4e59\u4e8c\u9187)\u7684\u6c27\u5316\u5f00\u88c2\u7684\u624b\u6cd5\u3002\u8ddf\u9ad8\u7898\u9178\u94a0\u7684\u6c27\u5316\u5f00\u88c2\u76f8\u6bd4\uff0c\u8be5\u53cd\u5e94\u4e0d\u9700\u8981\u6c34\u7cfb\u6eb6\u5242\uff0c\u800c\u4e14\u53cd\u5e94\u6027\u4e5f\u66f4\u9ad8\u3002 &nbsp; \u57fa\u672c\u6587\u732e Criegee, R. Ber. 1933, 64, 260. &nbsp; \u53cd\u5e94\u673a\u7406 Malaprade\u88c2\u89e3(\u9ad8\u7898\u9178\u94a0\u6cd5)\u3001\u76f8\u5bf9\u4e8e\u5e95\u7269\u6765\u8bf4\uff0c\u5fc5\u987b\u662fcis\u914d\u7f6e\u7684\u4e8c\u9187\u624d\u53ef\u4ee5\u5f15\u53d1\u88c2\u89e3\u53cd\u5e94\uff0c\u800cCriegee\u6cd5\u5219\u6ca1\u6709\u8fd9\u79cd\u9650\u5236\u3002\u6839\u636e\u8fd9\u4e2a\u7279\u70b9\uff0c\u4e00\u822c\u8ba4\u4e3a\u8be5\u53cd\u5e94\u4e0d\u4f1a\u5f62\u6210\u73af\u72b6\u4e2d\u95f4\u4f53\u3002 &nbsp; \u53cd\u5e94\u5b9e\u4f8b Merrilactone A\u7684\u5408\u6210[1] &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e [1] (a) Inoue, M.; Sato, T.; Hirama, M. J. Am. Chem. Soc.\u00a02003, 125, 10772. DOI: 10.1021\/ja036587+\u00a0(b) Inoue, M.; Sato, T.; Hirama, M. Angew. Chem. Int. Ed.\u00a02006, 45, 4843. doi:10.1002\/anie.200601358 (c) Inoue, M.; Lee, N.; Kasuya, S.; Sato, T.; Hirama, M.; Moriyama,\u00a0M.; Fukuyama, Y. J. Org. Chem. 2007,72,\u00a03065. DOI: 10.1021\/jo0700474 &nbsp; \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01","protected":false},"author":5,"featured_media":5488,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[915,916,914],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/06\/2014-10-29_15-34-48.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-1qv","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/5487"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=5487"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/5487\/revisions"}],"predecessor-version":[{"id":27894,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/5487\/revisions\/27894"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/5488"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=5487"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=5487"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=5487"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}