{"id":5932,"date":"2015-08-01T08:25:05","date_gmt":"2015-08-01T00:25:05","guid":{"rendered":"\/\/www.gsbet888.com\/?p=5932"},"modified":"2019-08-02T18:55:17","modified_gmt":"2019-08-02T10:55:17","slug":"%e7%a2%97%e7%83%afcorannulene","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/molecule\/2015\/08\/%e7%a2%97%e7%83%afcorannulene.html","title":{"rendered":"\u7897\u70ef(Corannulene)"},"content":{"rendered":"

\u7897\u70ef\uff08\u5fc3\u73af\u70ef, corannulene\uff09\u9996\u6b21\u57281966\u5e74\u88abLawton\u4e0eBarth\u5408\u6210\u62a5\u9053[1]<\/sup>\u3002\u7897\u70ef\u7684\u5171\u8f6d\u7ed3\u6784\u5982\u4e0b\u56fe\u5de6\u6240\u793a\uff0c\u6574\u4e2a\u7ed3\u6784\u53ef\u4ee5\u770b\u505a\u5185\u4fa7\u662f\u73af\u620a\u4e8c\u70ef\u9634\u79bb\u5b50\u3001\u5916\u4fa7[15]\u662f\u73af\u8f6e\u70ef\u9633\u79bb\u5b50\u3002\u901a\u8fc7\u8fd9\u4e2a\u7ed3\u6784\u7684\u7279\u5f81\uff0c\u7528\u62c9\u4e01\u8bed\u8868\u793a\u4e2d\u5fc3(\u5fc3\u810f)\u300ccor\u300d\u4ee5\u53ca\u73af\u8f6e\u70ef\u7684\u300cannulene\u300d\u7ec4\u5408\u6210\u300ccorannulene\u300d\u4f5c\u4e3a\u8fd9\u4e2a\u5316\u5408\u7269\u7684\u540d\u5b57\u3002\u6700\u521d\u8ba4\u4e3a\u8fd9\u4e2a\u7ed3\u6784\u80fd\u591f\u7a33\u5b9a\u5b58\u5728\u4e3b\u8981\u662f\u56e0\u4e3a\u5176\u5171\u632f\u7a33\u5b9a\u7ed3\u6784\uff0c\u800c\u8fd1\u5e74\u6765\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u53d1\u73b0\uff0c\u5171\u632f\u7ed3\u6784\u5bf9\u5176\u7a33\u5b9a\u6027\u7684\u8d21\u732e\u5e76\u4e0d\u5927[2]<\/sup>\u3002<\/p>\n

\u7897\u70ef\u7684\u7ed3\u6784\u5176\u5b9e\u662f\u5bcc\u52d2\u70ef(C60<\/sub>)\u7ed3\u6784\u7684\u6700\u5c0f\u90e8\u5206\uff0c\u901a\u8fc7X\u5c04\u7ebf\u5355\u6676\u884d\u5c04\u5df2\u7ecf\u786e\u8ba4\u8be5\u7269\u8d28\u5177\u6709\u7897\u72b6\u7ed3\u6784[3]<\/sup>\u3002\u7897\u70ef\u76844\u79cdC-C\u952e\u7ed3\u5408\u662f\u8f66\u8f6e\u72b6\u7684\u6784\u6210\u8981\u7d20\u6240\u4ee5\u88ab\u79f0\u4e3a\u4e3a\u300chub\u300d\u3001\u300cspoke\u300d\u3001\u300cflank\u300d\u3001\u300crim\u300d\uff0c\u6700\u7ec8\u5f62\u6210\u7897\u72b6\u7684\u5f2f\u66f2\u6784\u9020\u7684\u4e3b\u56e0\u4e5f\u6b63\u662f\u56e0\u4e3a\u8fd9\u56db\u79cdC-C\u952e\u7684\u957f\u5ea6\u4e0e\u53cd\u5e94\u6027\u7684\u5dee\u5f02(\u56fe1\u53f3)<\/p>\n

\"\u7121\u984c\"<\/a><\/p>\n

 <\/p>\n

\u7897\u70ef\u7684\u5408\u6210\uff1b<\/h4>\n

\u7897\u70ef\u6700\u5f00\u59cb\u7684\u5408\u6210\u5f00\u53d1\u8fd8\u662f\u5341\u5206\u6709\u6311\u6218\u6027\u7684\u30011991\u5e74\u5f00\u53d1\u51fa\u4e86\u51e0\u5341\u6beb\u514b\u7ea7\u7684\u65b0\u5408\u6210\u624b\u6cd5[4]<\/sup>\u3001\u52301997\u5e74\u6539\u5584\u65b9\u6cd5\u6269\u91cf\u5230\u6570\u767e\u6beb\u514b[5]<\/sup>\u30012006\u5e74\u5230\u514b\u7ea7\u3001\u7136\u540e\u52302012\u5e74\u53c8\u53d1\u5c55\u5230\u516c\u65a4\u7ea7[6]<\/sup>\u7684\u6539\u826f\u5408\u6210\u6cd5\u3001\u5229\u75282012\u5e74\u7684\u6539\u826f\u5408\u6210\u6cd5\u3001\u76ee\u524d\u7897\u70ef\u5df2\u7ecf\u6210\u4e3a\u4e86\u5e38\u89c1\u5e02\u552e\u8bd5\u5242\u3002\u5bf9\u4e8e\u5177\u4f53\u5408\u6210\u65b9\u6cd5\u3001\u8be6\u7ec6\u8bf7\u53c2\u7167\u300c\u7eb3\u7c73\u4e16\u754c\u7684\u559c\u8baf\uff1f\uff01-\u7897\u70ef\u7684kg\u7ea7\u5408\u6210\u6cd5-<\/a>\u300d<\/p>\n

\u5728\u65e5\u672c\u7684\u8bdd\u53ef\u4ee5\u901a\u8fc7\u4e1c\u4eac\u5316\u6210TCI\u8d2d\u4e7019100\u5186 (200mg\u3000\u5236\u54c1Code\uff1aC2572<\/a>)\u3002\u6700\u8fd1\u5173\u4e1c\u5316\u5b66\u4e5f\u5f00\u59cb\u51fa\u552e\uff0c\u552e\u4ef722,000\u5186 (1g: \u5236\u54c1Code\uff1a\u00a007363-65<\/a>)\uff0c\u5927\u91cf\u8d2d\u4e70\u7684\u8bdd\u76f8\u5bf9\u6765\u8bf4\u66f4\u52a0\u5ec9\u4ef7\u3002<\/p>\n

\"2015-06-02_13-37-501\"<\/a><\/p>\n

 <\/p>\n

\u8bba\u6587\u51fa\u7248\u6570<\/h4>\n

\u8fd1\u5e74\u6765\uff0c\u5173\u4e8e\u7897\u70ef\u7684\u5408\u6210\u6cd5\u7684\u76f8\u5173\u8bba\u6587\u6570\u5927\u91cf\u589e\u52a0\uff0c\u52302015\u5e746\u67088\u65e5\u4e3a\u6b62\uff0c\u901a\u8fc7SciFinder\u7edf\u8ba1\uff0c\u5173\u4e8e\u7897\u70ef\u7684\u8bba\u6587\u7efc\u8ff0\u5df2\u7ecf\u8fbe\u5230939\u7bc7\u3002\u8bba\u6587\u6570\u51fa\u7248\u4f5c\u8005\u7684\u6392\u5e8f\u4e3a<\/p>\n

1 \u4f4d Lawrence T. Scott 124 \u7bc7<\/p>\n

2 \u4f4d Marina A. Petrukhina 89 \u7bc7<\/p>\n

3 \u4f4d Jay S. Siegel 76 \u7bc7<\/p>\n

\"2015-07-07_20-16-182\"<\/a><\/p>\n

 <\/p>\n

\u5e94\u7528\u7814\u7a76<\/h4>\n

\u540d\u53e4\u5c4b\u5927\u5b66\u7684\u4f0a\u4e39\u5065\u4e00\u90ce<\/a>\u3001\u901a\u8fc7\u6ce2\u58eb\u987f\u5927\u5b66Scott\u7b49\u4eba\u5408\u6210\u7684\u5e02\u552e\u7897\u70ef\u4f5c\u4e3a\u539f\u6599\uff0c\u53ea\u75282\u6b65\u53cd\u5e94\u6210\u529f\u5408\u6210\u4e86\u542b\u670980\u4e2a\u78b3\u539f\u5b50\u4e0e30\u4e2a\u6c22\u539f\u5b50\u7684\u5f2f\u66f2\u78b3\u7eb3\u7c73\u77f3\u58a8\u70ef\u3002[7]<\/sup><\/p>\n

\"C80H30_f1-254x300\"<\/a><\/p>\n

 <\/p>\n

\u4e1c\u4eac\u5927\u5b66\u7684\u76f8\u7530\u5353\u4e09<\/a>\u7b49\u4eba\u3001\u5229\u7528\u542b\u6709\u9170\u80fa\u7684\u786b\u4ee3\u5355\u4f53(monomer)\uff0c\u5bfc\u5165\u7897\u70ef\u4e2d\uff0c\u5229\u7528\u8be5\u65b0\u65b9\u6cd5\u5408\u6210\u4e86\u65b0\u578b\u8d85\u5206\u5b50\u805a\u5408\u7269\u3002[8]\n

\"2b530e80c7d0de90885e285c5d798063\"<\/a><\/p>\n

 <\/p>\n

\u53e6\u5916\uff0c\u6700\u8fd1\u4e1c\u4eac\u5927\u5b66\u7684\u5869\u8c37\u5149\u5f66<\/a>\u7814\u7a76\u5ba4\u3001\u62a5\u9053\u4e86\u7897\u70ef\u7684\u7a33\u5b9a\u7684flank\u952e\u7684\u50ac\u5316\u5f00\u73af\u7684\u65b9\u6cd5\u3002[9]<\/sup><\/p>\n

\"2015-06-17_02-41-36\"<\/a><\/p>\n

 <\/p>\n

\u53c2\u8003\u6587\u732e<\/h4>\n
    \n
  1. Barth, W. E.; Lawton, R. G.\u00a0J. Am. Chem. Soc.<\/em>\u00a01966<\/strong>,\u00a088<\/em>, 380. DOI:\u00a010.1021\/ja00954a049<\/a><\/li>\n
  2. Monaco, G.; Scott, L. T.; Zanasi, R.\u00a0J. Phys. Chem. A<\/em>\u00a02008<\/strong>,\u00a0112<\/em>, 8136. DOI:\u00a010.1021\/jp8038779<\/a><\/li>\n
  3. Hanson, J. C.; Nordman, C. E.\u00a0Acta Crystallogr<\/em>.\u00a01976<\/strong>,\u00a0B32<\/em>, 1147.<\/li>\n
  4. Scott, L. T.; Hashemi, M. M.; Meyer, D. T.; Warren, H. B. J. Am. Chem. Soc.<\/em> 1991<\/strong>, 113<\/em>, 7082. DOI:\u00a010.1021\/ja00018a082<\/a><\/li>\n
  5. Scott, L. T.; Cheng, P.-C.; Hashemi, M. M.; Bratcher, M. S.; Warren, H. B. J. Am. Chem. Soc.<\/em> 1997<\/strong>,119<\/em>, 10963. DOI:\u00a010.1021\/ja972019g<\/a><\/li>\n
  6. Butterfield, A. M.; Gilomen, B.; Siegel, J.S. Org. Process Res. Dev.<\/em> 2012<\/strong>, 16<\/em>, 664. DOI:10.1021\/op200387s<\/a><\/li>\n
  7. Kawasumi, K.; Zhang, Q.; Segawa, Y.; Scott, L. T.; Itami, K. Nature Chemistry<\/i> 2013<\/b>, 5<\/i>, 739. DOI:\u00a010.1038\/nchem.1704<\/a><\/li>\n
  8. Kang, J.; Miyajima, D.; Mori, T.; Inoue, Y.; Itoh, Y.; Aida, T\u00a0Science<\/em>\u00a02015<\/strong>,\u00a0347<\/em>, 646. DOI:10.1126\/science.aaa4249<\/a><\/li>\n
  9. Tashiro, S.; Yamada, M.; Shionoya, M.\u00a0Angew. Chem. Int. Ed.\u00a0<\/i>2015<\/b>,\u00a054<\/i>, 5351. DOI:\u00a010.1002\/anie.201500819<\/a><\/li>\n<\/ol>\n

     <\/p>\n

    \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d\uff01<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u7897\u70ef\uff08\u5fc3\u73af\u70ef, corannulene\uff09\u9996\u6b21\u57281966\u5e74\u88abLawton\u4e0eBarth\u5408\u6210\u62a5\u9053[1]\u3002\u7897\u70ef\u7684\u5171\u8f6d\u7ed3\u6784\u5982\u4e0b\u56fe\u5de6\u6240\u793a\uff0c\u6574\u4e2a\u7ed3\u6784\u53ef\u4ee5\u770b\u505a\u5185\u4fa7\u662f\u73af\u620a\u4e8c\u70ef\u9634\u79bb\u5b50\u3001\u5916\u4fa7[15]\u662f\u73af\u8f6e\u70ef\u9633\u79bb\u5b50\u3002\u901a\u8fc7\u8fd9\u4e2a\u7ed3\u6784\u7684\u7279\u5f81\uff0c\u7528\u62c9\u4e01\u8bed\u8868\u793a\u4e2d\u5fc3(\u5fc3\u810f)\u300ccor\u300d\u4ee5\u53ca\u73af\u8f6e\u70ef\u7684\u300cannulene\u300d\u7ec4\u5408\u6210\u300ccorannulene\u300d\u4f5c\u4e3a\u8fd9\u4e2a\u5316\u5408\u7269\u7684\u540d\u5b57\u3002\u6700\u521d\u8ba4\u4e3a\u8fd9\u4e2a\u7ed3\u6784\u80fd\u591f\u7a33\u5b9a\u5b58\u5728\u4e3b\u8981\u662f\u56e0\u4e3a\u5176\u5171\u632f\u7a33\u5b9a\u7ed3\u6784\uff0c\u800c\u8fd1\u5e74\u6765\u901a\u8fc7\u7406\u8bba\u8ba1\u7b97\u53d1\u73b0\uff0c\u5171\u632f\u7ed3\u6784\u5bf9\u5176\u7a33\u5b9a\u6027\u7684\u8d21\u732e\u5e76\u4e0d\u5927[2]\u3002 \u7897\u70ef\u7684\u7ed3\u6784\u5176\u5b9e\u662f\u5bcc\u52d2\u70ef(C60)\u7ed3\u6784\u7684\u6700\u5c0f\u90e8\u5206\uff0c\u901a\u8fc7X\u5c04\u7ebf\u5355\u6676\u884d\u5c04\u5df2\u7ecf\u786e\u8ba4\u8be5\u7269\u8d28\u5177\u6709\u7897\u72b6\u7ed3\u6784[3]\u3002\u7897\u70ef\u76844\u79cdC-C\u952e\u7ed3\u5408\u662f\u8f66\u8f6e\u72b6\u7684\u6784\u6210\u8981\u7d20\u6240\u4ee5\u88ab\u79f0\u4e3a\u4e3a\u300chub\u300d\u3001\u300cspoke\u300d\u3001\u300cflank\u300d\u3001\u300crim\u300d\uff0c\u6700\u7ec8\u5f62\u6210\u7897\u72b6\u7684\u5f2f\u66f2\u6784\u9020\u7684\u4e3b\u56e0\u4e5f\u6b63\u662f\u56e0\u4e3a\u8fd9\u56db\u79cdC-C\u952e\u7684\u957f\u5ea6\u4e0e\u53cd\u5e94\u6027\u7684\u5dee\u5f02(\u56fe1\u53f3)   \u7897\u70ef\u7684\u5408\u6210\uff1b \u7897\u70ef\u6700\u5f00\u59cb\u7684\u5408\u6210\u5f00\u53d1\u8fd8\u662f\u5341\u5206\u6709\u6311\u6218\u6027\u7684\u30011991\u5e74\u5f00\u53d1\u51fa\u4e86\u51e0\u5341\u6beb\u514b\u7ea7\u7684\u65b0\u5408\u6210\u624b\u6cd5[4]\u3001\u52301997\u5e74\u6539\u5584\u65b9\u6cd5\u6269\u91cf\u5230\u6570\u767e\u6beb\u514b[5]\u30012006\u5e74\u5230\u514b\u7ea7\u3001\u7136\u540e\u52302012\u5e74\u53c8\u53d1\u5c55\u5230\u516c\u65a4\u7ea7[6]\u7684\u6539\u826f\u5408\u6210\u6cd5\u3001\u5229\u75282012\u5e74\u7684\u6539\u826f\u5408\u6210\u6cd5\u3001\u76ee\u524d\u7897\u70ef\u5df2\u7ecf\u6210\u4e3a\u4e86\u5e38\u89c1\u5e02\u552e\u8bd5\u5242\u3002\u5bf9\u4e8e\u5177\u4f53\u5408\u6210\u65b9\u6cd5\u3001\u8be6\u7ec6\u8bf7\u53c2\u7167\u300c\u7eb3\u7c73\u4e16\u754c\u7684\u559c\u8baf\uff1f\uff01-\u7897\u70ef\u7684kg\u7ea7\u5408\u6210\u6cd5-\u300d \u5728\u65e5\u672c\u7684\u8bdd\u53ef\u4ee5\u901a\u8fc7\u4e1c\u4eac\u5316\u6210TCI\u8d2d\u4e7019100\u5186 (200mg\u3000\u5236\u54c1Code\uff1aC2572)\u3002\u6700\u8fd1\u5173\u4e1c\u5316\u5b66\u4e5f\u5f00\u59cb\u51fa\u552e\uff0c\u552e\u4ef722,000\u5186 (1g: \u5236\u54c1Code\uff1a\u00a007363-65)\uff0c\u5927\u91cf\u8d2d\u4e70\u7684\u8bdd\u76f8\u5bf9\u6765\u8bf4\u66f4\u52a0\u5ec9\u4ef7\u3002   \u8bba\u6587\u51fa\u7248\u6570 \u8fd1\u5e74\u6765\uff0c\u5173\u4e8e\u7897\u70ef\u7684\u5408\u6210\u6cd5\u7684\u76f8\u5173\u8bba\u6587\u6570\u5927\u91cf\u589e\u52a0\uff0c\u52302015\u5e746\u67088\u65e5\u4e3a\u6b62\uff0c\u901a\u8fc7SciFinder\u7edf\u8ba1\uff0c\u5173\u4e8e\u7897\u70ef\u7684\u8bba\u6587\u7efc\u8ff0\u5df2\u7ecf\u8fbe\u5230939\u7bc7\u3002\u8bba\u6587\u6570\u51fa\u7248\u4f5c\u8005\u7684\u6392\u5e8f\u4e3a 1 \u4f4d Lawrence T. Scott 124 \u7bc7 2 \u4f4d Marina A. Petrukhina 89 \u7bc7 3 \u4f4d Jay S. Siegel 76 \u7bc7   \u5e94\u7528\u7814\u7a76 \u540d\u53e4\u5c4b\u5927\u5b66\u7684\u4f0a\u4e39\u5065\u4e00\u90ce\u3001\u901a\u8fc7\u6ce2\u58eb\u987f\u5927\u5b66Scott\u7b49\u4eba\u5408\u6210\u7684\u5e02\u552e\u7897\u70ef\u4f5c\u4e3a\u539f\u6599\uff0c\u53ea\u75282\u6b65\u53cd\u5e94\u6210\u529f\u5408\u6210\u4e86\u542b\u670980\u4e2a\u78b3\u539f\u5b50\u4e0e30\u4e2a\u6c22\u539f\u5b50\u7684\u5f2f\u66f2\u78b3\u7eb3\u7c73\u77f3\u58a8\u70ef\u3002[7]   \u4e1c\u4eac\u5927\u5b66\u7684\u76f8\u7530\u5353\u4e09\u7b49\u4eba\u3001\u5229\u7528\u542b\u6709\u9170\u80fa\u7684\u786b\u4ee3\u5355\u4f53(monomer)\uff0c\u5bfc\u5165\u7897\u70ef\u4e2d\uff0c\u5229\u7528\u8be5\u65b0\u65b9\u6cd5\u5408\u6210\u4e86\u65b0\u578b\u8d85\u5206\u5b50\u805a\u5408\u7269\u3002[8]   \u53e6\u5916\uff0c\u6700\u8fd1\u4e1c\u4eac\u5927\u5b66\u7684\u5869\u8c37\u5149\u5f66\u7814\u7a76\u5ba4\u3001\u62a5\u9053\u4e86\u7897\u70ef\u7684\u7a33\u5b9a\u7684flank\u952e\u7684\u50ac\u5316\u5f00\u73af\u7684\u65b9\u6cd5\u3002[9]   \u53c2\u8003\u6587\u732e Barth, W. E.; Lawton, R. G.\u00a0J. Am. Chem. Soc.\u00a01966,\u00a088, 380. DOI:\u00a010.1021\/ja00954a049 Monaco, G.; Scott, L. T.; Zanasi, R.\u00a0J. Phys. Chem. A\u00a02008,\u00a0112, 8136. DOI:\u00a010.1021\/jp8038779 Hanson, J. C.; Nordman, C. E.\u00a0Acta Crystallogr.\u00a01976,\u00a0B32, 1147. Scott, L. T.; Hashemi, M. M.; Meyer, D. T.; Warren, H. B. J. Am. Chem. Soc. 1991, 113, 7082. DOI:\u00a010.1021\/ja00018a082 Scott, L. T.; Cheng, P.-C.; Hashemi, M. M.; Bratcher, M. S.; Warren, H. B. J. Am. […]","protected":false},"author":5,"featured_media":5933,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[869],"tags":[959,960,958],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/07\/2015-07-07_20-47-24.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-1xG","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/5932"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=5932"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/5932\/revisions"}],"predecessor-version":[{"id":27870,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/5932\/revisions\/27870"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/5933"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=5932"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=5932"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=5932"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}