{"id":6335,"date":"2015-08-29T07:54:02","date_gmt":"2015-08-28T23:54:02","guid":{"rendered":"\/\/www.gsbet888.com\/?p=6335"},"modified":"2019-08-02T18:55:12","modified_gmt":"2019-08-02T10:55:12","slug":"doering-laflamme%e4%b8%99%e4%ba%8c%e7%83%af%e5%90%88%e6%88%90doering-laflamme-allene-synthesis","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e9%87%8d%e6%8e%92%e5%8f%8d%e5%ba%94\/2015\/08\/doering-laflamme%e4%b8%99%e4%ba%8c%e7%83%af%e5%90%88%e6%88%90doering-laflamme-allene-synthesis.html","title":{"rendered":"Doering-LaFlamme\u4e19\u4e8c\u70ef\u5408\u6210(Doering-LaFlamme Allene Synthesis)"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>1,1\uff0d\u4e8c\u5364\u4ee3\u73af\u4e19\u70f7\u5728\u70f7\u57fa\u9502\u4f5c\u7528\u4e0b\uff0c\u5f62\u6210\u5361\u5bbe\u540e\u5f15\u8d77\u91cd\u6392\u53cd\u5e94\uff0c\u5f97\u5230\u4e19\u4e8c\u70ef\u7684\u53cd\u5e94\u3002<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Doering, W. v. E.; Hoffmann, A. K. <em>J. Am. Chem. Soc.<\/em> <strong>1954<\/strong>,\u00a0<em>76<\/em>, 6162. DOI: 10.1021\/ja01652a087<\/li>\n<li>Doering, W. v. E.; LaFlamme, P. <em>J. Am. Chem. Soc.<\/em> <strong>1956<\/strong>,\u00a0<em>78<\/em>, 5447. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/ja01601a079\">10.1021\/ja01601a079<\/a><\/li>\n<li>Dorging, W. v. E.; LaFlamme, P. <em>Tetrahedron<\/em> <strong>1958<\/strong>,\u00a0<em>2<\/em>, 75. doi: <a href=\"http:\/\/dx.doi.org\/10.1016\/0040-4020(58)88025-4\">10.1016\/0040-4020(58)88025-4<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p>\u03b1-\u6d88\u9664\u540e\u3001\u5f62\u6210\u5361\u5bbe\u4e2d\u95f4\u4f53\u5f15\u8d77\u91cd\u6392\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/08\/doering_allene_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-6337 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/08\/doering_allene_2.gif\" alt=\"doering_allene_2\" width=\"344\" height=\"186\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6280\u5de7<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 1,1\uff0d\u4e8c\u5364\u4ee3\u73af\u4e19\u70f7\u5728\u70f7\u57fa\u9502\u4f5c\u7528\u4e0b\uff0c\u5f62\u6210\u5361\u5bbe\u540e\u5f15\u8d77\u91cd\u6392\u53cd\u5e94\uff0c\u5f97\u5230\u4e19\u4e8c\u70ef\u7684\u53cd\u5e94\u3002 \u57fa\u672c\u6587\u732e Doering, W. v. E.; Hoffmann, A. K. J. Am. Chem. Soc. 1954,\u00a076, 6162. DOI: 10.1021\/ja01652a087 Doering, W. v. E.; LaFlamme, P. J. Am. Chem. Soc. 1956,\u00a078, 5447. DOI: 10.1021\/ja01601a079 Dorging, W. v. E.; LaFlamme, P. Tetrahedron 1958,\u00a02, 75. doi: 10.1016\/0040-4020(58)88025-4 &nbsp; \u53cd\u5e94\u673a\u7406 \u03b1-\u6d88\u9664\u540e\u3001\u5f62\u6210\u5361\u5bbe\u4e2d\u95f4\u4f53\u5f15\u8d77\u91cd\u6392\u3002 &nbsp; \u53cd\u5e94\u5b9e\u4f8b &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e &nbsp; \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d","protected":false},"author":5,"featured_media":6336,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[12],"tags":[377,862,716],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/08\/2014-10-29_14-09-51.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-1Eb","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/6335"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=6335"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/6335\/revisions"}],"predecessor-version":[{"id":27853,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/6335\/revisions\/27853"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/6336"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=6335"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=6335"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=6335"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}