{"id":7558,"date":"2015-12-03T07:30:30","date_gmt":"2015-12-02T23:30:30","guid":{"rendered":"\/\/www.gsbet888.com\/?p=7558"},"modified":"2019-08-02T18:54:56","modified_gmt":"2019-08-02T10:54:56","slug":"post-7558","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e9%87%8d%e6%8e%92%e5%8f%8d%e5%ba%94\/2015\/12\/post-7558.html","title":{"rendered":"Ferrier\u91cd\u6392\u53cd\u5e94(Ferrier Rearrangement)"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>2,3-\u70ef\u7cd6\u901a\u8fc7\u70ef\u4e19\u57fa\u91cd\u6392\u4e0e\u4eb2\u6838\u53cd\u5e94\u57281\u4f4d\u5bfc\u5165\u53d6\u4ee3\u57fa\u7684\u624b\u6cd5\u3002<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Ferrier, R.J. <em>J. Chem. Soc., Perkin Trans I<\/em> <strong>1979<\/strong>,\u00a01455.<\/li>\n<li>Danishefsky, S. J.; Kerwin Jr., J. F. <em>J. Org. Chem. <\/em><strong>1982<\/strong>,\u00a0<em>47<\/em>, 3803. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/jo00140a053\">10.1021\/jo00140a053<\/a><\/li>\n<li>Danishefsky, S. J.; DeNinno, S.; Lartey, P. <em>J. Am. Chem. Soc.\u00a0<\/em><strong>1987<\/strong>, <em>109<\/em>, 2082. DOI:<a href=\"http:\/\/dx.doi.org\/10.1021\/ja00241a028\">10.1021\/ja00241a028<\/a><\/li>\n<li>Ferrier, R. J.; Middleton, S. <em>Chem. Rev.<\/em> <strong>1993<\/strong>,\u00a0<em>93<\/em>, 2779. DOI: <a href=\"http:\/\/dx.doi.org\/10.1021\/cr00024a008\">10.1021\/cr00024a008<\/a><\/li>\n<li>Ferrier, R. J. <em>Top. Curr. Chem.<\/em> <strong>2001<\/strong>, <em>215<\/em>,\u00a0153.<\/li>\n<li>Ferrier, R. J.; Zubkov, O. A. <em>Org. React.<\/em> <strong>2003<\/strong>,\u00a0<em>vol 62<\/em>. doi:<a href=\"http:\/\/dx.doi.org\/10.1002\/0471264180.or062.04\">10.1002\/0471264180.or062.04<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5fdc\u6a5f\u69cb<\/h4>\n<p>\u901a\u8fc7\u8def\u6613\u65af\u9178\u6d3b\u5316\u79bb\u53bb\u57fa\u56e2\u540e\u4ea7\u751f\u79bb\u57df\u7684\u6c27\u6742\u70ef\u4e19\u57fa\u78b3\u6b63\u79bb\u5b50\u4f5c\u4e3a\u53cd\u5e94\u6d3b\u6027\u79cd\u8fdb\u884c\u53cd\u5e94\u3002 <a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/11\/ferrier_2.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-7560 size-full\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/11\/ferrier_2.gif\" alt=\"ferrier_2\" width=\"436\" height=\"98\" \/><\/a><\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6b65\u9aa4<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u5b9e\u9a8c\u6280\u5de7<\/h4>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<\/strong><a href=\"\/\/www.gsbet888.com\/\"><strong><span style=\"color: #0066cc\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/span><\/strong><\/a><strong>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 2,3-\u70ef\u7cd6\u901a\u8fc7\u70ef\u4e19\u57fa\u91cd\u6392\u4e0e\u4eb2\u6838\u53cd\u5e94\u57281\u4f4d\u5bfc\u5165\u53d6\u4ee3\u57fa\u7684\u624b\u6cd5\u3002 \u57fa\u672c\u6587\u732e Ferrier, R.J. J. Chem. Soc., Perkin Trans I 1979,\u00a01455. Danishefsky, S. J.; Kerwin Jr., J. F. J. Org. Chem. 1982,\u00a047, 3803. DOI: 10.1021\/jo00140a053 Danishefsky, S. J.; DeNinno, S.; Lartey, P. J. Am. Chem. Soc.\u00a01987, 109, 2082. DOI:10.1021\/ja00241a028 Ferrier, R. J.; Middleton, S. Chem. Rev. 1993,\u00a093, 2779. DOI: 10.1021\/cr00024a008 Ferrier, R. J. Top. Curr. Chem. 2001, 215,\u00a0153. Ferrier, R. J.; Zubkov, O. A. Org. React. 2003,\u00a0vol 62. doi:10.1002\/0471264180.or062.04 &nbsp; \u53cd\u5fdc\u6a5f\u69cb \u901a\u8fc7\u8def\u6613\u65af\u9178\u6d3b\u5316\u79bb\u53bb\u57fa\u56e2\u540e\u4ea7\u751f\u79bb\u57df\u7684\u6c27\u6742\u70ef\u4e19\u57fa\u78b3\u6b63\u79bb\u5b50\u4f5c\u4e3a\u53cd\u5e94\u6d3b\u6027\u79cd\u8fdb\u884c\u53cd\u5e94\u3002 \u53cd\u5e94\u5b9e\u4f8b &nbsp; \u5b9e\u9a8c\u6b65\u9aa4 &nbsp; \u5b9e\u9a8c\u6280\u5de7 &nbsp; \u53c2\u8003\u6587\u732e &nbsp; \u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0Chem-Station\u5316\u5b66\u7a7a\u95f4\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d","protected":false},"author":5,"featured_media":7559,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[12],"tags":[1134,1133,466],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2015\/11\/2014-10-30_00-15-21.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-1XU","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/7558"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=7558"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/7558\/revisions"}],"predecessor-version":[{"id":27796,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/7558\/revisions\/27796"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/7559"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=7558"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=7558"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=7558"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}