{"id":834,"date":"2014-03-23T22:58:16","date_gmt":"2014-03-23T14:58:16","guid":{"rendered":"\/\/www.gsbet888.com\/?p=834"},"modified":"2019-08-02T18:57:08","modified_gmt":"2019-08-02T10:57:08","slug":"%e9%86%87%e5%88%b0%e7%83%b7%e7%9a%84%e8%bd%ac%e5%8f%98conversion-from-alcohol-to-alkane","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e5%8f%96%e4%bb%a3%e5%8f%8d%e5%ba%94\/2014\/03\/%e9%86%87%e5%88%b0%e7%83%b7%e7%9a%84%e8%bd%ac%e5%8f%98conversion-from-alcohol-to-alkane.html","title":{"rendered":"\u9187\u5230\u70f7\u7684\u8f6c\u53d8Conversion from Alcohol to Alkane"},"content":{"rendered":"
\u4e00\u822c\u6765\u8bf4\uff0c\u7531\u9187\u76f4\u63a5\u8fd8\u539f\u751f\u6210\u70f7\u7684\u8f6c\u5316\u8f83\u4e3a\u56f0\u96be\u3002\u901a\u5e38\u3001\u5c06\u9187\u53d8\u4e3a\u5364\u5316\u7269\u3001\u78fa\u9178\u916f\u7b49\u5bb9\u6613\u79bb\u53bb\u7684\u57fa\u56e2\u540e\uff0c\u518d\u52a0\u5165\u91d1\u5c5e\u6c22\u8d1f\u79bb\u5b50\u6e90<\/span>(LiAlH4<\/sub>\u3001LiHBEt3<\/sub>\u3001Bu3<\/sub>SnH+\u81ea\u7531\u57fa\u5f15\u53d1\u5242\u7b49)<\/strong><\/span>\u6765\u5b9e\u73b0\u9187\u5230\u70f7\u7684\u8f6c\u5316\u3002\u719f\u4e3a\u4eba\u77e5\u7684\u5c06\u5364\u5316\u7269\u8fd8\u539f\u8131\u5364\u7684\u7ecf\u5178\u6761\u4ef6\u662f<\/span>\u50ac\u5316\u52a0\u6c22<\/a>\u3001<\/strong>Birch\u8fd8\u539f<\/a><\/strong>\u7b49\u3002<\/span><\/p>\n \u9187\u7684\u5364\u5316\u53ef\u7528PX3<\/sub>\u3001PX5<\/sub>\u3001SOCl2<\/sub>\u3001(COCl)2<\/sub><\/strong>\u7b49\u7b80\u4fbf\u6613\u5f97\u7684\u53cd\u5e94\u8bd5\u5242\u6765\u5b9e\u73b0\u3002\u82e5\u60f3\u8981\u53cd\u5e94\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u53ef\u7528Appel\u53cd\u5fdc<\/strong><\/a>\u3002\u9187\u7684\u78fa\u9178\u916f\u5316<\/a>\u53ef\u5728MsCl-Et3<\/sub>N\u3001TsCl-Py\uff08-DMAP)\u4f53\u7cfb\u4e2d\u53d1\u751f\u00a0<\/strong>\u3002<\/p>\n \u8102\u80aa\u65cf\u4f2f\u9187\u4ee5\u5916\u7684\u9187\u53ef\u5728LiAlH4<\/sub>-AlCl3<\/sub>(1:3)<\/strong>\u7684\u6761\u4ef6\u4e0b\u8fd8\u539f\u3001\u4f46\u7531\u4e8e\u5f62\u6210\u78b3\u6b63\u79bb\u5b50\u4e2d\u95f4\u4f53\u3001\u57fa\u56e2\u8fc1\u79fb\uff0c\u5f02\u6784\u5316\u7b49\u8f83\u5bb9\u6613\u53d1\u751f\u3002<\/p>\n