{"id":840,"date":"2014-03-24T09:49:23","date_gmt":"2014-03-24T01:49:23","guid":{"rendered":"\/\/www.gsbet888.com\/?p=840"},"modified":"2019-08-02T18:57:08","modified_gmt":"2019-08-02T10:57:08","slug":"post-840","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e5%8f%96%e4%bb%a3%e5%8f%8d%e5%ba%94\/2014\/03\/post-840.html","title":{"rendered":"\u6851\u5fb7\u8fc8\u5c14\u53cd\u5e94 Sandmeyer Reaction"},"content":{"rendered":"<ul>\n<li>\u6982\u8981<\/li>\n<\/ul>\n<p>\u8be5\u53cd\u5e94\u82b3\u9999\u65cf\u91cd\u6c2e\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u4e00\u7cfb\u5217\u53d6\u4ee3\u57fa\u7684\u603b\u79f0\u3002\u91cd\u6c2e\u5316\u5408\u7269\u662f\u7531\u8148\u6216\u82ef\u80fa\u7b49\u4f5c\u4e3a\u539f\u6599\u5f88\u5bb9\u6613\u5f97\u5230\u7684\u884d\u751f\u7269\u3002<\/p>\n<ul>\n<li>\u57fa\u672c\u6587\u732e<\/li>\n<\/ul>\n<p>\u30fbSandmeyer, T.\u00a0<em>Ber.<\/em>\u00a0<strong>1884<\/strong>,\u00a0<em>17<\/em>, 1633.<br \/>\n\u30fbSandmeyer, T.\u00a0<em>Ber.<\/em>\u00a0<strong>1884<\/strong>,\u00a0<em>17<\/em>, 2650.<br \/>\n\u30fbHodgson, H. H.\u00a0<em>Chem. Rev.<\/em>\u00a0<strong>1947<\/strong>,\u00a0<em>40<\/em>, 251. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/cr60126a003\">10.1021\/cr60126a003\u00a0<\/a><br \/>\n\u30fbGalli, C.\u00a0<em>Chem. Rev.<\/em>\u00a0<strong>1988<\/strong>,\u00a0<em>88<\/em>, 765. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/cr00087a004\">10.1021\/cr00087a004<\/a><\/p>\n<ul>\n<li>\u53cd\u5e94\u673a\u7406<\/li>\n<\/ul>\n<p>\u4ece\u5f62\u5f0f\u4e0a\u76f8\u5f53\u4e8e\u82b3\u9999\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\u3002\u5b9e\u9645\u53ef\u80fd\u7531\u5355\u7535\u5b50\u8f6c\u79fb\u673a\u7406\u5b8c\u6210\uff0c\u4f46\u76ee\u524d\u5c1a\u672a\u660e\u786e\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter\" src=\"http:\/\/www.chem-station.com\/odos\/images\/sandmeyer_3.gif\" alt=\"sandmeyer_3.gif\" width=\"601\" height=\"64\" \/><\/p>\n<ul>\n<li>\u53cd\u5e94\u5b9e\u4f8b<\/li>\n<\/ul>\n<p>\u82b3\u9999\u91cd\u6c2e\u76d0\u7684\u4e00\u7cfb\u5217\u8f6c\u5316\uff1a\u5728CuCN\u4f5c\u7528\u4e0b\u3001\u53ef\u5f97\u5230\u76f8\u5e94\u7684\u82ef\u8148\u3002\u82e5\u7528CuCl\u3001CuBr\u5904\u7406\uff0c\u5219\u80fd\u5f97\u5230\u5bf9\u5e94\u7684\u5364\u4ee3\u884d\u751f\u7269\u3002\u548c\u7898\u5316\u94a0\u52a0\u70ed\u5219\u5f97\u7898\u4ee3\u884d\u751f\u7269\u3001\u7531\u56db\u6c1f\u787c\u9178\u94f6\u5904\u7406\u5f97\u5230\u6c1f\u787c\u9178\u91cd\u6c2e\u76d0\uff0c\u52a0\u70ed\u540e\u5f97\u5230\u6c1f\u4ee3\u884d\u751f\u7269(\u53c2\u89c1<a href=\"http:\/\/www.chem-station.com\/user-cgi-bin\/odoos\/ps_search.cgi?act=jump&amp;access=1&amp;url=http%3a%2f%2fwww%2echem%2dstation%2ecom%2fodos%2f2009%2f07%2fbalz%2dschiemann%2dbalz%2dschiemann%2ehtml\" target=\"_blank\">Balz-Schiemann\u53cd\u5e94<\/a>)\u3002\u8fd8\u6709\u3001\u52a0\u6c34\u6216\u9187\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\uff0c\u53ef\u5f97\u5230\u5bf9\u5e94\u7684\u915a\u3001\u82b3\u57fa\u919a\u7c7b\u884d\u751f\u7269\u3002\u7528\u4e9a\u78f7\u9178\u5904\u7406\u91cd\u6c2e\u76d0\u5219\u88ab\u6c22\u53d6\u4ee3\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter\" src=\"http:\/\/www.chem-station.com\/odos\/images\/sandmeyer_2.gif\" alt=\"sandmeyer_2.gif\" width=\"457\" height=\"291\" \/><\/p>\n<ul>\n<li>\u5b9e\u9a8c\u6b65\u9aa4<\/li>\n<\/ul>\n<ul>\n<li>\u5b9e\u9a8c\u6280\u5de7<\/li>\n<\/ul>\n<ul>\n<li>\u53c2\u8003\u6587\u732e<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u8be5\u53cd\u5e94\u82b3\u9999\u65cf\u91cd\u6c2e\u5316\u5408\u7269\u8f6c\u5316\u4e3a\u4e00\u7cfb\u5217\u53d6\u4ee3\u57fa\u7684\u603b\u79f0\u3002\u91cd\u6c2e\u5316\u5408\u7269\u662f\u7531\u8148\u6216\u82ef\u80fa\u7b49\u4f5c\u4e3a\u539f\u6599\u5f88\u5bb9\u6613\u5f97\u5230\u7684\u884d\u751f\u7269\u3002 \u57fa\u672c\u6587\u732e \u30fbSandmeyer, T.\u00a0Ber.\u00a01884,\u00a017, 1633. \u30fbSandmeyer, T.\u00a0Ber.\u00a01884,\u00a017, 2650. \u30fbHodgson, H. H.\u00a0Chem. Rev.\u00a01947,\u00a040, 251. DOI:\u00a010.1021\/cr60126a003\u00a0 \u30fbGalli, C.\u00a0Chem. Rev.\u00a01988,\u00a088, 765. DOI:\u00a010.1021\/cr00087a004 \u53cd\u5e94\u673a\u7406 \u4ece\u5f62\u5f0f\u4e0a\u76f8\u5f53\u4e8e\u82b3\u9999\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\u3002\u5b9e\u9645\u53ef\u80fd\u7531\u5355\u7535\u5b50\u8f6c\u79fb\u673a\u7406\u5b8c\u6210\uff0c\u4f46\u76ee\u524d\u5c1a\u672a\u660e\u786e\u3002 \u53cd\u5e94\u5b9e\u4f8b \u82b3\u9999\u91cd\u6c2e\u76d0\u7684\u4e00\u7cfb\u5217\u8f6c\u5316\uff1a\u5728CuCN\u4f5c\u7528\u4e0b\u3001\u53ef\u5f97\u5230\u76f8\u5e94\u7684\u82ef\u8148\u3002\u82e5\u7528CuCl\u3001CuBr\u5904\u7406\uff0c\u5219\u80fd\u5f97\u5230\u5bf9\u5e94\u7684\u5364\u4ee3\u884d\u751f\u7269\u3002\u548c\u7898\u5316\u94a0\u52a0\u70ed\u5219\u5f97\u7898\u4ee3\u884d\u751f\u7269\u3001\u7531\u56db\u6c1f\u787c\u9178\u94f6\u5904\u7406\u5f97\u5230\u6c1f\u787c\u9178\u91cd\u6c2e\u76d0\uff0c\u52a0\u70ed\u540e\u5f97\u5230\u6c1f\u4ee3\u884d\u751f\u7269(\u53c2\u89c1Balz-Schiemann\u53cd\u5e94)\u3002\u8fd8\u6709\u3001\u52a0\u6c34\u6216\u9187\u5728\u52a0\u70ed\u6761\u4ef6\u4e0b\uff0c\u53ef\u5f97\u5230\u5bf9\u5e94\u7684\u915a\u3001\u82b3\u57fa\u919a\u7c7b\u884d\u751f\u7269\u3002\u7528\u4e9a\u78f7\u9178\u5904\u7406\u91cd\u6c2e\u76d0\u5219\u88ab\u6c22\u53d6\u4ee3\u3002 \u5b9e\u9a8c\u6b65\u9aa4 \u5b9e\u9a8c\u6280\u5de7 \u53c2\u8003\u6587\u732e","protected":false},"author":3,"featured_media":841,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[16,99],"tags":[102,103,101,59,100],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2014\/03\/n-ar-111.gif","jetpack_shortlink":"https:\/\/wp.me\/p96op1-dy","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/840"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=840"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/840\/revisions"}],"predecessor-version":[{"id":28264,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/840\/revisions\/28264"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/841"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=840"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=840"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=840"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}