{"id":9182,"date":"2016-03-18T08:22:09","date_gmt":"2016-03-18T00:22:09","guid":{"rendered":"\/\/www.gsbet888.com\/?p=9182"},"modified":"2019-08-02T18:54:35","modified_gmt":"2019-08-02T10:54:35","slug":"post-9182","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94\/2016\/03\/post-9182.html","title":{"rendered":"Marshall \u7094\u4e19\u57fa\u5316"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>Marshall \u7094\u4e19\u57fa\u5316\u662f\u7094\u4e19\u57fa\u7532\u78fa\u9178\u916f\u8fd8\u539f\u6761\u4ef6\u4e0b\u4e0e\u919b\u57fa\u53d1\u751f\u5076\u8054\uff0c\u4ea7\u751f\u78b3-\u78b3\u952e\u7684\u53cd\u5e94\u3002\u7532\u78fa\u9178\u916f\u6240\u5728\u7684\u78b3\u539f\u5b50\u7684\u624b\u6027\u7ffb\u8f6c\uff0c\u751f\u6210\u7684\u4ea7\u7269\u6709\u4e24\u4e2a\u4e0d\u5bf9\u79f0\u4e2d\u5fc3\u3002\u53cd\u5e94\u5e38\u7528\u53cc\u4e59\u57fa\u950c\u3001InI(I)\u7b49\u4f5c\u4e3a\u8fd8\u539f\u5242\uff0c\u5e76\u4e14\u53ef\u4ee5\u5927\u91cf\u5408\u6210\u3002<\/p>\n<p>&nbsp;<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Marshall, J. A.; Adams, N. D.\u00a0<em>J. Org. Chem.<\/em>\u00a0<strong>1998<\/strong>,\u00a0<em>63<\/em>, 3812. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo980623j\">10.1021\/jo980623j<\/a><\/li>\n<li>Marshall, J. A.; Adams, N. D.\u00a0<em>J. Org. Chem.<\/em>\u00a0<strong>1999<\/strong>,\u00a0<em>64<\/em>, 5201. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo9823083\">10.1021\/jo9823083<\/a><\/li>\n<li>Marshall, J. A.; Grant, C. M.\u00a0<em>J. Org. Chem.<\/em>\u00a0<strong>1999<\/strong>,\u00a0<em>64<\/em>, 696. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo982255p\">10.1021\/jo982255p<\/a><\/li>\n<li>Marshall, J. A.; Chobanian, H. R.; Yanik, M. M.\u00a0<em>Org. Lett.\u00a0<\/em><strong>2001<\/strong>,\u00a0<em>3<\/em>, 3369. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ol016605x\">10.1021\/ol016605x<\/a><\/li>\n<li>Marshall, J. A.; Schaaf, G. M.\u00a0<em>J. Org. Chem.<\/em>\u00a0<strong>2001<\/strong>,\u00a0<em>66<\/em>, 7825. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo015936k\">10.1021\/jo015936k<\/a><\/li>\n<\/ul>\n<p><strong>&lt;review&gt;<\/strong><\/p>\n<ul>\n<li>Marshall, J. A.\u00a0<em>J. Org. Chem.<\/em>\u00a0<strong>2007<\/strong>,\u00a0<em>72<\/em>,\u00a08153. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo070787c\">10.1021\/jo070787c<\/a><\/li>\n<li>Ding, C.-H.; Hou, X.-L.\u00a0<em>Chem. Rev.<\/em>\u00a0<strong>2011<\/strong>,\u00a0<em>111<\/em>, 1914. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/cr100284m\">10.1021\/cr100284m<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p>\u901a\u8fc7\u94af\u50ac\u5316\u5242\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u80fd\u591f\u751f\u6210\u7acb\u4f53\u7279\u5f02\u6027\u7684\u624b\u6027\u4e19\u4e8c\u70ef\u91d1\u5c5e\u4e2d\u95f4\u4f53\uff0c\u518d\u4e0e\u919b\u901a\u8fc7\u73af\u72b6\u8fc7\u6e21\u4e2d\u95f4\u4f53\u53d1\u751f\u624b\u6027\u7ffb\u8f6c\uff0c\u5e76\u751f\u6210\u65b0\u7684\u78b3-\u78b3\u952e\u3002<\/p>\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_2.png\" rel=\"attachment wp-att-9186\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-9186\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_2.png\" alt=\"marshall_propargylation_2\" width=\"908\" height=\"639\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_2.png 908w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_2-300x211.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_2-768x540.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_2-680x479.png 680w\" sizes=\"(max-width: 908px) 100vw, 908px\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>Iejimalide B\u7684\u5408\u6210[1]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_1.png\" rel=\"attachment wp-att-9187\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-9187\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_1.png\" alt=\"marshall_propargylation_1\" width=\"1400\" height=\"261\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_1.png 1400w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_1-300x56.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_1-768x143.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_1-680x127.png 680w\" sizes=\"(max-width: 1400px) 100vw, 1400px\" \/><\/a><\/p>\n<p>Ushikulide A\u7684\u5168\u5408\u6210[2]\n<p><a href=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_3-1024x325.png\" rel=\"attachment wp-att-9188\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-9188\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_3-1024x325.png\" alt=\"marshall_propargylation_3-1024x325\" width=\"1024\" height=\"325\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_3-1024x325.png 1024w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_3-1024x325-300x95.png 300w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_3-1024x325-768x244.png 768w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/marshall_propargylation_3-1024x325-680x216.png 680w\" sizes=\"(max-width: 1024px) 100vw, 1024px\" \/><\/a><\/p>\n<p>&nbsp;<\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n<ol>\n<li>Chen, Q.; Schweitzer, D.; Kane, J.; Davisson, V. J.; Helquist,P.\u00a0<em>J. Org. Chem.<\/em>\u00a0<strong>2011<\/strong>,\u00a0<em>76<\/em>, 5157.\u00a0DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo200514m\">10.1021\/jo200514m<\/a><\/li>\n<li>(a) Trost, B. M.; O\u2019Boyle, B. M.<em>\u00a0J. Am. Chem. Soc.<\/em>\u00a0<strong>2008<\/strong>,\u00a0<em>130<\/em>, 16190. (b) Trost, B. M.; O\u2019Boyle, B. M.; Hund, D.\u00a0<em>J.\u00a0Am. Chem. Soc.<\/em>\u00a0<strong>2009<\/strong>,\u00a0<em>131<\/em>, 15061. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja906056v\">10.1021\/ja906056v<\/a><\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<h4>\u5916\u90e8\u94fe\u63a5<\/h4>\n<ul>\n<li><a href=\"http:\/\/faculty.virginia.edu\/marshallgroup\/\">Marshall Group\u00a0<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<p><strong>\u672c\u6587\u7248\u6743\u5c5e\u4e8e\u00a0<a href=\"\/\/www.gsbet888.com\/\">Chem-Station\u5316\u5b66\u7a7a\u95f4<\/a>\uff0c \u6b22\u8fce\u70b9\u51fb\u6309\u94ae\u5206\u4eab\uff0c\u672a\u7ecf\u8bb8\u53ef\uff0c\u8c22\u7edd\u8f6c\u8f7d<\/strong> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 Marshall \u7094\u4e19\u57fa\u5316\u662f\u7094\u4e19\u57fa\u7532\u78fa\u9178\u916f\u8fd8\u539f\u6761\u4ef6\u4e0b\u4e0e\u919b\u57fa\u53d1\u751f\u5076\u8054\uff0c\u4ea7\u751f\u78b3-\u78b3\u952e\u7684\u53cd\u5e94\u3002\u7532\u78fa\u9178\u916f\u6240\u5728\u7684\u78b3\u539f\u5b50\u7684\u624b\u6027\u7ffb\u8f6c\uff0c\u751f\u6210\u7684\u4ea7\u7269\u6709\u4e24\u4e2a\u4e0d\u5bf9\u79f0\u4e2d\u5fc3\u3002\u53cd\u5e94\u5e38\u7528\u53cc\u4e59\u57fa\u950c\u3001InI(I)\u7b49\u4f5c\u4e3a\u8fd8\u539f\u5242\uff0c\u5e76\u4e14\u53ef\u4ee5\u5927\u91cf\u5408\u6210\u3002 &nbsp; \u57fa\u672c\u6587\u732e Marshall, J. A.; Adams, N. D.\u00a0J. Org. Chem.\u00a01998,\u00a063, 3812. DOI:\u00a010.1021\/jo980623j Marshall, J. A.; Adams, N. D.\u00a0J. Org. Chem.\u00a01999,\u00a064, 5201. DOI:\u00a010.1021\/jo9823083 Marshall, J. A.; Grant, C. M.\u00a0J. Org. Chem.\u00a01999,\u00a064, 696. DOI:\u00a010.1021\/jo982255p Marshall, J. A.; Chobanian, H. R.; Yanik, M. M.\u00a0Org. Lett.\u00a02001,\u00a03, 3369. DOI:\u00a010.1021\/ol016605x Marshall, J. A.; Schaaf, G. M.\u00a0J. Org. Chem.\u00a02001,\u00a066, 7825. DOI:\u00a010.1021\/jo015936k &lt;review&gt; Marshall, J. A.\u00a0J. Org. Chem.\u00a02007,\u00a072,\u00a08153. DOI:\u00a010.1021\/jo070787c Ding, C.-H.; Hou, X.-L.\u00a0Chem. Rev.\u00a02011,\u00a0111, 1914. DOI:\u00a010.1021\/cr100284m &nbsp; \u53cd\u5e94\u673a\u7406 \u901a\u8fc7\u94af\u50ac\u5316\u5242\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\u80fd\u591f\u751f\u6210\u7acb\u4f53\u7279\u5f02\u6027\u7684\u624b\u6027\u4e19\u4e8c\u70ef\u91d1\u5c5e\u4e2d\u95f4\u4f53\uff0c\u518d\u4e0e\u919b\u901a\u8fc7\u73af\u72b6\u8fc7\u6e21\u4e2d\u95f4\u4f53\u53d1\u751f\u624b\u6027\u7ffb\u8f6c\uff0c\u5e76\u751f\u6210\u65b0\u7684\u78b3-\u78b3\u952e\u3002 &nbsp; \u53cd\u5e94\u5b9e\u4f8b Iejimalide B\u7684\u5408\u6210[1] Ushikulide A\u7684\u5168\u5408\u6210[2] &nbsp; \u53c2\u8003\u6587\u732e Chen, Q.; Schweitzer, D.; Kane, J.; Davisson, V. J.; Helquist,P.\u00a0J. Org. Chem.\u00a02011,\u00a076, 5157.\u00a0DOI:\u00a010.1021\/jo200514m (a) Trost, B. M.; O\u2019Boyle, B. M.\u00a0J. Am. Chem. Soc.\u00a02008,\u00a0130, 16190. (b) Trost, B. M.; [&hellip;]","protected":false},"author":3,"featured_media":9185,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[3,7],"tags":[1277,1278,1251,1276],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/03\/2015-08-01_09-25-44.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-2o6","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/9182"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=9182"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/9182\/revisions"}],"predecessor-version":[{"id":27727,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/9182\/revisions\/27727"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/9185"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=9182"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=9182"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=9182"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}