{"id":9328,"date":"2016-04-07T07:31:46","date_gmt":"2016-04-06T23:31:46","guid":{"rendered":"\/\/www.gsbet888.com\/?p=9328"},"modified":"2019-08-02T18:54:32","modified_gmt":"2019-08-02T10:54:32","slug":"post-9328","status":"publish","type":"post","link":"\/\/www.gsbet888.com\/reactions\/2016\/04\/post-9328.html","title":{"rendered":"Hayashi-Jorgensen\u50ac\u5316\u5242\uff08Hayashi-Jorgensen Catalyst\uff09"},"content":{"rendered":"<h4>\u6982\u8981<\/h4>\n<p>\u4e8c\u82b3\u57fa\u812f\u6c28\u9187\u7845\u919a\u53ef\u4ee5\u4e0e\u919b\u5f62\u6210\u5404\u79cd\u70ef\u80fa\/\u4e9a\u80fa\u578b\u6d3b\u6027\u4e2d\u95f4\u4f53\uff0c\u8fdb\u884c\u5404\u79cd\u624b\u6027\u50ac\u5316\u53cd\u5e94\u5f97\u5230\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684\u4ea7\u7269\u3002\u5e76\u4e14\u8be5\u50ac\u5316\u5242\u4f7f\u7528\u8d77\u6765\u5341\u5206\u7b80\u4fbf\uff0c\u4e0e\u539f\u578bProline\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u518d\u6d3b\u6027\u4e0e\u6eb6\u89e3\u6027\u4e0a\u5177\u6709\u5de8\u5927\u7684\u4f18\u52bf\u3002<\/p>\n<p><a class=\"broken_link\" href=\"http:\/\/www.ykbsc-chem.com\/\">\u6797\u96c4\u4e8c\u90ce<\/a>\u3001<a href=\"http:\/\/pure.au.dk\/portal\/en\/persons\/karl-anker-joergensen(3493fd45-67db-4228-a0a5-5d93bb039a30).html\">Karl\u00a0Anker Jorgensen<\/a>\u51e0\u4e4e\u5728\u540c\u4e00\u65f6\u671f\u5408\u6210\u5e94\u7528\u4e86\u8be5\u50ac\u5316\u5242\uff0c\u6240\u4ee5\u8be5\u50ac\u5316\u5242\u4e5f\u53eb<strong>\u6797-Jorgensen\u50ac\u5316\u5242<\/strong>\u3002<a href=\"http:\/\/www.chem-station.com\/odos\/2010\/01\/-macmillans-catalyst.html\">MacMillan<\/a>\u50ac\u5316\u5242\u4e3b\u8981\u662f\u4e9a\u80fa\u578b\u7684\u53cd\u5e94\u4e3a\u4e3b\uff0c\u800c\u8be5\u50ac\u5316\u5242\u4e3b\u8981\u662f\u70ef\u80fa\u578b\u7684\u8f83\u591a\u3002<\/p>\n<h4>\u57fa\u672c\u6587\u732e<\/h4>\n<ul>\n<li>Marigo, M.; Wabnitz, T. C.; Fielenbach, D.; Jorgensen, K. A.\u00a0<em>Angew.\u00a0Chem. Int. Ed.<\/em>\u00a0<strong>2005<\/strong>,\u00a0<em>44<\/em>, 794. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.200462101\">10.1002\/anie.200462101<br \/>\n<\/a><\/li>\n<li>Hayashi, Y.; Gotoh, H.; Hayashi, T.; Shoji, M.\u00a0<em>Angew. Chem. Int.\u00a0Ed.<\/em>\u00a0<strong>2005<\/strong>,\u00a0<em>44<\/em>, 4212. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.200500599\">10.1002\/anie.200500599<br \/>\n<\/a><\/li>\n<li>Franzen, J.; Marigo, M.; Fielenbach, D.; Wabnitz, T. C.; Kjarsgaard,\u00a0A.; Jorgensen, K. A.\u00a0<em>J. Am. Chem. Soc.\u00a0<\/em><strong>2005<\/strong>,\u00a0<em>127<\/em>, 18296. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja056120u\">10.1021\/ja056120u<\/a><\/li>\n<\/ul>\n<p>&lt;review&gt;<\/p>\n<ul>\n<li>Jensen, K. L.; Dickmeiss, G.; Jiang, H.; Albrecht, L.; Jorgensen,\u00a0K. A.\u00a0<em>Acc. Chem. Res.<\/em>\u00a0<strong>2012<\/strong>,\u00a0<em>45<\/em>,\u00a0248. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ar200149w\">10.1021\/ar200149w<br \/>\n<\/a><\/li>\n<li>Wroblewska, A.\u00a0<em>Synlett<\/em>\u00a0<strong>2012<\/strong>,\u00a0<em>23<\/em>,\u00a0953. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1055\/s-0031-1290774\">10.1055\/s-0031-1290774<\/a><\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h4>\u53cd\u5e94\u673a\u7406<\/h4>\n<p>\u8d28\u5b50\u9178\u5171\u50ac\u5316\u5242\u7684\u6dfb\u52a0\u53ef\u4ee5\u5f97\u5230\u60ca\u4eba\u7684\u6548\u679c\u3002(\u53c2\u8003\uff1a<em>Helv. Chim. Acta<\/em>\u00a0<strong>2011<\/strong>,\u00a0<em>94<\/em>, 719;\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja203660r\"><em>J. Am. Chem. Soc.<\/em>\u00a0<strong>2011<\/strong>,\u00a0<em>133<\/em>, 8822<\/a>;\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja300415t\"><em>J. Am. Chem. Soc.<\/em>\u00a0<strong>2012<\/strong>,\u00a0<em>134<\/em>, 6741<\/a>.)<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-medium wp-image-9330\" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/04\/Hayashi_Jorgensen_3-274x300.png\" alt=\"Hayashi_Jorgensen_3\" width=\"274\" height=\"300\" srcset=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/04\/Hayashi_Jorgensen_3-274x300.png 274w, https:\/\/assets.www.gsbet888.com\/uploads\/2016\/04\/Hayashi_Jorgensen_3.png 283w\" sizes=\"(max-width: 274px) 100vw, 274px\" \/><\/p>\n<h4>\u53cd\u5e94\u5b9e\u4f8b<\/h4>\n<p>\u8fbe\u83f2\u7684\u8d85\u9ad8\u6548\u5408\u6210\u5e94\u7528[1]\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-9331 \" src=\"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/04\/Hayashi_Jorgensen_2.gif\" alt=\"Hayashi_Jorgensen_2\" width=\"432\" height=\"226\" \/><\/p>\n<h4>\u53c2\u8003\u6587\u732e<\/h4>\n[1] Ishikawa, H.; Suzuki, T.; Hayashi, Y.\u00a0<em>Angew. Chem. Int. Ed.<\/em>\u00a0<strong>2009<\/strong>,\u00a0<em>48<\/em>, 1304. DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.200804883\">10.1002\/anie.200804883<\/a> <\/p>\n","protected":false},"excerpt":{"rendered":"\u6982\u8981 \u4e8c\u82b3\u57fa\u812f\u6c28\u9187\u7845\u919a\u53ef\u4ee5\u4e0e\u919b\u5f62\u6210\u5404\u79cd\u70ef\u80fa\/\u4e9a\u80fa\u578b\u6d3b\u6027\u4e2d\u95f4\u4f53\uff0c\u8fdb\u884c\u5404\u79cd\u624b\u6027\u50ac\u5316\u53cd\u5e94\u5f97\u5230\u9ad8\u5bf9\u6620\u9009\u62e9\u6027\u7684\u4ea7\u7269\u3002\u5e76\u4e14\u8be5\u50ac\u5316\u5242\u4f7f\u7528\u8d77\u6765\u5341\u5206\u7b80\u4fbf\uff0c\u4e0e\u539f\u578bProline\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u518d\u6d3b\u6027\u4e0e\u6eb6\u89e3\u6027\u4e0a\u5177\u6709\u5de8\u5927\u7684\u4f18\u52bf\u3002 \u6797\u96c4\u4e8c\u90ce\u3001Karl\u00a0Anker Jorgensen\u51e0\u4e4e\u5728\u540c\u4e00\u65f6\u671f\u5408\u6210\u5e94\u7528\u4e86\u8be5\u50ac\u5316\u5242\uff0c\u6240\u4ee5\u8be5\u50ac\u5316\u5242\u4e5f\u53eb\u6797-Jorgensen\u50ac\u5316\u5242\u3002MacMillan\u50ac\u5316\u5242\u4e3b\u8981\u662f\u4e9a\u80fa\u578b\u7684\u53cd\u5e94\u4e3a\u4e3b\uff0c\u800c\u8be5\u50ac\u5316\u5242\u4e3b\u8981\u662f\u70ef\u80fa\u578b\u7684\u8f83\u591a\u3002 \u57fa\u672c\u6587\u732e Marigo, M.; Wabnitz, T. C.; Fielenbach, D.; Jorgensen, K. A.\u00a0Angew.\u00a0Chem. Int. Ed.\u00a02005,\u00a044, 794. DOI:\u00a010.1002\/anie.200462101 Hayashi, Y.; Gotoh, H.; Hayashi, T.; Shoji, M.\u00a0Angew. Chem. Int.\u00a0Ed.\u00a02005,\u00a044, 4212. DOI:\u00a010.1002\/anie.200500599 Franzen, J.; Marigo, M.; Fielenbach, D.; Wabnitz, T. C.; Kjarsgaard,\u00a0A.; Jorgensen, K. A.\u00a0J. Am. Chem. Soc.\u00a02005,\u00a0127, 18296. DOI:\u00a010.1021\/ja056120u &lt;review&gt; Jensen, K. L.; Dickmeiss, G.; Jiang, H.; Albrecht, L.; Jorgensen,\u00a0K. A.\u00a0Acc. Chem. Res.\u00a02012,\u00a045,\u00a0248. DOI:\u00a010.1021\/ar200149w Wroblewska, A.\u00a0Synlett\u00a02012,\u00a023,\u00a0953. DOI:\u00a010.1055\/s-0031-1290774 &nbsp; \u53cd\u5e94\u673a\u7406 \u8d28\u5b50\u9178\u5171\u50ac\u5316\u5242\u7684\u6dfb\u52a0\u53ef\u4ee5\u5f97\u5230\u60ca\u4eba\u7684\u6548\u679c\u3002(\u53c2\u8003\uff1aHelv. Chim. Acta\u00a02011,\u00a094, 719;\u00a0J. Am. Chem. Soc.\u00a02011,\u00a0133, 8822;\u00a0J. Am. Chem. Soc.\u00a02012,\u00a0134, 6741.) \u53cd\u5e94\u5b9e\u4f8b \u8fbe\u83f2\u7684\u8d85\u9ad8\u6548\u5408\u6210\u5e94\u7528[1] \u53c2\u8003\u6587\u732e [1] Ishikawa, H.; Suzuki, T.; Hayashi, Y.\u00a0Angew. Chem. Int. Ed.\u00a02009,\u00a048, 1304. DOI:\u00a010.1002\/anie.200804883","protected":false},"author":5,"featured_media":9329,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","enabled":false},"version":2}},"categories":[2],"tags":[320,863,526],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/assets.www.gsbet888.com\/uploads\/2016\/04\/2014-11-29_21-00-02.png","jetpack_shortlink":"https:\/\/wp.me\/p96op1-2qs","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/9328"}],"collection":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/comments?post=9328"}],"version-history":[{"count":2,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/9328\/revisions"}],"predecessor-version":[{"id":27715,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/posts\/9328\/revisions\/27715"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media\/9329"}],"wp:attachment":[{"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/media?parent=9328"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/categories?post=9328"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.gsbet888.com\/wp-json\/wp\/v2\/tags?post=9328"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}